SpringerLink
Log in

Determination of o-phthalic acid esters in water by chromatography–mass spectrometry with emulsion dispersive liquid–liquid microextraction preconcentration

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Using emulsion dispersive liquid–liquid microextraction preconcentration and injection of a large volume of an extract (10 μL), the limits of chromatographic–mass spectrometric detection of o-phthalic acid esters in water have been attained at the level 4 × 10–6–1 × 10–5 mg/L. The main source of the systemic error of the determination of impurities was found to be the release of o-phthalates from microparticles of chromatographic septum to the carrier gas. The extractant (n-octane) was purified by Rayleigh distillation. The independence of the concentration coefficient of the studied o-phthalates of concentration in the range (0.4–30) × 10–4 mg/L has been demonstrated. The relative expanded uncertainty of the determination of o-phthalates has been calculated and equals 12–39%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price includes VAT (France)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. GN (Hygienic Norms) 2.1.5.1315-03: Maximum Permissible Concentration (MPC) of Chemicals in Water Bodies of Drinking and Community Water Use, Moscow: SanEpidSluzhba, 2003.

  2. Kokosa, J.M., Przyjazny, A., and Jeannot, M.A., Solvent Microextraction: Theory and Practice, New Jersey: Wiley, 2009.

    Google Scholar 

  3. Krylov, V.A., Krylov, A.V., Mosyagin, P.V., and Matkivskaya, Yu.O., J. Anal. Chem., 2011, vol. 66, no. 4, p. 331.

    Article  CAS  Google Scholar 

  4. Krylov, V.A. and Volkova, V.V., Vestn. Nizhegorod. Gos. Univ., 2014, no. 1, p. 119.

    Google Scholar 

  5. Krylov, V.A., Volkova, V.V., and Zaitsev, S.D., Anal. Kontrol’, 2013, vol. 17, no. 3, p. 295.

    Google Scholar 

  6. Chiou, C.T., Freed, V.H., Schmedding, D.W., and Kohnert, R.L., Environ. Sci. Technol., 1977, vol. 11, no. 5, p. 475.

    Article  CAS  Google Scholar 

  7. Wells, M.J.M. and Somenath, M.M., in Principles of Extraction and the Extraction of Semivolatile Organics from Liquids, Winefordner, J.D., Ed., New Jersey: Wiley, 2003, p. 37.

  8. Zhang, H., Chen, X., and Jiang, X., Anal. Chim. Acta, 2011, vol. 689, no. 1, p. 137.

    Article  CAS  Google Scholar 

  9. Zhang, Y. and Lee, H., J. Chromatogr. A, 2013, vol. 1274, p. 28.

    Article  CAS  Google Scholar 

  10. Farajzadeh, M.A. and Mogaddam, M.R.A., Anal. Chim. Acta, 2012, vol. 728, p. 31.

    Article  CAS  Google Scholar 

  11. Regueiro, J., Llompart, M., Garcia-Jares, C., Garcia-Monteagudo, J.C., and Cela, R., J. Chromatogr. A, 2008, vol. 1190, nos. 1–2, p. 27.

    Article  CAS  Google Scholar 

  12. Kamarei, F., Ebrahimzadeh, H., and Yamini, Y., Microchem. J., 2011, vol. 99, no. 1, p. 26.

    Article  CAS  Google Scholar 

  13. Noti, A. and Grob, K., Anal. Chim. Acta, 2007, vol. 582, no. 2, p. 353.

    Article  Google Scholar 

  14. Spravochnik khimika (A Chemist’s Handbook) Nikol’skii, B.P., Ed., Moscow: Khimiya, 1963.

    Google Scholar 

  15. Zel’venskii, Ya.D., Titov, A.A., and Shalygin, V.A., Rektifikatsiya razbavlennykh rastvorov (Rectification of Dilute Solutions), Leningrad: Khimiya, 1974.

    Google Scholar 

  16. Devyatykh, G.G., Murskii, L.G., Loginov, A.V., Rodchenkov, V.I., Agliulov, N.Kh., and Krylov, V.A., Vysokochist. Veshchestva, 1988, no. 6, p. 129.

    Google Scholar 

  17. Krylov, A.V., Krylov, V.A., Bochkareva, L.V., Mosyagin, P.V., and Matkivskaya, Yu.O., J. Anal. Chem., 2012, vol. 67, no. 3, p. 207.

    Article  CAS  Google Scholar 

  18. Krylov, V.A., Matkivskaya, Yu.O., Krylov, A.V., and Mosyagin, P.V., in Materialy Vseros. konf. “Analiticheskaya khromatografiya i kapillyarnyi elektroforez” (Proc. All-Russian Conf. on Analytical Chromatography and Capillary Electrophoresis), Krasnodar, 2010, p. 81.

    Google Scholar 

  19. Ul’trazvukovaya Entsiklopediya (Encyclopedia of Ultrasound), Golyamina, I.P., Ed., Moscow: Sovetskaya entsiklopediya, 1979.

    Google Scholar 

  20. Yan, H., Liu, B., Du, J., and Row, K.H., Analyst, 2010, vol. 135, no. 10, p. 585.

    Article  Google Scholar 

  21. Bowen, T.J., An Introduction to Ultracentrifugation, London: Wiley, 1970.

    Google Scholar 

  22. Su, Y. and Jen, J., J. Chromatogr. A, 2010, vol. 1217, no. 31, p. 5043.

    Article  CAS  Google Scholar 

  23. Zhang, J., Gao, H., Peng, B., Li, Y., Li, S., and Zhou, Z., Talanta, 2012, vol. 88, p. 330.

    Article  CAS  Google Scholar 

  24. Merlin Instrument Company. www.merlinic.com/products/merlin-microseal/how-the-merlin-microsealworks. Cited May 23, 2015.

  25. Markovich, R.P. and Veeten, A.R., RF Patent 2179563, Byull. Izobret., 2005, no. 13.

  26. Sil’vio, P., Rainer, Sh., and Antonella, A., RF Patent 2230089, Byull. Izobret., 2010, no. 20.

  27. Gawlic-Jedrusiak, M., J. Anal. Chem., 2013, vol. 68, no. 11, p. 959.

    Article  Google Scholar 

  28. Validation of Analytical Methods. Definitions and Terminology, ICH Q2A Guideline, Geneva, 1995.

  29. Guideline Validation of Analytical Procedures. Methodology, ICH Q2B, Geneva, 1996.

  30. Liang, P., Xu, J., and Li, Q., Anal. Chim. Acta, 2008, vol. 609, no. 1, p. 53.

    Article  CAS  Google Scholar 

  31. Psillacis, E. and Kalogerakis, N., J. Chromatogr. A, 2003, vol. 999, no. 1, p. 145.

    Article  Google Scholar 

  32. ISO 5725-4: Accuracy (Trueness and Precision) of Measurement Methods and Results, part 4: Basic Methods for the Determination of the Trueness of a Standard Measurement Method, 1994.

  33. Xu, J., Liang, P., and Zhang, T., Anal. Chim. Acta, 2007, vol. 597, no. 1, p. 1.

    Article  CAS  Google Scholar 

  34. Yao, J., Xu, H., Lili, L., Song, D., Cui, Y., Zhang, T., and Feng, Y., Anal. Chim. Acta, 2008, vol. 616, no. 1, p. 42.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nizhny Novgorod State University, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia

    V. A. Krylov & V. V. Nesterova

Authors
  1. V. A. Krylov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Nesterova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Krylov.

Additional information

Original Russian Text © V.A. Krylov, V.V. Nesterova, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 8, pp. 809–817.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krylov, V.A., Nesterova, V.V. Determination of o-phthalic acid esters in water by chromatography–mass spectrometry with emulsion dispersive liquid–liquid microextraction preconcentration. J Anal Chem 71, 777–785 (2016). https://doi.org/10.1134/S1061934816080098

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934816080098

Keywords

Search

Navigation