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Synthesis and structural characterization of oxovanadium(V) complexes with mixed tridentate benzohydrazone and bidentate no ligands

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Abstract

New oxovanadium(V) complexes, [VO(L1)(Bha)] (I) and [VO(L2)(Qnl)] (II), were prepared by the reactions of [VO(Acac)2] (Acac = acetylacetonate), (4-nitrophenoxy)acetic acid [1-(2-hydroxy-3-methylphenyl)methylidene]hydrazide (H2L1) and benzohydroxamic acid (HBha), and [VO(Acac)2], N′-(2-hydroxy-5-methylbenzylidene)-3-methylbenzohydrazide (H2L2), and 8-hydroxyquinoline (HQnl) in methanol, respectively. Crystal and molecular structures of complexes I and II were determined by elemental analysis, infrared and UV-Vis spectra and single crystal X-ray diffraction (CIF files CCDC nos. 1000875 (I) and 1012028 (II)). The V atoms in the complexes are in octahedral coordination. Thermal stability of complex I was studied.

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Authors and Affiliations

  1. School of Life Sciences, Shandong University of Technology, ZiBo, 255049, P.R. China

    G. H. Sheng, Y. W. Han, Y. Xu, X. M. Hu & H. L. Zhu

  2. Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, P.R. China

    Z. L. You

Authors
  1. G. H. Sheng
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  2. Y. W. Han
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  3. Y. Xu
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  4. X. M. Hu
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  5. Z. L. You
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  6. H. L. Zhu
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Correspondence to Z. L. You.

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Sheng, G.H., Han, Y.W., Xu, Y. et al. Synthesis and structural characterization of oxovanadium(V) complexes with mixed tridentate benzohydrazone and bidentate no ligands. Russ J Coord Chem 41, 496–502 (2015). https://doi.org/10.1134/S1070328415080047

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  • DOI: https://doi.org/10.1134/S1070328415080047

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