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Synthesis and Investigation of Magnesium–Aluminum Nanopowders and Ceramics Activated by Copper

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Abstract

Nanopowders of two crystalline phases, magnesium–aluminum spinel (98 wt %), and cuprite (2 wt %) have been obtained by laser evaporation of a solid target, which is a mechanical mixture of simple oxides (MgO, Al2O3, CuO). These nanopowders have been used to prepare test samples of transparent Cu:MgAl2O4 ceramics, the IR transmission spectra of which revealed two new strong absorption bands at λ1 ≈ 1.55 (1.45) μm and λ2 ≈ 3.45 (3.03) μm, corresponding to transitions between the Stark levels 2E(\({\text{t}}_{2}^{6}\)e3) and 2T2 (\({\text{t}}_{2}^{5}\)e4) of Cu2+ ions in octahedral and tetrahedral positions, respectively.

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Funding

The work was carried out within the framework of the Russian Foundation for Basic Research (project no. 20-08-00054) and in the framework of the state budget of the Institute of Electrophysics of the Ural Branch of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Electrophysics of the Ural Branch of the Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    V. V. Osipov, V. I. Solomonov, A. V. Podkin, V. A. Shitov & E. V. Tikhonov

  2. Ural Federal University Named after the First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia

    V. I. Solomonov & A. S. Korsakov

Authors
  1. V. V. Osipov
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  2. V. I. Solomonov
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  3. A. V. Podkin
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  4. V. A. Shitov
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  5. E. V. Tikhonov
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  6. A. S. Korsakov
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Correspondence to V. V. Osipov.

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Translated by D. Kharitonov

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Osipov, V.V., Solomonov, V.I., Podkin, A.V. et al. Synthesis and Investigation of Magnesium–Aluminum Nanopowders and Ceramics Activated by Copper. Tech. Phys. 66, 149–154 (2021). https://doi.org/10.1134/S1063784221010151

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  • DOI: https://doi.org/10.1134/S1063784221010151

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