Abstract
The effect of thermal treatment in zinc vapor on the stoichiometry, defect and impurity structure, and activator cathodoluminescence of ZnSe doped with iron by the thermal diffusion method has been studied. Using a variety of measurement methods, it is found that, on the one hand, the separate regions in which the edge luminescence intensity drops become larger. On the other hand, the stoichiometry is improved and the integrated luminescence intensity, as well as the activator luminescence intensity, increase. The data obtained agree with the general approach to the mechanism of the influence of thermal treatment on the properties of doped ZnSe.
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ACKNOWLEDGMENTS
We are grateful to K.V. Chizh and M.S. Storozhevykh for fruitful discussion of the results.
The work was supported by the Ministry of Science and Higher Education within the State assigment FSRC “Crystallography and Phonics” of RAS in part of electron microscopy investigation and equipment of the Mixed-Use Center “Technolojgical and Diagnostic Center for Production, Investigation and Certification of Micro- and Nanostructures” of the Pro-khorov General Physics Institute of the Russian Academy of Sciences. The study was supported (in part) the Russian Foundation for Basic Research, project no. 19-02-00294a.
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Translated by A. Zolot’ko
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Kalinushkin, V.P., Klechkovskaya, V.V., Klevkov, Y.V. et al. Influence of Annealing in Zinc Vapor on the Microstructure and Activator Radiation of ZnSe : Fe. Crystallogr. Rep. 64, 113–118 (2019). https://doi.org/10.1134/S1063774518060159
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DOI: https://doi.org/10.1134/S1063774518060159