SpringerLink
Log in

Analytical Characteristics of Multicapillary Gas Chromatographic Columns with 25 µm Capillaries

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Straight multicapillary columns (MCCs) with 40 µm capillaries are used in portable gas analyzers. In order to increase the efficiency and speed of gas chromatographic separation, straight MCCs with a diameter of 25 μm and a length of 200–250 mm with an OV-5 stationary phase (film thickness, 0.1–0.2 μm) were fabricated and their main chromatographic characteristics were determined. It was shown that the maximum specific efficiency of the MCCs was 25 600 theoretical plates/m and the separation rate reached 630 theoretical plates/s, which significantly exceed the corresponding values for 40 μm MCCs. The test MCCs retained high separation efficiency in wide ranges of carrier gas flow rates: 30–170 cm3/min for argon and nitrogen and 120–420 cm3/min for helium. However, as compared to the 40 µm columns, approximately twice the pressure was required to ensure the same flow of a carrier gas through the 25 µm MCCs. A decrease in the diameter of MCC channels from 40 to 25 µm made it possible to shorten the column length by about 1/3 with the retention of the column efficiency.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Gruznov, V.M., Shishmarev, A.T., Filonenko, V.G., Baldin, M.N., and Naumenko, I.I., J. Anal. Chem., 1999, vol. 54, no. 9, p. 850.

    CAS  Google Scholar 

  2. Baldin, M.N. and Gruznov, V.M., J. Anal. Chem., 2013, vol. 68, no. 11, p. 1002. https://doi.org/10.7868/S0044450213110029

    Article  CAS  Google Scholar 

  3. Gruznov, V.M., Baldin, M.N., Naumenko, I.I., Kartashov, E.V., and Pryamov, M.V., in Khimicheskii analiz v geologii i geokhimii (Chemical Analysis in Geology and Geochemistry), Anoshin, G.N., Ed., Novosibirsk: Geo, 2016.

  4. Malysheva, A.O., Baldin, M.N., Gruznov, V.M., and Blinova, L.V., Anal. Kontrol’, 2018, vol. 22, no. 2, p. 177. https://doi.org/10.15826/analitika.2018.22.2.007

    Article  Google Scholar 

  5. Portable gas chromatograph GKhS-02P. http://www. sibel.info/en/gas-chromatographs/gcs-02f.html. Accessed February 2022.

  6. Izdelie “Shpinat-M1”. Rukovodstvo po ekspluatatsii (“Spinach-M1” Instrument: Manual), Smolensk: Analitpribor, 2006.

  7. Buryakov, I.A., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2004, vol. 800, p. 75. https://doi.org/10.1016/j.jchromb.2003.10.064

    Article  CAS  Google Scholar 

  8. Baumbach, J.I., Eiceman, G.A., Klockow, D., Sielemann, St., and Irmer, A.V., Int. J. Environ. Anal. Chem., 1997, vol. 66, no. 4, p. 225. https://doi.org/10.1080/03067319708028366

    Article  CAS  Google Scholar 

  9. Sielemann, St., Baumbach, J.I., and Schmidt, H., Int. J. Ion Mobility Spectrom., 2000, vol. 5, no. 3, p. 143.

    Google Scholar 

  10. Aguilera-Herradora, E., Cardenasa, S., Ruzsanyi, V., Sielemann, St., and Valcarcel, M., J. Chromatogr. A, 2008, vol. 1214, p. 143. https://doi.org/10.1016/j.chroma.2008.10.050

    Article  CAS  Google Scholar 

  11. Jünger, M., Bodeker, B., and Baumbach, J.I., Anal. Bioanal. Chem., 2010, vol. 396, p. 471. https://doi.org/10.1007/s00216-010-3798-1

    Article  CAS  Google Scholar 

  12. Perl, T., Bödeker, B., Jünger, M., Nolte, J., and Vautz, W., Anal. Bioanal. Chem., 2010, vol. 397, p. 2385. https://doi.org/10.1007/s00216-010-3798-1

    Article  CAS  Google Scholar 

  13. Hauschild, A.-C., Schneider, T., Pauling, J., Rupp, K., Jang, M., Baumbach, J.I., and Baumbach, J., Metabolites, 2012, vol. 2, p. 733. https://doi.org/10.3390/metabo2040733

    Article  CAS  Google Scholar 

  14. Garrido-Delgado, R., Dobao-Prieto, M., del Mar, ArceL., and Valcarcel, M., Food Chem., 2015, vol. 187, p. 572. https://doi.org/10.1016/j.foodchem.2015.04.082

    Article  CAS  Google Scholar 

  15. Marquez-Silleroa, I., Cardenasa, S., Sielemann, St., and Valcarcela, M., J. Chromatogr. A, 2014, vol. 1333, p. 99. https://doi.org/10.1016/j.chroma.2014.01.062

  16. **e, Z., Sielemann, St., Schmidt, H., and Baumbach, J.I., Int. J. Ion Mobility Spectrom., 2000, vol. 4, no. 1, p. 77.

    Google Scholar 

  17. Baumbach, J.I., Sielemann, St., **e, Z., and Schmidt, H., Anal. Chem., 2003, vol. 75, p. 1483. https://doi.org/10.1021/ac020342i

    Article  CAS  Google Scholar 

  18. Range of Products. http://mcc-chrom.com/catalogue. Accessed February 2022.

  19. Sacks, R.D., in Modern Practice of Gas Chromatography, Grob, R.L. and Barry, E.F., Eds., New York: Wiley, 2004, p. 229.

    Google Scholar 

  20. Naumenko, I.I. and Efimenko, A.P., Zavod. Lab., Diagn. Mater., 2016, vol. 82, no. 4, p. 73.

    Google Scholar 

  21. Naumenko, I.I. and Soboleva, V.K., Sorbtsionnye Khromatogr. Protsessy, 2016, vol. 16, no. 5, p. 591.

    CAS  Google Scholar 

  22. Naumenko, I.I., Efimenko, A.P., Baldin, M.N., and Gruznov, V.M., Datchiki Sist., 2013, no. 11, p. 51.

  23. Soldatov, V.P., Efimenko, A.P., Naumenko, I.I., and Chertilina, L.N., USSR Inventor’s Certificate no. 1659838, 1991.

  24. Efimenko A.P., Naumenko I.I., and Soboleva V.K., Russ. J. Phys. Chem., 2007, vol. 81, p. 410. https://doi.org/10.1134/S003602440703020X

    Article  CAS  Google Scholar 

  25. Sidel’nikov, V.N. and Patrushev, Yu.V., Ross. Khim. Zh., 2003, vol. 47, no. 1, p. 23.

    Google Scholar 

  26. Yashin, Ya.I. and Yashin, A.Ya., J. Anal. Chem., 2001, vol. 56, no. 9, p. 794.

    Article  CAS  Google Scholar 

  27. Baldin, M.N., Gorokhov, A.F., Kile, A.N., and Rybolovlev, V.G., RF Patent 2207563, 2001.

  28. Cooke, W.S., Today Chem. Work, 1996, vol. 5, no. 1, p. 16.

    Google Scholar 

  29. Pereiro, I.R., Schmitt, V.O., and Lobinski, R., Anal. Chem., 1997, vol. 69, no. 23, p. 4799. https://doi.org/10.1021/ac970410e

    Article  CAS  Google Scholar 

  30. Lobinski, R., Sidelmkov, V., Patrushev, Y., Rodriguez, I., and Wasik, A., TrAC, Trends Anal. Chem., 1999, vol. 18, no. 7, p. 449. https://doi.org/10.1016/S0165-9936(99)00119-3

    Article  CAS  Google Scholar 

  31. Rosenkranz, B. and Bettmer, J., Anal. Bioanal. Chem., 2002, vol. 373, p. 461. https://doi.org/10.1007/s00216-002-1331-x

    Article  CAS  Google Scholar 

  32. Hinshaw, J.V., LC GC Asia Pac., 2013, vol. 16, no. 4, p. 22. http://www.researchgate.net/publication/286655912_Practical_Gas_Chromatography.

  33. Gruznov, V.M., Baldin, M.N., Makas, A.L., and Titov, B.G., J. Anal. Chem., 2011, vol. 66, no. 11, p. 1121. https://doi.org/10.1134/S1061934811110074

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Comprehensive Program for Fundamental Research of the Siberian Branch of the Russian Academy of Sciences (project nos. 0385-2018-0014, 0331-2019-0029, and 0331-2018-0009).

Author information

Authors and Affiliations

  1. Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    I. I. Naumenko & V. M. Gruznov

  2. Multichrom Ltd., 630117, Novosibirsk, Russia

    A. P. Efimenko

  3. Novosibirsk State University, 630090, Novosibirsk, Russia

    V. M. Gruznov

  4. Novosibirsk State Technical University, 630073, Novosibirsk, Russia

    V. M. Gruznov

Authors
  1. I. I. Naumenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. P. Efimenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Gruznov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. I. Naumenko.

Additional information

Translated by V. Makhlyarchuk

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Naumenko, I.I., Efimenko, A.P. & Gruznov, V.M. Analytical Characteristics of Multicapillary Gas Chromatographic Columns with 25 µm Capillaries. J Anal Chem 77, 1570–1576 (2022). https://doi.org/10.1134/S1061934822120097

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934822120097

Keywords:

Search

Navigation