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Wet spun cellulose nanocrystal/MXene hybrid fiber regulated by bridging effect for high electrochemical performance supercapacitor

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Abstract

Cellulose nanocrystals (CNC) possess a large aspect ratio, high crystallinity, good mechanical performance, and environmental friendliness. It can be used as a frame and spacer of two-dimensional conductive materials, which reduces the stacking effect and is conducive to enhancing the mechanical and electrochemical properties of two-dimensional materials. In this study, CNC-regulated MXene fibers with high electrical conductivity (344.67 S cm−1) were prepared by wet spinning. There is a strong bridging effect between CNC molecules rich in -OH and MXene molecules. This makes them have good compatibility and is good to the preparation of uniform dispersion solution. The prepared hybrid fibers exhibit superior electrochemical performance. In three-electrode system, the volumetric capacitance of the hybrid fibers reaches up to 885.6 F cm−3 (0.38 A cm−3). The energy density of symmetric supercapacitors assembled from CNC/MXene hybrid fibers is 11.30 mWh cm−3, and the power density is 11.40 mW cm−3. Furthermore, after 9000 charge-discharge cycles, the capacitance maintains 93% of its initial capacity, demonstrating outstanding cycle stability. It is believed that this study can provide a simple and effective method for the preparation of portable and wearable energy storage devices.

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Funding

This work was supported by the National Natural Science Foundation of China (32371809 and 32301530), the Open Project of State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Natural Science Foundation of Tian** (23JCZDJC00630), Young Elite Scientist Sponsorship Program by Cast (No.YESS20230242), and the China Postdoctoral Science Foundation (2023 M740563).

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Authors and Affiliations

  1. State Key Laboratory of Biobased Fiber Manufacturing Technology, Tian** Key Laboratory of Pulp and Paper, Tian** University of Science and Technology, Tian**, 300457, China

    Yaxuan Wang, Ting Xu, Junjie Qi, Aoran Wang, Kun Liu, Meng Zhang & Chuanling Si

  2. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China

    Ting Xu & Hengxue **ang

  3. College of Chemistry and Materials Engineering, Zhejiang A&F University, Province, Zhejiang, 311300, Hangzhou, China

    Weiwei Huan & Jie Li

  4. Zhejiang **chang Special Paper Co Ltd, Quzhou, 324400, China

    Ting Xu, Yu Meng & Shuhua Tong

  5. Robustnique Co. Ltd., Block C, Phase II, Pioneer Park, Lanyuan Road, Tian**, 300384, China

    Ting Xu, Chunyang Zheng & Chuanling Si

  6. Key Laboratory of Bio-based Material Science and Technology, Ministry of Education, Material Science and Engineering College, Northeast Forestry University, Harbin, 150040, China

    Ting Xu

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  1. Yaxuan Wang
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  2. Ting Xu
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  11. Hengxue **ang
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  12. Jie Li
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  13. Chuanling Si
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Contributions

Yaxuan Wang and Ting Xu made plans for the experiment. Yaxuan Wang, Junjie Qi, Aoran Wang, Kun Liu, Meng Zhang, Weiwei Huan completed the experiment, processed the data and drafted the manuscript. Ting Xu, Yu Meng, Shuhua Tong, Chunyang Zheng, Hengxue **ang, Jie Li, Chuanling Si supervised the manuscript. All authors discussed the experiments and results and have given approval for the final version of the manuscript.

Corresponding authors

Correspondence to Ting Xu, Hengxue **ang, Jie Li or Chuanling Si.

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Wang, Y., Xu, T., Qi, J. et al. Wet spun cellulose nanocrystal/MXene hybrid fiber regulated by bridging effect for high electrochemical performance supercapacitor. Adv Compos Hybrid Mater 7, 120 (2024). https://doi.org/10.1007/s42114-024-00918-2

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