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Iron(III) Complexes Based on N-Benzylidene-2-Hydroxy-3,5-Di-tert-Butylaniline

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Abstract

Five-coordinate iron(III) complexes, (ImPh)2FeX (X = Cl (I), Br (II), I (III), N3 (IV)) containing two bidentate Schiff bases (N-benzylidene-2-hydroxy-3,5-di-tert-butylaniline (ImPh)H) and a halogen atom/azide group in the coordination sphere were synthesized and characterized in detail. According to the magnetic susceptibility measurements for polycrystalline samples of I–IV and Mössbauer spectroscopy data in the 2–300 K range, the complexes contain a high-spin metal ion (HS Fe3+, d5, SFe = 5/2). Compounds I–IV are stable in the crystalline state in the absence of oxygen or air moisture; however, in solution, they undergo symmetrization, resulting in the formation of the tris-ligand complex (ImPh)3Fe (V), which was also synthesized by the reaction (ImPh)H and FeCl3 (3 : 1). Unlike five-coordinate complexes I–IV, six-coordinate complex V contains low-spin iron(III) ion (LS Fe3+, d5, SFe = 1/2). The molecular structure of I was determined by X-ray diffraction (CIF file CCDC no. 1996527).

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REFERENCES

  1. van Koningsbruggen, P.J., Maeda, Y., and Oshio, H., Top. Curr. Chem., 2004, vol. 233, p. 259.

    Article  CAS  Google Scholar 

  2. Nihei, M., Shiga, T., Maeda, Y., and Oshio, H., Coord. Chem. Rev., 2007, vol. 251, p. 2606.

    Article  CAS  Google Scholar 

  3. Harding, D.J., Harding, P., and Phonsri, W., Coord. Chem. Rev., 2016, vol. 313, p. 38.

    Article  CAS  Google Scholar 

  4. Ksenofontov, V., Gaspar, A.B., and Gutlich, P., Top. Curr. Chem., 2004, vol. 235, p. 23.

    Article  CAS  Google Scholar 

  5. Hauser, A., Top. Curr. Chem., 2004, vol. 234, p. 155.

    Article  CAS  Google Scholar 

  6. Létard, J.-F., J. Mater. Chem., 2006, vol. 16, p. 2550.

    Article  Google Scholar 

  7. Cannizzo, A., Milne, C.J., Consani, C., et al., Coord. Chem. Rev., 2010, vol. 254, p. 2677.

    Article  CAS  Google Scholar 

  8. Bousseksou, A., Varret, F., Goiran, M., et al., Top. Curr. Chem., 2004, vol. 235, p. 65.

    Article  CAS  Google Scholar 

  9. Halcrow, M.A., Spin-Crossover Materials, Properties and Applications, New York: Wiley, 2013.

    Book  Google Scholar 

  10. Starikova, A., Starikov, A.G., and Minkin, V.I., Russ. Chem. Bull., 2016, vol. 65, p. 1464.

    Article  CAS  Google Scholar 

  11. Starikova, A.A., Starikov, A.G., and Minkin, V.I., Russ. J. Coord. Chem., 2017, vol. 43, p. 718. https://doi.org/10.1134/S1070328417110094

    Article  CAS  Google Scholar 

  12. Starikov, A.G., Chegerev, M.G., Starikova, A.A., and Minkin, V.I., Russ. J. Coord. Chem., 2019, vol. 45, p. 675. https://doi.org/10.1134/S1070328419090082

    Article  CAS  Google Scholar 

  13. Starikov, A.G., Starikova, A.A., Chegerev, M.G., and Minkin, V.I., Russ. Chem. Bull., 2019, vol. 68, p. 725.

    Article  CAS  Google Scholar 

  14. Starikova, A.A., Chegerev, M.G., Starikov, A.G., and Minkin, V.I., J. Comput. Chem., 2019, vol. 40, p. 2284.

    Article  CAS  Google Scholar 

  15. Starikova, A.A., Metelitsa, E.A., and Starikov, A.G., J. Struct. Chem., 2019, vol. 60, p. 1219.

    Article  CAS  Google Scholar 

  16. Earnshaw, A., King, E.A., and Larkworthy, L.F., Chem. Commun. (London), 1965, p. p. 180.

  17. Earnshaw, A., King, E.A., and Larkworthy, L.F., J. Chem. Soc. A, 1969, p. 2459.

  18. Haller, K.J., Johnson, P.L., Feltham, R.D., et al., Inorg. Chim. Acta, 1979, vol. 33, p. 119.

    Article  CAS  Google Scholar 

  19. Fitzsimmons, B.W., Larkworthy, L.F., and Rogers, K.A., Inorg. Chim. Acta, 1980, vol. 44, p. L53.

    Article  CAS  Google Scholar 

  20. Wells, F.V., McCann, S.W., Wickman, H.H., et al., Inorg. Chem., 1982, vol. 21, p. 2306.

    Article  CAS  Google Scholar 

  21. Koenig, E., Ritter, G., Waigel, J., et al., Inorg. Chem., 1987, vol. 26, p. 1563.

    Article  CAS  Google Scholar 

  22. Weber, B., Gorls, H., Rudolph, M., and Jäger, E.-G., Inorg. Chim. Acta, 2002, vol. 337, p. 247.

    Article  CAS  Google Scholar 

  23. Nakamura, M., Coord. Chem. Rev., 2006, vol. 250, p. 2271.

    Article  CAS  Google Scholar 

  24. Ohgo, Y., Chiba, Y., Hashizume, D., et al., Chem. Commun., 2006, p. 1935.

  25. Chun, H., Weyhermüller, T., Bill, E., and Wieghardt, K., Angew. Chem., Int. Ed. Engl., 2001, vol. 40, p. 2489.

    Article  CAS  Google Scholar 

  26. Chun, H., Bill, E., Weyhermüller, T., and Wieghardt, K., Inorg. Chem., 2003, vol. 42, p. 5612.

    Article  CAS  Google Scholar 

  27. Abakumov, G.A., Cherkasov, V.K., Bubnov, M.P., et al., Russ. Chem. Bull. Int. Ed., 2006, vol. 55, p. 44.

    Article  CAS  Google Scholar 

  28. Piskunov, A.V., Pashanova, K.I., Ershova, I.V., et al., J. Mol. Struct., 2018, vol. 1165, p. 51.

    Article  CAS  Google Scholar 

  29. Ershova, I.V., Bogomyakov, A.S., Kubrin, S.P., et al., Inorg. Chim. Acta, 2020, vol. 503, p. 119402.

    Article  Google Scholar 

  30. Credendino, L. and Sproules, S., Asian J. Org. Chem., 2019, vol. 9, p. 421.

    Article  Google Scholar 

  31. Perrin, D.D., Armarego, W.L.F., and Perrin, D.R., Purification of Laboratory Chemicals, Oxford: Pergamon, 1980.

    Google Scholar 

  32. Yasuhiko, S., Norio, K., and Terunori, F., Chem. Lett., 2002, vol. 31, p. 358.

    Article  Google Scholar 

  33. Rigaku Oxford Diffraction. CrysAlis Pro Software System. Version 1.171.38.46, Wroclaw: Rigaku Corporation, 2015.

  34. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  35. Spek, A.L., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 9.

    Article  CAS  Google Scholar 

  36. Piskunov, A.V., Ershova, I.V., Bogomyakov, A.S., et al., Inorg. Chem., 2015, vol. 54, p. 6090.

    Article  CAS  Google Scholar 

  37. Piskunov, A.V., Ershova, I.V., Bogomyakov, A.S., and Fukin, G.K., Inorg. Chem. Commun., 2016, vol. 66, p. 94.

    Article  CAS  Google Scholar 

  38. Ershova, I.V., Bogomyakov, A.S., Fukin, G.K., and Piskunov, A.V., Eur. J. Inorg. Chem., 2019, vol. 2019, p. 938.

    Article  CAS  Google Scholar 

  39. Beilstein, F., Ber. Dtsch. Chem. Ges., 1872, vol. 5, p. 620.

    Article  Google Scholar 

  40. Addison, A.W., Rao, T.N., Reedijk, J., et al., Dalton Trans., 1984, p. 1349.

  41. Mukherjee, S., Weyhermüller, T., Bothe, E., and Chaudhuri, P., Eur. J. Inorg. Chem., 2003, vol. 2003, p. 1956.

    Article  Google Scholar 

  42. Suzuki, Y., Tanaka, H., Oshiki, T., et al., Chem. Asian J., 2006, vol. 1, p. 878.

    Article  CAS  Google Scholar 

  43. Zhang, L., Luo, X., Gao, W., et al., Organometallics, 2013, vol. 32, p. 6277.

    Article  CAS  Google Scholar 

  44. Safaei, E., Alaji, Z., Panahi, F., et al., New J. Chem., 2018, vol. 42, p. 7230.

    Article  CAS  Google Scholar 

  45. Batsanov, S.S. Russ. J. Inorg. Chem. 1991, vol. 36, p. 1694.

    Google Scholar 

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ACKNOWLEDGMENTS

The studies were carried out using research equipment of the Center for Collective Use “Analytical Center of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences” at the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences and supported by the Federal Research Program “Research and Development in the Priority Areas of the Science and Technology Sector of Russia for 2014–2020” (unique identifier of the project: RFMEFI62120X0040).

Funding

The study was supported by the Russian Science Foundation (project no. 18-73-00268).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    I. V. Ershova, A. V. Cherkasov & A. V. Piskunov

  2. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Bogomyakov

  3. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    S. P. Kubrin

Authors
  1. I. V. Ershova
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  2. A. S. Bogomyakov
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  3. S. P. Kubrin
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  4. A. V. Cherkasov
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  5. A. V. Piskunov
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Correspondence to A. V. Piskunov.

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Translated by Z. Svitanko

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Ershova, I.V., Bogomyakov, A.S., Kubrin, S.P. et al. Iron(III) Complexes Based on N-Benzylidene-2-Hydroxy-3,5-Di-tert-Butylaniline. Russ J Coord Chem 47, 1–9 (2021). https://doi.org/10.1134/S1070328421010012

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