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Copper(II) Complexes with Mono- and Double Reduced Forms of 3,5-Di-tert-octyl-o-benzoquinone

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Abstract

Copper(II) complexes based on 3,5-di-tert-octyl-o-benzoquinone (3,5-t-Oc-Q) have been synthesized. Derivatives of the composition (3,5-t-Oc-SQ)2Cu (I), (3,5-t-Oc-Cat)Cu(Phen) (II), (3,5‑t-Oc-Cat)Cu(DPQ) (III), and (3,5-t-Oc-Cat)Cu(DPPZ) (IV) have been obtained and characterized, where 3,5-t-Oc-SQ is the radical anion of 3,5-di-tert-octyl-o-benzoquinone, 3,5-t-Oc-Cat is the 3,5-di-tert-octyl-o-benzoquinone dianion, Phen is phenanthroline, DPQ is dipyrido[3,2-d:2′,3′-f]quinoxaline, and DPPZ is dipyrido[3,2-a:2′,3′-c]phenazine. The molecular and crystal structures of complexes I and II have been determined by X-ray diffraction. The spectral characteristics of the synthesized copper(II) derivatives have been studied using electron absorption spectroscopy. Crystallographic data for compounds I and II have been deposited with the Cambridge Structural Database (nos. 2291614 and 2279045 for I and II, respectively).

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ACKNOWLEDGMENTS

The work was carried out using the equipment of the Center for Collective Use “Analytical Center of the G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences” (Nizhny Novgorod, Russia). X-ray diffraction data for complex II were obtained at the X-ray beam of the Belok station of the Kurchatov Synchrotron Radiation Center at the National Research Center “Kurchatov Institute” (Moscow, Russia).

Funding

This study was carried out within the framework of the State assignment of the G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    O. Yu. Trofimova, A. V. Maleeva, M. V. Arseniev, T. N. Kocherova, A. V. Cherkasov & A. V. Piskunov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. A. Yakushev

  3. National Research Center “Kurchatov Institute,”, 123182, Moscow, Russia

    P. V. Dorovatovski

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  1. O. Yu. Trofimova
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Trofimova, O.Y., Maleeva, A.V., Arseniev, M.V. et al. Copper(II) Complexes with Mono- and Double Reduced Forms of 3,5-Di-tert-octyl-o-benzoquinone. Russ. J. Inorg. Chem. (2024). https://doi.org/10.1134/S0036023623602945

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