Abstract
A one-step method for preparing composites based on calcium phosphates (CPs) and calcium silicates (CSs) with variable contents of the components is proposed. The combination of chemical analysis, X-ray powder diffraction, and simultaneous thermal analysis with mass-spectrometric detection (STA-MS) showed that the coprecipitation of salts from aqueous solutions yielded mixtures of poorly crystallized carbonate hydroxyapatite (CHA) and xonotlite with minor calcite. Scanning electron microscopy and low-temperature nitrogen adsorption showed that nanosized crystallites of these phases during crystallization were combined into mesoporous aggregates (the mean pore size was 6–11 nm) to form micrometer-sized bulk structures with a developed surface. Two-hour calcination of synthesis products at 1000°С yielded mixtures of well-crystallized Са10(РО4)6(ОН)2 and β-CaSiO3.
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Original Russian Text © A.P. Solonenko, A.I. Blesman, D.A. Polonyankin, V.A. Gorbunov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 8, pp. 953–960.
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Solonenko, A.P., Blesman, A.I., Polonyankin, D.A. et al. Synthesis of Calcium Phosphate and Calcium Silicate Composites. Russ. J. Inorg. Chem. 63, 993–1000 (2018). https://doi.org/10.1134/S0036023618080211
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DOI: https://doi.org/10.1134/S0036023618080211