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Effect of Dopants on the Functional Properties of Lithium-Rich Cathode Materials for Lithium-Ion Batteries

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

A comparative study was made of the effect of the dopant nature on the electrochemical performance of lithium-rich oxides of the general composition 0.5Li2MnO3⋅0.5LiMn0.33Ni0.33Co0.31M0.02O2 (M = Mg, Cr, Zr). The obtained materials were tested as cathodes in CR2032 coin-type cells versus lithium metal. The results of the study attested to the fact that the main role in the degradation of the material is played by the migration of transition metals, which depends on the dopant-oxygen binding energy. The do** with magnesium suppresses the phase transition, thus stabilizing the oxide structure. By the 110th cycle in the voltage range of 2.5–4.8 V at a current of 100 mA/g, the sample doped with magnesium retains 10% more specific energy than the initial oxide.

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ACKNOWLEDGMENTS

The studies in this work were made using the equipment of the Center for Shared Use of Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia.

Funding

This work was supported by the Russian Science Foundation (project no. 20-13-00423).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    L. S. Pechen, E. V. Makhonina, A. E. Medvedeva, Yu. A. Politov & I. L. Eremenko

  2. Ioffe Physicotechnical Institute, Russian Academy of Sciences, 194021, St. Petersburg, Russia

    A. M. Rumyantsev

  3. Peter the Great St. Petersburg Polytechnical University, 195251, St. Petersburg, Russia

    Yu. M. Koshtyal

  4. Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    A. S. Goloveshkin

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  1. L. S. Pechen
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  2. E. V. Makhonina
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  4. A. M. Rumyantsev
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Correspondence to L. S. Pechen or E. V. Makhonina.

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Translated by V. Glyanchenko

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Pechen, L.S., Makhonina, E.V., Medvedeva, A.E. et al. Effect of Dopants on the Functional Properties of Lithium-Rich Cathode Materials for Lithium-Ion Batteries. Russ. J. Inorg. Chem. 66, 777–788 (2021). https://doi.org/10.1134/S0036023621050144

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