Abstract
Solid electrolytes for all-solid-state lithium batteries are excellent in terms of stability, and their performance has been improved through many studies. However, due to the interfacial reaction with lithium and sold electrolyte, there is a problem that the performance is deteriorated when used for a long time. In this study, the charge/discharge evaluation of more than 50 cycles was conducted and we analyzed the change Ti4+ to Ti3+ in the solid electrolyte using X-ray photoelectron spectroscopy. Finally, it was confirmed that the performance of the LiNbO3-coated solid electrolyte did not decrease even after long-term use.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-021-00110-y/MediaObjects/43207_2021_110_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-021-00110-y/MediaObjects/43207_2021_110_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-021-00110-y/MediaObjects/43207_2021_110_Fig3_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-021-00110-y/MediaObjects/43207_2021_110_Fig4_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-021-00110-y/MediaObjects/43207_2021_110_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-021-00110-y/MediaObjects/43207_2021_110_Fig6_HTML.png)
Similar content being viewed by others
References
J.M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries. Nature 414, 359–367 (2001)
J.W. Fergus, Ceramic and polymeric solid electrolytes for lithium-ion batteries. J. Power Sour. 195(15), 4554–4569 (2010)
P. Knauth, Inorganic solid Li ion conductors: an overview. Solid State Ion 180(14–16), 911–916 (2009)
B. Kang, H. Park, S. Woo, M. Kang, A. Kim, Research progress of oxide solid electrolytes for next-generation Li-ion batteries. Ceramist 21(4), 349–365 (2018)
H. Nakano, K. Dokko, J. Sugaya, T. Yasukawa, T. Matsue, K. Kanamura, All-solid-state micro lithium-ion batteries fabricated by using dry polymer electrolyte with micro-phase separation structure. Electrochem. Commun. 9(8), 2013–2017 (2007)
F. Croce, F. Serraino Fiory, L. Persi, B. Scrosati, A high-rate, long-life, lithium nanocomposite polymer electrolyte battery. Electrochem. Solid-State Lett. 4(8), 121–123 (2001)
K. Takada, M. Tansho, I. Yanase, T. Inada, A. Kajiyama, M. Kouguchi, S. Kondo, M. Watanabe, Lithium ion conduction in LiTi2(PO4)3. Solid State Ion. 139(3–4), 241–247 (2001)
T. Abe, M. Ohtsuka, F. Sagane, Y. Iriyama, Z. Ogumi, Lithium-ion transfer at the interface between lithium-ion conductive ceramic electrolyte and liquid electrolyte-a key to enhancing the rate capability of lithium-ion batteries. J. Electrochem. Soc. 151(11), 2151–2154 (2004)
A. Hayashi, T. Konishi, K. Tadanaga, M. Tatsumisago, Formation of electrode–electrolyte interface by lithium insertion to SnS–P2S5 negative electrode materials in all-solid-state cells. Solid State Ion. 177(26–32), 2737–2740 (2006)
A. Atkin et al., Inorganic Chemistry, 4th edn. (OUP Oxford, Oxford, 2006), pp. 729–731
J. Ahn, S. Yoon, Amorphous lithium lanthanum titanate solid electrolyte grown on LiCoO2 cathode by pulsed laser deposition for all-solid-state lithium thin film microbattery. J. Korean Ceram. Soc. 41(8), 593–598 (2004)
T. Katoh, Y. Inda, M. Baba, Y. Rongbin, Lithium-ion conductive glass-ceramics with composition ratio control and their electrochemical characteristics. J. Ceram. Soc. Jpn. 118(12), 1159–1162 (2010)
P. Hartmamn, T. Leichtweiss, M. Busche, M. Schneider, M. Reich, J. Sann, P. Adelhelm, J. Janek, Degradation of NASICON-type materials in contact with lithium metal: formation of mixed conducting interphases (MCI) on solid electrolytes. J. Phys. Chem. C. 117, 21064–21074 (2013)
X. Li, Z. Wang, H. Lin, Y. Liu, Y. Min, F. Pan, Composite electrolytes of pyrrolidone-derivatives-PEO enable to enhance performance of all solid state lithium-ion batteries. Electrochimi. Acta 293, 25–29 (2019)
C. Tao, M. Gao, B. Yin, B. Li, Y. Huang, G. Xu, J. Bao, A promising TPU/PEO blend polymer electrolyte for all-solid-state lithium ion batteries. Electrochimi. Acta 257(10), 31–39 (2017)
Acknowledgements
This work was supported by a 2-Year Research Grant of Pusan National University
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Lim, HS., Liu, L., Lee, HJ. et al. The study on the interface characteristics of solid-state electrolyte. J. Korean Ceram. Soc. 58, 373–377 (2021). https://doi.org/10.1007/s43207-021-00110-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s43207-021-00110-y