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Model of the Lomonosov diamond deposit as a water–rock system: Migration Species, Groundwater Saturation with Rock-Forming and Ore Minerals, and Ecological Assessment of Water Quality

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Abstract

Thermodynamic numerical simulations were carried out to determine the principal simple and complex migration species of Ca, Mg, Na, K, Al, B, Mn, Mo, Sr, and U with Cl, OH, SO4−2, HCO3, and CO32− in waters at the Lomonosov diamond deposit and to estimate the saturation indexes with respect to kaolinite, Na- and Mg-montmorillonite, Mg- and Na-saponite, muscovite and paragonite, biotite, phlogopite, chromite, pyrite, plagioclase (anorthite, labradorite, and andesine), olivine (forsterite and fayalite), diopside, pyrope, gypsum, anhydrite, barite, magnesite, calcite, dolomite, talc, chrysotile, chlorite, goethite, quartz, microcline, and albite. The waters are proved not to be saturated with respect to the primary (hydrothermal) minerals. The saturation of certain water samples with uranophane suggests that this mineral is of secondary genesis. The ascent of highly mineralized deep waters shall result in the dissolution of minerals whose concentrations are near the saturation ones. To maintain the ecological standards of the discharged waters, they should be diluted and/or purified by adsorbing dissolved U on a reducing reactive barrier.

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References

  • M. V. Borisov and Yu. V. Shvarov, Thermodynamics of Geochemical Processes (Mosk, Gos, Univ., Moscow, 1992) [in Russian].

    Google Scholar 

  • D. Brookins, Eh-pH Diagrams for Geochemistry (Department of Geology University of New Mexico, New Mexico, 1987).

    Google Scholar 

  • R. M. Garrels and C. L. Christ, Solutions, Minerals, and Equilibria (Harper and Row, New York, 1965). Geological Evolution and Self-Organization of the Water–Rock System. Volume 5. Water–rock System in the Earth’s Crust: Interaction, Kinetics, Equilibrium, and Simulation, Ed. by S. L. Shvartsev, (SO RAN, Novosibirsk, 2005) [in Russian].

  • S. R. Krainov, B. N. Ryzhenko, and V. M. Shvets, Geochemistry of Groundwaters. Theoretical, Applied, and Ecological Aspects (Nauka, Moscow, 2012) [in Russian].

    Google Scholar 

  • S. R. Krainov, V. I. Sobolev, and V. I. Solomin, “Fe-bearing groundwaters of Russia and geochemical problems of iron removal,” Razv. Okhr. Nedr, No. 5, 14–20 (2001).

    Google Scholar 

  • A. I. Malov, “Primary composition of Vendian rocks of the Mezen Syneclise,” Dokl. Earth Sci. 392, 968–972 (2003)

    Google Scholar 

  • T. Pačes, “Chemical characteristics and equilibration in the natural water–felsic rock–CO2 system,” Geochim. Cosmochim. Acta 36, 217–240 (1972).

    Article  Google Scholar 

  • B. N. Ryzhenko, Thermodynamics of Equilibria in Hydrothermal Solutions (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  • Yu. V. Shvarov, “Algorithmization of the numeric equilibrium modeling of dynamic geochemical processes,” Geochem. Int. 37 (6), 571–576 (1999).

    Google Scholar 

  • V. L. Tauson, “Systematic of processes of trace element uptake by real mineral crystals,” Geochem. Int. 43 (2), 184–190 (2005).

    Google Scholar 

  • V. P. Zverev, A. I. Malov, and I. A. Kostikov, Geochemical state of groundwaters from active water exchange zone in the Lomonosov diamond deposit area, Geoekologiya, No. 2, 298–303 (2005).

    Google Scholar 

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Correspondence to A. I. Malov.

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Original Russian Text © A.I. Malov, E.S. Sidkina, B.N. Ryzhenko, 2017, published in Geokhimiya, 2017, No. 12, pp. 1128–1140.

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Malov, A.I., Sidkina, E.S. & Ryzhenko, B.N. Model of the Lomonosov diamond deposit as a water–rock system: Migration Species, Groundwater Saturation with Rock-Forming and Ore Minerals, and Ecological Assessment of Water Quality. Geochem. Int. 55, 1118–1130 (2017). https://doi.org/10.1134/S0016702917090038

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  • DOI: https://doi.org/10.1134/S0016702917090038

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