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Electrochemical Control of the Electron Conductivity of Thin Films of Metalorganic Polymers

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Abstract

The dependence of the conductivity of thin films of polymer complexes of nickel with N4 ligands of macrocyclic and chelate structure on the do** level has been studied by the method of electrochemical in situ conductivity. The electrochemical conductivity window of polymers depends on the structure of the monomers and reaches 1.2 V for the macrocyclic complex. Electrochemical do** changes the electrical resistance of the investigated materials by 4 orders of magnitude.

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Funding

This work was supported in part by the Russian Science Foundation, project no. 19-73-00246.

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Authors and Affiliations

  1. Ioffe Physical Technical Institute, 194021, St. Petersburg, Russia

    M. P. Karushev & A. M. Timonov

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  1. M. P. Karushev
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  2. A. M. Timonov
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Correspondence to M. P. Karushev.

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Translated by P. Pozdeev

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Karushev, M.P., Timonov, A.M. Electrochemical Control of the Electron Conductivity of Thin Films of Metalorganic Polymers. Tech. Phys. Lett. 47, 789–791 (2021). https://doi.org/10.1134/S1063785021080174

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  • DOI: https://doi.org/10.1134/S1063785021080174

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