Abstract
Two-dimensional (2D) mesoporous materials (2DMMs), defined as 2D nanosheets with randomly dispersed or orderly aligned mesopores of 2–50 nm, can synergistically combine the fascinating merits of 2D materials and mesoporous materials, while overcoming their intrinsic shortcomings, e.g., easy self-stacking of 2D materials and long ion transport paths in bulk mesoporous materials. These unique features enable fast ion diffusion, large specific surface area, and enriched adsorption/reaction sites, thus offering a promising solution for designing high-performance electrode/catalyst materials for next-generation energy storage and conversion devices (ESCDs). Herein, we review recent advances of state-of-the-art 2DMMs for high-efficiency ESCDs, focusing on two different configurations of in-plane mesoporous nanosheets and sandwich-like mesoporous heterostructures. Firstly, a brief introduction is given to highlighting the structural advantages (e.g., tailored chemical composition, sheet configuration, and mesopore geometry) and key roles (e.g., active materials and functional additives) of 2DMMs for high-performance ESCDs. Secondly, the chemical synthesis strategies of 2DMMs are summarized, including template-free, 2D-template, mesopore-template, and 2D mesopore dual-template methods. Thirdly, the wide applications of 2DMMs in advanced supercapacitors, rechargeable batteries, and electrocatalysis are discussed, enlightening their intrinsic structure–property relationships. Finally, the future challenges and perspectives of 2DMMs in energy-related fields are presented.
Graphical Abstract
In this review, the recent advances of 2DMMs (including in-plane mesoporous nanosheets and sandwich-like mesoporous heterostructures) for energy storage and conversion are systematically summarized.
Similar content being viewed by others
References
Chu, S., Majumdar, A.: Opportunities and challenges for a sustainable energy future. Nature 488, 294–303 (2012). https://doi.org/10.1038/nature11475
Mahlia, T.M.I., Saktisahdan, T.J., Jannifar, A., et al.: A review of available methods and development on energy storage; technology update. Renew. Sustain. Energy Rev. 33, 532–545 (2014). https://doi.org/10.1016/j.rser.2014.01.068
Aricò, A.S., Bruce, P., Scrosati, B., et al.: Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater. 4, 366–377 (2005). https://doi.org/10.1038/nmat1368
Sutherland, B.R.: Charging up stationary energy storage. Joule 3, 1–3 (2019). https://doi.org/10.1016/j.joule.2018.12.022
Wang, G.P., Zhang, L., Zhang, J.J.: A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797–828 (2012). https://doi.org/10.1039/c1cs15060j
Wang, J.H., Li, F., Zhu, F., et al.: Recent progress in micro-supercapacitor design, integration, and functionalization. Small Methods 3, 1800367 (2018). https://doi.org/10.1002/smtd.201800367
Tarascon, J.M., Armand, M.: Issues and challenges facing rechargeable lithium batteries. Nature 414, 359–367 (2001). https://doi.org/10.1038/35104644
Wang, Y.R., Chen, R.P., Chen, T., et al.: Emerging non-lithium ion batteries. Energy Storage Mater. 4, 103–129 (2016). https://doi.org/10.1016/j.ensm.2016.04.001
Zhang, Y.K., Lin, Y.X., Duan, T., et al.: Interfacial engineering of heterogeneous catalysts for electrocatalysis. Mater. Today 48, 115–134 (2021). https://doi.org/10.1016/j.mattod.2021.02.004
Geim, A.K.: Graphene: status and prospects. Science 324, 1530–1534 (2009). https://doi.org/10.1126/science.1158877
Allen, M.J., Tung, V.C., Kaner, R.B.: Honeycomb carbon: a review of graphene. Chem. Rev. 110, 132–145 (2010). https://doi.org/10.1021/cr900070d
Zhu, Y.W., Murali, S., Cai, W.W., et al.: Graphene and graphene oxide: synthesis, properties, and applications. Adv. Mater. 22, 3906–3924 (2010). https://doi.org/10.1002/adma.201001068
ten Elshof, J.E., Yuan, H.Y., Gonzalez Rodriguez, P.: Two-dimensional metal oxide and metal hydroxide nanosheets: synthesis, controlled assembly and applications in energy conversion and storage. Adv. Energy Mater. 6, 1600355 (2016). https://doi.org/10.1002/aenm.201600355
**ao, X., Song, H.B., Lin, S.Z., et al.: Scalable salt-templated synthesis of two-dimensional transition metal oxides. Nat. Commun. 7, 11296 (2016). https://doi.org/10.1038/ncomms11296
Manzeli, S., Ovchinnikov, D., Pasquier, D., et al.: 2D transition metal dichalcogenides. Nat. Rev. Mater. 2, 17033 (2017). https://doi.org/10.1038/natrevmats.2017.33
Lukatskaya, M.R., Mashtalir, O., Ren, C.E., et al.: Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science 341, 1502–1505 (2013). https://doi.org/10.1126/science.1241488
Ghidiu, M., Lukatskaya, M.R., Zhao, M.Q., et al.: Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature 516, 78–81 (2014). https://doi.org/10.1038/nature13970
Anasori, B., Lukatskaya, M.R., Gogotsi, Y.: 2D metal carbides and nitrides (MXenes) for energy storage. Nat. Rev. Mater. 2, 16098 (2017). https://doi.org/10.1038/natrevmats.2016.98
Batmunkh, M., Bat-Erdene, M., Shapter, J.G.: Phosphorene and phosphorene-based materials: prospects for future applications. Adv. Mater. 28, 8586–8617 (2016). https://doi.org/10.1002/adma.201602254
Pang, J.B., Bachmatiuk, A., Yin, Y., et al.: Applications of phosphorene and black phosphorus in energy conversion and storage devices. Adv. Energy Mater. 8, 1702093 (2018). https://doi.org/10.1002/aenm.201702093
Nakhanivej, P., Yu, X., Park, S.K., et al.: Revealing molecular-level surface redox sites of controllably oxidized black phosphorus nanosheets. Nat. Mater. 18, 156–162 (2019). https://doi.org/10.1038/s41563-018-0230-2
Pakdel, A., Bando, Y., Golberg, D.: Nano boron nitride flatland. Chem. Soc. Rev. 43, 934–959 (2014). https://doi.org/10.1039/c3cs60260e
Zhang, J., Tan, B.Y., Zhang, X., et al.: Atomically thin hexagonal boron nitride and its heterostructures. Adv. Mater. 33, 2000769 (2021). https://doi.org/10.1002/adma.202000769
**ong, M.Y., Rong, Q.M., Meng, H.M., et al.: Two-dimensional graphitic carbon nitride nanosheets for biosensing applications. Biosens. Bioelectron. 89, 212–223 (2017). https://doi.org/10.1016/j.bios.2016.03.043
Wang, Y.H., Liu, L.Z., Ma, T.Y., et al.: 2D graphitic carbon nitride for energy conversion and storage. Adv. Funct. Mater. 31, 2102540 (2021). https://doi.org/10.1002/adfm.202102540
Zhang, H.: Ultrathin two-dimensional nanomaterials. ACS Nano 9, 9451–9469 (2015). https://doi.org/10.1021/acsnano.5b05040
Zhang, X.Y., Hou, L.L., Ciesielski, A., et al.: 2D materials beyond graphene for high-performance energy storage applications. Adv. Energy Mater. 6, 1600671 (2016). https://doi.org/10.1002/aenm.201600671
Zhang, H., Cheng, H.M., Ye, P.D.: 2D nanomaterials: beyond graphene and transition metal dichalcogenides. Chem. Soc. Rev. 47, 6009–6012 (2018). https://doi.org/10.1039/c8cs90084a
Tan, C.L., Cao, X.H., Wu, X.J., et al.: Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 117, 6225–6331 (2017). https://doi.org/10.1021/acs.chemrev.6b00558
Li, W., Liu, J., Zhao, D.Y.: Mesoporous materials for energy conversion and storage devices. Nat. Rev. Mater. 1, 16023 (2016). https://doi.org/10.1038/natrevmats.2016.23
Zou, Y.D., Zhou, X.R., Ma, J.H., et al.: Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications. Chem. Soc. Rev. 49, 1173–1208 (2020). https://doi.org/10.1039/c9cs00334g
Zu, L.H., Zhang, W., Qu, L.B., et al.: Mesoporous materials for electrochemical energy storage and conversion. Adv. Energy Mater. 10, 2002152 (2020). https://doi.org/10.1002/aenm.202002152
Ai, Y., Li, W., Zhao, D.Y.: 2D mesoporous materials. Natl. Sci. Rev. 9, nwab108 (2022). https://doi.org/10.1093/nsr/nwab108
Huang, H.B., Shi, H.D., Das, P., et al.: The chemistry and promising applications of graphene and porous graphene materials. Adv. Funct. Mater. 30, 1909035 (2020). https://doi.org/10.1002/adfm.201909035
Han, S., Wu, D.Q., Li, S., et al.: Porous graphene materials for advanced electrochemical energy storage and conversion devices. Adv. Mater. 26, 849–864 (2014). https://doi.org/10.1002/adma.201303115
Bu, F.X., Zagho, M.M., Ibrahim, Y., et al.: Porous MXenes: synthesis, structures, and applications. Nano Today 30, 100803 (2020). https://doi.org/10.1016/j.nantod.2019.100803
He, Y.F., Zhuang, X.D., Lei, C.J., et al.: Porous carbon nanosheets: synthetic strategies and electrochemical energy related applications. Nano Today 24, 103–119 (2019). https://doi.org/10.1016/j.nantod.2018.12.004
Fang, Y., Lv, Y.Y., Che, R.C., et al.: Two-dimensional mesoporous carbon nanosheets and their derived graphene nanosheets: synthesis and efficient lithium ion storage. J. Am. Chem. Soc. 135, 1524–1530 (2013). https://doi.org/10.1021/ja310849c
Kim, H.-K., Bak, S.-M., Lee, S.W., et al.: Scalable fabrication of micron-scale graphene nanomeshes for high-performance supercapacitor applications. Energy Environ. Sci. 9, 1270–1281 (2016). https://doi.org/10.1039/C5EE03580E
**, X., Wu, D.Q., Han, L., et al.: Highly uniform carbon sheets with orientation-adjustable ordered mesopores. ACS Nano 12, 5436–5444 (2018). https://doi.org/10.1021/acsnano.8b00576
Peng, L.L., **ong, P., Ma, L., et al.: Holey two-dimensional transition metal oxide nanosheets for efficient energy storage. Nat. Commun. 8, 15139 (2017). https://doi.org/10.1038/ncomms15139
Lan, K., Liu, Y., Zhang, W., et al.: Uniform ordered two-dimensional mesoporous TiO2 nanosheets from hydrothermal-induced solvent-confined monomicelle assembly. J. Am. Chem. Soc. 140, 4135–4143 (2018). https://doi.org/10.1021/jacs.8b00909
Liu, L.L., Yang, X.Y., **e, Y.J., et al.: A universal lab-on-salt-particle approach to 2D single-layer ordered mesoporous materials. Adv. Mater. 32, 1906653 (2020). https://doi.org/10.1002/adma.201906653
Das, P., Fu, Q., Bao, X.H., et al.: Recent advances in the preparation, characterization, and applications of two-dimensional heterostructures for energy storage and conversion. J. Mater. Chem. A 6, 21747–21784 (2018). https://doi.org/10.1039/c8ta04618b
Wang, J., Chang, Z., Ding, B., et al.: Universal access to two-dimensional mesoporous heterostructures by micelle-directed interfacial assembly. Angew. Chem. Int. Ed. 59, 19570–19575 (2020). https://doi.org/10.1002/anie.202007063
Yang, S.B., Feng, X.L., Wang, L., et al.: Graphene-based nanosheets with a sandwich structure. Angew. Chem. 122, 4905–4909 (2010). https://doi.org/10.1002/ange.201001634
Yang, S.B., Feng, X.L., Wang, X.C., et al.: Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions. Angew. Chem. Int. Ed. 50, 5339–5343 (2011). https://doi.org/10.1002/anie.201100170
Huang, L., Hu, Z.M., **, H.R., et al.: Salt-assisted synthesis of 2D materials. Adv. Funct. Mater. 30, 1908486 (2020). https://doi.org/10.1002/adfm.201908486
Fuertes, A.B., Sevilla, M.: Hierarchical microporous/mesoporous carbon nanosheets for high-performance supercapacitors. ACS Appl. Mater. Interfaces 7, 4344–4353 (2015). https://doi.org/10.1021/am508794f
Wang, D.D., Shan, Z.Q., Tian, J.H., et al.: Understanding the formation of ultrathin mesoporous Li4Ti5O12 nanosheets and their application in high-rate, long-life lithium-ion anodes. Nanoscale 11, 520–531 (2019). https://doi.org/10.1039/c8nr07249c
**ao, Y.T., Tian, G.H., Li, W., et al.: Molecule self-assembly synthesis of porous few-layer carbon nitride for highly efficient photoredox catalysis. J. Am. Chem. Soc. 141, 2508–2515 (2019). https://doi.org/10.1021/jacs.8b12428
Tao, Y., Sui, Z.Y., Han, B.H.: Advanced porous graphene materials: from in-plane pore generation to energy storage applications. J. Mater. Chem. A 8, 6125–6143 (2020). https://doi.org/10.1039/d0ta00154f
Zheng, X.Y., Luo, J.Y., Lv, W., et al.: Two-dimensional porous carbon: synthesis and ion-transport properties. Adv. Mater. 27, 5388–5395 (2015). https://doi.org/10.1002/adma.201501452
Ren, C.E., Zhao, M.Q., Makaryan, T., et al.: Porous two-dimensional transition metal carbide (MXene) flakes for high-performance Li-ion storage. ChemElectroChem 3, 689–693 (2016). https://doi.org/10.1002/celc.201600059
AbdelHamid, A.A., Yu, Y., Yang, J.H., et al.: Generalized synthesis of metal oxide nanosheets and their application as Li-ion battery anodes. Adv. Mater. 29, 1701427 (2017). https://doi.org/10.1002/adma.201701427
Liu, S.H., Wang, F.X., Dong, R.H., et al.: Dual-template synthesis of 2D mesoporous polypyrrole nanosheets with controlled pore size. Adv. Mater. 28, 8365–8370 (2016). https://doi.org/10.1002/adma.201603036
Liu, S.H., Zhang, J., Dong, R.H., et al.: Two-dimensional mesoscale-ordered conducting polymers. Angew. Chem. Int. Ed. 55, 12516–12521 (2016). https://doi.org/10.1002/anie.201606988
Ai, Y., Han, Z.L., Jiang, X.L., et al.: General construction of 2D ordered mesoporous iron-based metal-organic nanomeshes. Small 16, 2002701 (2020). https://doi.org/10.1002/smll.202002701
Wei, F.C., Wang, T.T., Jiang, X.L., et al.: Controllably engineering mesoporous surface and dimensionality of SnO2 toward high-performance CO2 electroreduction. Adv. Funct. Mater. 30, 2002092 (2020). https://doi.org/10.1002/adfm.202002092
Qin, J.Q., Wang, S., Zhou, F., et al.: 2D mesoporous MnO2 nanosheets for high-energy asymmetric micro-supercapacitors in water-in-salt gel electrolyte. Energy Storage Mater. 18, 397–404 (2019). https://doi.org/10.1016/j.ensm.2018.12.022
Li, B.S., **, B.J., Feng, Z.Y., et al.: Hierarchical porous nanosheets constructed by graphene-coated, interconnected TiO2 nanoparticles for ultrafast sodium storage. Adv. Mater. 30, 1705788 (2018). https://doi.org/10.1002/adma.201705788
Fan, Z.J., Liu, Y., Yan, J., et al.: Template-directed synthesis of pillared-porous carbon nanosheet architectures: high-performance electrode materials for supercapacitors. Adv. Energy Mater. 2, 419–424 (2012). https://doi.org/10.1002/aenm.201100654
Zhuang, X.D., Zhang, F., Wu, D.Q., et al.: Graphene coupled Schiff-base porous polymers: towards nitrogen-enriched porous carbon nanosheets with ultrahigh electrochemical capacity. Adv. Mater. 26, 3081–3086 (2014). https://doi.org/10.1002/adma.201305040
Yuan, K., Zhuang, X.D., Fu, H.Y., et al.: Two-dimensional core-shelled porous hybrids as highly efficient catalysts for the oxygen reduction reaction. Angew. Chem. 128, 6972–6977 (2016). https://doi.org/10.1002/ange.201600850
Wang, Q., Yan, J., Fan, Z.J.: Nitrogen-doped sandwich-like porous carbon nanosheets for high volumetric performance supercapacitors. Electrochim. Acta 146, 548–555 (2014). https://doi.org/10.1016/j.electacta.2014.09.036
Wei, J., Hu, Y.X., Liang, Y., et al.: Nitrogen-doped nanoporous carbon/graphene nano-sandwiches: synthesis and application for efficient oxygen reduction. Adv. Funct. Mater. 25, 5768–5777 (2015). https://doi.org/10.1002/adfm.201502311
Wu, Z., Zhang, X.B.: N,O-codoped porous carbon nanosheets for capacitors with ultra-high capacitance. Sci. China Mater. 59, 547–557 (2016). https://doi.org/10.1007/s40843-016-5067-4
Liang, Y.R., **ong, X., Xu, Z.J., et al.: Ultrathin 2D mesoporous TiO2/rGO heterostructure for high-performance lithium storage. Small 16, 2000030 (2020). https://doi.org/10.1002/smll.202000030
Tong, Z.Q., Liu, S.K., Zhou, Y., et al.: Rapid redox kinetics in uniform sandwich-structured mesoporous Nb2O5/graphene/mesoporous Nb2O5 nanosheets for high-performance sodium-ion supercapacitors. Energy Storage Mater. 13, 223–232 (2018). https://doi.org/10.1016/j.ensm.2017.12.005
Bai, J.W., Zhong, X., Jiang, S., et al.: Graphene nanomesh. Nat. Nanotechnol. 5, 190–194 (2010). https://doi.org/10.1038/nnano.2010.8
Jiang, B., Guo, Y.N., Kim, J., et al.: Mesoporous metallic iridium nanosheets. J. Am. Chem. Soc. 140, 12434–12441 (2018). https://doi.org/10.1021/jacs.8b05206
Jiang, B., Kim, J., Guo, Y.N., et al.: Efficient oxygen evolution on mesoporous IrOx nanosheets. Catal. Sci. Technol. 9, 3697–3702 (2019). https://doi.org/10.1039/c9cy00302a
Qin, M.L., Li, S.M., Zhao, Y.Z., et al.: Unprecedented synthesis of holey 2D layered double hydroxide nanomesh for enhanced oxygen evolution. Adv. Energy Mater. 9, 1803060 (2019). https://doi.org/10.1002/aenm.201803060
Li, Y.Q., Liu, Y.W., Li, J., et al.: A centimeter scale self-standing two-dimensional ultra-thin mesoporous platinum nanosheet. Mater. Horiz. 7, 489–494 (2020). https://doi.org/10.1039/c9mh01142k
Liu, R.L., Wan, L., Liu, S.Q., et al.: An interface-induced co-assembly approach towards ordered mesoporous carbon/graphene aerogel for high-performance supercapacitors. Adv. Funct. Mater. 25, 526–533 (2015). https://doi.org/10.1002/adfm.201403280
Yang, S.B., Feng, X.L., Müllen, K.: Sandwich-like, graphene-based titania nanosheets with high surface area for fast lithium storage. Adv. Mater. 23, 3575–3579 (2011). https://doi.org/10.1002/adma.201101599
Lan, K., **a, Y., Wang, R.C., et al.: Confined interfacial monomicelle assembly for precisely controlled coating of single-layered titania mesopores. Matter 1, 527–538 (2019). https://doi.org/10.1016/j.matt.2019.03.003
Yang, S., Yue, W.B., Zhu, J., et al.: Graphene-based mesoporous SnO2 with enhanced electrochemical performance for lithium-ion batteries. Adv. Funct. Mater. 23, 3570–3576 (2013). https://doi.org/10.1002/adfm.201203286
Wang, L., Bi, X.F., Yang, S.B.: Partially single-crystalline mesoporous Nb2O5 nanosheets in between graphene for ultrafast sodium storage. Adv. Mater. 28, 7672–7679 (2016). https://doi.org/10.1002/adma.201601723
Liu, S.H., Gordiichuk, P., Wu, Z.S., et al.: Patterning two-dimensional free-standing surfaces with mesoporous conducting polymers. Nat. Commun. 6, 8817 (2015). https://doi.org/10.1038/ncomms9817
Tian, H., Qin, J.Q., Hou, D., et al.: General interfacial self-assembly engineering for patterning two-dimensional polymers with cylindrical mesopores on graphene. Angew. Chem. 131, 10279–10284 (2019). https://doi.org/10.1002/ange.201903684
Shi, H.D., Qin, J.Q., Huang, K., et al.: A two-dimensional mesoporous polypyrrole-graphene oxide heterostructure as a dual-functional ion redistributor for dendrite-free lithium metal anodes. Angew. Chem. Int. Ed. 132, 12245–12251 (2020). https://doi.org/10.1002/ange.202004284
Wang, Q., Yan, J., Fan, Z.J., et al.: Mesoporous polyaniline film on ultra-thin graphene sheets for high performance supercapacitors. J. Power Sources 247, 197–203 (2014). https://doi.org/10.1016/j.jpowsour.2013.08.076
Liu, Z.Y., Liu, S.H., Dong, R.H., et al.: High power in-plane micro-supercapacitors based on mesoporous polyaniline patterned graphene. Small 13, 1603388 (2017). https://doi.org/10.1002/smll.201603388
Wei, W., Liang, H.W., Parvez, K., et al.: Nitrogen-doped carbon nanosheets with size-defined mesopores as highly efficient metal-free catalyst for the oxygen reduction reaction. Angew. Chem. Int. Ed. 53, 1570–1574 (2014). https://doi.org/10.1002/anie.201307319
Wang, N., Tian, H., Zhu, S.Y., et al.: Two-dimensional nitrogen-doped mesoporous carbon/graphene nanocomposites from the self-assembly of block copolymer micelles in solution. Chin. J. Polym. Sci. 36, 266–272 (2018). https://doi.org/10.1007/s10118-018-2091-1
Zhang, L.L., Wang, T., Gao, T.N., et al.: Multistage self-assembly strategy: designed synthesis of N-doped mesoporous carbon with high and controllable pyridine N content for ultrahigh surface-area-normalized capacitance. CCS Chem. 3, 870–881 (2021). https://doi.org/10.31635/ccschem.020.202000233
Shi, Y.Z., Li, B., Zhu, Q., et al.: MXene-based mesoporous nanosheets toward superior lithium ion conductors. Adv. Energy Mater. 10, 1903534 (2020). https://doi.org/10.1002/aenm.201903534
Fang, Y., Lv, Y.Y., Gong, F., et al.: Synthesis of 2D-mesoporous-carbon/MoS2 heterostructures with well-defined interfaces for high-performance lithium-ion batteries. Adv. Mater. 28, 9385–9390 (2016). https://doi.org/10.1002/adma.201602210
Tian, H., Zhu, S.Y., Xu, F.G., et al.: Growth of 2D mesoporous polyaniline with controlled pore structures on ultrathin MoS2 nanosheets by block copolymer self-assembly in solution. ACS Appl. Mater. Interfaces 9, 43975–43982 (2017). https://doi.org/10.1021/acsami.7b13666
Lan, K., Wei, Q.L., Wang, R.C., et al.: Two-dimensional mesoporous heterostructure delivering superior pseudocapacitive sodium storage via bottom-up monomicelle assembly. J. Am. Chem. Soc. 141, 16755–16762 (2019). https://doi.org/10.1021/jacs.9b06962
Ji, X.L., Lee, K.T., Nazar, L.F.: A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries. Nat. Mater. 8, 500–506 (2009). https://doi.org/10.1038/nmat2460
**ao, Z.B., Li, Z.L., Meng, X.P., et al.: MXene-engineered lithium–sulfur batteries. J. Mater. Chem. A 7, 22730–22743 (2019). https://doi.org/10.1039/c9ta08600e
Zhang, C.F., Cui, L.F., Abdolhosseinzadeh, S., et al.: Two-dimensional MXenes for lithium-sulfur batteries. InfoMat 2, 613–638 (2020). https://doi.org/10.1002/inf2.12080
Wang, Y.G., Song, Y.F., **a, Y.Y.: Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem. Soc. Rev. 45, 5925–5950 (2016). https://doi.org/10.1039/c5cs00580a
Simon, P., Gogotsi, Y.: Materials for electrochemical capacitors. Nat. Mater. 7, 845–854 (2008). https://doi.org/10.1038/nmat2297
Simon, P., Gogotsi, Y.: Perspectives for electrochemical capacitors and related devices. Nat. Mater. 19, 1151–1163 (2020). https://doi.org/10.1038/s41563-020-0747-z
Zhang, L.L., Zhao, X.S.: Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38, 2520–2531 (2009). https://doi.org/10.1039/b813846j
Wei, L., Yushin, G.: Nanostructured activated carbons from natural precursors for electrical double layer capacitors. Nano Energy 1, 552–565 (2012). https://doi.org/10.1016/j.nanoen.2012.05.002
Xu, Y.X., Lin, Z.Y., Zhong, X., et al.: Holey graphene frameworks for highly efficient capacitive energy storage. Nat. Commun. 5, 4554 (2014). https://doi.org/10.1038/ncomms5554
Xu, Y.X., Chen, C.Y., Zhao, Z.P., et al.: Solution processable holey graphene oxide and its derived macrostructures for high-performance supercapacitors. Nano Lett. 15, 4605–4610 (2015). https://doi.org/10.1021/acs.nanolett.5b01212
Chodankar, N.R., Pham, H.D., Nanjundan, A.K., et al.: True meaning of pseudocapacitors and their performance metrics: asymmetric versus hybrid supercapacitors. Small 16, 2002806 (2020). https://doi.org/10.1002/smll.202002806
Mathis, T.S., Kurra, N., Wang, X.H., et al.: Energy storage data reporting in perspective: guidelines for interpreting the performance of electrochemical energy storage systems. Adv. Energy Mater. 9, 1902007 (2019). https://doi.org/10.1002/aenm.201902007
Zhang, P.F., Qiao, Z.A., Zhang, Z.Y., et al.: Mesoporous graphene-like carbon sheet: high-power supercapacitor and outstanding catalyst support. J. Mater. Chem. A 2, 12262–12269 (2014). https://doi.org/10.1039/c4ta02307b
Zhu, S.Y., Tian, H., Wang, N., et al.: Patterning graphene surfaces with iron-oxide-embedded mesoporous polypyrrole and derived N-doped carbon of tunable pore size. Small 14, 1702755 (2018). https://doi.org/10.1002/smll.201702755
Qin, J.Q., Zhou, F., **ao, H., et al.: Mesoporous polypyrrole-based graphene nanosheets anchoring redox polyoxometalate for all-solid-state micro-supercapacitors with enhanced volumetric capacitance. Sci. China Mater. 61, 233–242 (2018). https://doi.org/10.1007/s40843-017-9132-8
Shown, I., Ganguly, A., Chen, L.C., et al.: Conducting polymer-based flexible supercapacitor. Energy Sci. Eng. 3, 2–26 (2015). https://doi.org/10.1002/ese3.50
Wang, Y.Q., Ding, Y., Guo, X.L., et al.: Conductive polymers for stretchable supercapacitors. Nano Res. 12, 1978–1987 (2019). https://doi.org/10.1007/s12274-019-2296-9
Zheng, S.H., Tang, X.Y., Wu, Z.S., et al.: Arbitrary-shaped graphene-based planar sandwich supercapacitors on one substrate with enhanced flexibility and integration. ACS Nano 11, 2171–2179 (2017). https://doi.org/10.1021/acsnano.6b08435
Das, P., Shi, X.Y., Fu, Q., et al.: Substrate-free and shapeless planar micro-supercapacitors. Adv. Funct. Mater. 30, 1908758 (2020). https://doi.org/10.1002/adfm.201908758
Liu, C.F., Liu, Y.C., Yi, T., et al.: Carbon materials for high-voltage supercapacitors. Carbon 145, 529–548 (2019). https://doi.org/10.1016/j.carbon.2018.12.009
Shi, X.Y., Zheng, S.H., Wu, Z.S., et al.: Recent advances of graphene-based materials for high-performance and new-concept supercapacitors. J. Energy Chem. 27, 25–42 (2018). https://doi.org/10.1016/j.jechem.2017.09.034
Qin, J.Q., Das, P., Zheng, S.H., et al.: A perspective on two-dimensional materials for planar micro-supercapacitors. APL Mater. 7, 090902 (2019). https://doi.org/10.1063/1.5113940
Zhang, P.P., Wang, F.X., Yu, M.H., et al.: Two-dimensional materials for miniaturized energy storage devices: from individual devices to smart integrated systems. Chem. Soc. Rev. 47, 7426–7451 (2018). https://doi.org/10.1039/c8cs00561c
Sumboja, A., Liu, J.W., Zheng, W.G., et al.: Electrochemical energy storage devices for wearable technology: a rationale for materials selection and cell design. Chem. Soc. Rev. 47, 5919–5945 (2018). https://doi.org/10.1039/C8CS00237A
Yao, L., Wu, Q., Zhang, P.X., et al.: Scalable 2D hierarchical porous carbon nanosheets for flexible supercapacitors with ultrahigh energy density. Adv. Mater. 30, 1706054 (2018). https://doi.org/10.1002/adma.201706054
Qi, D.P., Liu, Y., Liu, Z.Y., et al.: Design of architectures and materials in in-plane micro-supercapacitors: current status and future challenges. Adv. Mater. 29, 1602802 (2017). https://doi.org/10.1002/adma.201602802
Zheng, S.H., Shi, X.Y., Das, P., et al.: The road towards planar microbatteries and micro-supercapacitors: from 2D to 3D device geometries. Adv. Mater. 31, 1900583 (2019). https://doi.org/10.1002/adma.201900583
Wu, Z.S., Parvez, K., Li, S., et al.: Alternating stacked graphene-conducting polymer compact films with ultrahigh areal and volumetric capacitances for high-energy micro-supercapacitors. Adv. Mater. 27, 4054–4061 (2015). https://doi.org/10.1002/adma.201501643
Zheng, S.H., Wu, Z.S., Wang, S., et al.: Graphene-based materials for high-voltage and high-energy asymmetric supercapacitors. Energy Storage Mater. 6, 70–97 (2017). https://doi.org/10.1016/j.ensm.2016.10.003
Shi, X.Y., Pei, S.F., Zhou, F., et al.: Ultrahigh-voltage integrated micro-supercapacitors with designable shapes and superior flexibility. Energy Environ. Sci. 12, 1534–1541 (2019). https://doi.org/10.1039/c8ee02924e
Nomura, K., Nishihara, H., Kobayashi, N., et al.: 4.4 V supercapacitors based on super-stable mesoporous carbon sheet made of edge-free graphene walls. Energy Environ. Sci. 12, 1542–1549 (2019). https://doi.org/10.1039/c8ee03184c
Zhong, C., Deng, Y.D., Hu, W.B., et al.: A review of electrolyte materials and compositions for electrochemical supercapacitors. Chem. Soc. Rev. 44, 7484–7539 (2015). https://doi.org/10.1039/c5cs00303b
Zang, X.N., Shen, C.W., Sanghadasa, M., et al.: High-voltage supercapacitors based on aqueous electrolytes. ChemElectroChem 6, 976–988 (2019). https://doi.org/10.1002/celc.201801225
Shi, X.Y., Wu, Z.S., Qin, J.Q., et al.: Graphene-based linear tandem micro-supercapacitors with metal-free current collectors and high-voltage output. Adv. Mater. 29, 1703034 (2017). https://doi.org/10.1002/adma.201703034
Gao, J.M., Qin, J.Q., Chang, J.Y., et al.: NH3 sensor based on 2D wormlike polypyrrole/graphene heterostructures for a self-powered integrated system. ACS Appl. Mater. Interfaces 12, 38674–38681 (2020). https://doi.org/10.1021/acsami.0c10794
Shi, X.Y., Wu, Z.S., Bao, X.H.: Recent advancements and perspective of high-performance printed power sources with multiple form factors. Electrochem. Energy Rev. 3, 581–612 (2020). https://doi.org/10.1007/s41918-020-00071-6
Zheng, S.H., Wang, H., Das, P., et al.: Multitasking MXene inks enable high-performance printable microelectrochemical energy storage devices for all-flexible self-powered integrated systems. Adv. Mater. 33, 2005449 (2021). https://doi.org/10.1002/adma.202005449
Ma, J.X., Zheng, S.H., Cao, Y.X., et al.: Aqueous MXene/PH1000 hybrid inks for inkjet-printing micro-supercapacitors with unprecedented volumetric capacitance and modular self-powered microelectronics. Adv. Energy Mater. 11, 2100746 (2021). https://doi.org/10.1002/aenm.202100746
Qin, J.Q., Gao, J.M., Shi, X.Y., et al.: Hierarchical ordered dual-mesoporous polypyrrole/graphene nanosheets as bi-functional active materials for high-performance planar integrated system of micro-supercapacitor and gas sensor. Adv. Funct. Mater. 30, 1909756 (2020). https://doi.org/10.1002/adfm.201909756
Etacheri, V., Marom, R., Elazari, R., et al.: Challenges in the development of advanced Li-ion batteries: a review. Energy Environ. Sci. 4, 3243 (2011). https://doi.org/10.1039/c1ee01598b
Dunn, B., Kamath, H., Tarascon, J.M.: Electrical energy storage for the grid: a battery of choices. Science 334, 928–935 (2011). https://doi.org/10.1126/science.1212741
Goodenough, J.B., Park, K.S.: The Li-ion rechargeable battery: a perspective. J. Am. Chem. Soc. 135, 1167–1176 (2013). https://doi.org/10.1021/ja3091438
Bruce, P., Scrosati, B., Tarascon, J.M.: Nanomaterials for rechargeable lithium batteries. Angew. Chem. Int. Ed. 47, 2930–2946 (2008). https://doi.org/10.1002/anie.200702505
Goodenough, J.B., Kim, Y.: Challenges for rechargeable Li batteries. Chem. Mater. 22, 587–603 (2010). https://doi.org/10.1021/cm901452z
Zuo, X.X., Zhu, J., Müller-Buschbaum, P., et al.: Silicon based lithium-ion battery anodes: a chronicle perspective review. Nano Energy 31, 113–143 (2017). https://doi.org/10.1016/j.nanoen.2016.11.013
Eftekhari, A.: Low voltage anode materials for lithium-ion batteries. Energy Storage Mater. 7, 157–180 (2017). https://doi.org/10.1016/j.ensm.2017.01.009
Yao, W.Q., Chen, J., Zhan, L., et al.: Two-dimensional porous sandwich-like C/Si-graphene-Si/C nanosheets for superior lithium storage. ACS Appl. Mater. Interfaces 9, 39371–39379 (2017). https://doi.org/10.1021/acsami.7b11721
Palomares, V., Serras, P., Villaluenga, I., et al.: Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ. Sci. 5, 5884 (2012). https://doi.org/10.1039/c2ee02781j
Yabuuchi, N., Kubota, K., Dahbi, M., et al.: Research development on sodium-ion batteries. Chem. Rev. 114, 11636–11682 (2014). https://doi.org/10.1021/cr500192f
Muñoz-Márquez, M.Á., Saurel, D., Gómez-Cámer, J.L., et al.: Na-ion batteries for large scale applications: a review on anode materials and solid electrolyte interphase formation. Adv. Energy Mater. 7, 1700463 (2017). https://doi.org/10.1002/aenm.201700463
Wu, Y., Yu, Y.: 2D material as anode for sodium ion batteries: recent progress and perspectives. Energy Storage Mater. 16, 323–343 (2019). https://doi.org/10.1016/j.ensm.2018.05.026
Zhang, W., Tian, Y., He, H.L., et al.: Recent advances in the synthesis of hierarchically mesoporous TiO2 materials for energy and environmental applications. Natl. Sci. Rev. 7, 1702–1725 (2020). https://doi.org/10.1093/nsr/nwaa021
Cheng, X.B., Zhang, R., Zhao, C.Z., et al.: Toward safe lithium metal anode in rechargeable batteries: a review. Chem. Rev. 117, 10403–10473 (2017). https://doi.org/10.1021/acs.chemrev.7b00115
Li, S., Jiang, M.W., ** high-performance lithium metal anode in liquid electrolytes: challenges and progress. Adv. Mater. 30, 1706375 (2018). https://doi.org/10.1002/adma.201706375
Yang, H.J., Guo, C., Naveed, A., et al.: Recent progress and perspective on lithium metal anode protection. Energy Storage Mater. 14, 199–221 (2018). https://doi.org/10.1016/j.ensm.2018.03.001
Guo, W., Fu, Y.Z.: A perspective on energy densities of rechargeable Li–S batteries and alternative sulfur-based cathode materials. Energy Environ. Mater. 1, 20–27 (2018). https://doi.org/10.1002/eem2.12003
Seh, Z.W., Sun, Y.M., Zhang, Q.F., et al.: Designing high-energy lithium–sulfur batteries. Chem. Soc. Rev. 45, 5605–5634 (2016). https://doi.org/10.1039/c5cs00410a
Liu, X., Huang, J.Q., Zhang, Q., et al.: Nanostructured metal oxides and sulfides for lithium–sulfur batteries. Adv. Mater. 29, 1601759 (2017). https://doi.org/10.1002/adma.201601759
Peng, H.J., Huang, J.Q., Cheng, X.B., et al.: Review on high-loading and high-energy lithium–sulfur batteries. Adv. Energy Mater. 7, 1700260 (2017). https://doi.org/10.1002/aenm.201700260
Qiu, P.P., Yao, Y., Li, W., et al.: Sub-nanometric manganous oxide clusters in nitrogen doped mesoporous carbon nanosheets for high-performance lithium–sulfur batteries. Nano Lett. 21, 700–708 (2020). https://doi.org/10.1021/acs.nanolett.0c04322
Zhang, C.Y., Wang, A.X., Zhang, J.H., et al.: 2D materials for lithium/sodium metal anodes. Adv. Energy Mater. 8, 1802833 (2018). https://doi.org/10.1002/aenm.201802833
Li, G.X., Liu, Z., Huang, Q.Q., et al.: Stable metal battery anodes enabled by polyethylenimine sponge hosts by way of electrokinetic effects. Nat. Energy 3, 1076–1083 (2018). https://doi.org/10.1038/s41560-018-0276-z
Liu, W., Lin, D.C., Pei, A., et al.: Stabilizing lithium metal anodes by uniform Li-ion flux distribution in nanochannel confinement. J. Am. Chem. Soc. 138, 15443–15450 (2016). https://doi.org/10.1021/jacs.6b08730
Zhou, Y.G., Zhang, X., Ding, Y., et al.: Redistributing Li-ion flux by parallelly aligned holey nanosheets for dendrite-free Li metal anodes. Adv. Mater. 32, 2003920 (2020). https://doi.org/10.1002/adma.202003920
Qin, J.Q., Shi, H.D., Huang, K., et al.: Achieving stable Na metal cycling via polydopamine/multilayer graphene coating of a polypropylene separator. Nat. Commun. 12, 5786 (2021). https://doi.org/10.1038/s41467-021-26032-1
Chen, R.J., Qu, W.J., Guo, X., et al.: The pursuit of solid-state electrolytes for lithium batteries: from comprehensive insight to emerging horizons. Mater. Horiz. 3, 487–516 (2016). https://doi.org/10.1039/c6mh00218h
Jiang, C., Li, H.Q., Wang, C.L.: Recent progress in solid-state electrolytes for alkali-ion batteries. Sci. Bull. 62, 1473–1490 (2017). https://doi.org/10.1016/j.scib.2017.10.011
Manthiram, A., Yu, X.W., Wang, S.F.: Lithium battery chemistries enabled by solid-state electrolytes. Nat. Rev. Mater. 2, 16103 (2017). https://doi.org/10.1038/natrevmats.2016.103
Li, M.T., Zhu, W.S., Zhang, P.F., et al.: Graphene-analogues boron nitride nanosheets confining ionic liquids: a high-performance quasi-liquid solid electrolyte. Small 12, 3535–3542 (2016). https://doi.org/10.1002/smll.201600358
Tang, C., Titirici, M.M., Zhang, Q.: A review of nanocarbons in energy electrocatalysis: multifunctional substrates and highly active sites. J. Energy Chem. 26, 1077–1093 (2017). https://doi.org/10.1016/j.jechem.2017.08.008
Chia, X.Y., Pumera, M.: Characteristics and performance of two-dimensional materials for electrocatalysis. Nat. Catal. 1, 909–921 (2018). https://doi.org/10.1038/s41929-018-0181-7
Tian, X.Y., Zhao, P.C., Sheng, W.C.: Hydrogen evolution and oxidation: mechanistic studies and material advances. Adv. Mater. 31, 1808066 (2019). https://doi.org/10.1002/adma.201808066
Yao, J.D., Huang, W.J., Fang, W., et al.: Promoting electrocatalytic hydrogen evolution reaction and oxygen evolution reaction by fields: effects of electric field, magnetic field, strain, and light. Small Methods 4, 2000494 (2020). https://doi.org/10.1002/smtd.202000494
Mohiuddin, M., Zavabeti, A., Haque, F., et al.: Synthesis of two-dimensional hematite and iron phosphide for hydrogen evolution. J. Mater. Chem. A 8, 2789–2797 (2020). https://doi.org/10.1039/c9ta11945k
Chen, W.F., Muckerman, J.T., Fujita, E.: Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts. Chem. Commun. 49, 8896–8909 (2013). https://doi.org/10.1039/c3cc44076a
Miao, M., Pan, J., He, T., et al.: Molybdenum carbide-based electrocatalysts for hydrogen evolution reaction. Chem. A Eur. J. 23, 10947–10961 (2017). https://doi.org/10.1002/chem.201701064
Hou, D., Zhu, S.Y., Tian, H., et al.: Two-dimensional sandwich-structured mesoporous Mo2C/carbon/graphene nanohybrids for efficient hydrogen production electrocatalysts. ACS Appl. Mater. Interfaces 10, 40800–40807 (2018). https://doi.org/10.1021/acsami.8b15250
Guo, S.J., Zhang, S., Sun, S.H.: Tuning nanoparticle catalysis for the oxygen reduction reaction. Angew. Chem. Int. Ed. 52, 8526–8544 (2013). https://doi.org/10.1002/anie.201207186
Jiang, R.Y., Tung, S.O., Tang, Z., et al.: A review of core–shell nanostructured electrocatalysts for oxygen reduction reaction. Energy Storage Mater. 12, 260–276 (2018). https://doi.org/10.1016/j.ensm.2017.11.005
Liu, X., Zhang, G.Y., Wang, L., et al.: Structural design strategy and active site regulation of high-efficient bifunctional oxygen reaction electrocatalysts for Zn−air battery. Small 17, 2006766 (2021). https://doi.org/10.1002/smll.202006766
Tan, H.B., Zhao, Y.J., **a, W., et al.: Phosphorus- and nitrogen-doped carbon nanosheets constructed with monolayered mesoporous architectures. Chem. Mater. 32, 4248–4256 (2020). https://doi.org/10.1021/acs.chemmater.0c00731
Song, F., Bai, L.C., Moysiadou, A., et al.: Transition metal oxides as electrocatalysts for the oxygen evolution reaction in alkaline solutions: an application-inspired renaissance. J. Am. Chem. Soc. 140, 7748–7759 (2018). https://doi.org/10.1021/jacs.8b04546
Shi, Z.P., Wang, X., Ge, J.J., et al.: Fundamental understanding of the acidic oxygen evolution reaction: mechanism study and state-of-the-art catalysts. Nanoscale 12, 13249–13275 (2020). https://doi.org/10.1039/d0nr02410d
Li, Y.G., Wang, Y., Lu, J.M., et al.: 2D intrinsically defective RuO2/graphene heterostructures as all-pH efficient oxygen evolving electrocatalysts with unprecedented activity. Nano Energy 78, 105185 (2020). https://doi.org/10.1016/j.nanoen.2020.105185
Wu, Z.P., Lu, X.F., Zang, S.Q., et al.: Non-noble-metal-based electrocatalysts toward the oxygen evolution reaction. Adv. Funct. Mater. 30, 1910274 (2020). https://doi.org/10.1002/adfm.201910274
Wang, Z.L., Li, C.L., Yamauchi, Y.: Nanostructured nonprecious metal catalysts for electrochemical reduction of carbon dioxide. Nano Today 11, 373–391 (2016). https://doi.org/10.1016/j.nantod.2016.05.007
Birdja, Y.Y., Pérez-Gallent, E., Figueiredo, M.C., et al.: Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels. Nat. Energy 4, 732–745 (2019). https://doi.org/10.1038/s41560-019-0450-y
Zhang, Y., Li, L.B., Guo, S.X., et al.: Two-dimensional electrocatalysts for efficient reduction of carbon dioxide. ChemSusChem 13, 59–77 (2020). https://doi.org/10.1002/cssc.201901794
Zhang, J.C., Cai, W.Z., Hu, F.X., et al.: Recent advances in single atom catalysts for the electrochemical carbon dioxide reduction reaction. Chem. Sci. 12, 6800–6819 (2021). https://doi.org/10.1039/d1sc01375k
Li, F.W., Chen, L., Knowles, G.P., et al.: Hierarchical mesoporous SnO2 nanosheets on carbon cloth: a robust and flexible electrocatalyst for CO2 reduction with high efficiency and selectivity. Angew. Chem. Int. Ed. 56, 505–509 (2017). https://doi.org/10.1002/anie.201608279
Han, N., Wang, Y.Y., Deng, J., et al.: Self-templated synthesis of hierarchical mesoporous SnO2 nanosheets for selective CO2 reduction. J. Mater. Chem. A 7, 1267–1272 (2019). https://doi.org/10.1039/c8ta10959a
Zhao, S.L., Qin, Y., Guo, T., et al.: SnS nanoparticles grown on Sn-atom-modified N,S-codoped mesoporous carbon nanosheets as electrocatalysts for CO2 reduction to formate. ACS Appl. Nano Mater. 4, 2257–2264 (2021). https://doi.org/10.1021/acsanm.0c03361
Yang, H., Han, N., Deng, J., et al.: Selective CO2 reduction on 2D mesoporous Bi nanosheets. Adv. Energy Mater. 8, 1801536 (2018). https://doi.org/10.1002/aenm.201801536
Sun, H.T., Mei, L., Liang, J.F., et al.: Three-dimensional holey-graphene/niobia composite architectures for ultrahigh-rate energy storage. Science 356, 599–604 (2017). https://doi.org/10.1126/science.aam5852
Li, W., Li, M., Wang, X.Q., et al.: An in situ TEM microreactor for real-time nanomorphology & physicochemical parameters interrelated characterization. Nano Today 35, 100932 (2020). https://doi.org/10.1016/j.nantod.2020.100932
Li, H.Y., Guo, S.H., Zhou, H.S.: In-situ/operando characterization techniques in lithium-ion batteries and beyond. J. Energy Chem. 59, 191–211 (2021). https://doi.org/10.1016/j.jechem.2020.11.020
Su, X.L., Ye, J.L., Zhu, Y.W.: Advances in in situ characterizations of electrode materials for better supercapacitors. J. Energy Chem. 54, 242–253 (2021). https://doi.org/10.1016/j.jechem.2020.05.055
Acknowledgements
Jieqiong Qin, Zhi Yang, and Feifei **ng contributed equally to this work. The authors acknowledge the National Natural Science Foundation of China (Nos. 22125903, 51872283, 22109040), Dalian Innovation Support Plan for High Level Talents (2019RT09), DICP (ZZBS201802 and I202032), Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS (DNL201912 and DNL201915, DNL202016, DNL202019), Top-Notch Talent Program of Henan Agricultural University (30500947), the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy (YLU-DNL Fund 2021002, 2021009).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Ethics Statement
The study does not involve human or animal subjects and/or tissue.
Conflict of interest
The authors declare no conflict of interest.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Qin, J., Yang, Z., **ng, F. et al. Two-Dimensional Mesoporous Materials for Energy Storage and Conversion: Current Status, Chemical Synthesis and Challenging Perspectives. Electrochem. Energy Rev. 6, 9 (2023). https://doi.org/10.1007/s41918-022-00177-z
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s41918-022-00177-z