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Full-temperature covered switching material with triple optic-dielectric states in a lead-free hybrid perovskite

全温度覆盖的三重介电及荧光响应无铅杂化钙钛矿开关材料

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Abstract

Optic-electric responsive materials have attracted much attention for their applications in temperature-sensing, actuators, and memory switches. However, it is a challenge to integrate various functions to form multifunctional responsive materials. As molecule-based hybrid materials usually consist of organic and inorganic components, the introduction of multiple functions can be achieved through structural construction. Thus far, even though full-temperature cover is required for device applications, full-temperature covered multi-switchable hybrid materials have rarely been successfully synthesized. Herein, the dynamic [(CH3)3NOH]+ cation and luminous center Mn(II) were introduced to form a hybrid material [(CH3)3NOH][MnCl3], showing multiple temperature-responsive behaviors. Upon temperature change, it exhibits multi-state dielectric switching response and intensity or peak shift response of luminous in full-temperature range (low, room, and high temperatures). These responsive behaviors are triggered by the motion or reorientation of [(CH3)3NOH]+ cations and inorganic framework. Overall, the switchable photoelectric material has potential applications in multiple encrypted storage and sensor devices.

摘要

光电响应材料在温度传感、执行器、存储和功能开关领域的应用引起了广泛关注. 然而将各种功能整合形成多功能响应材料仍具有挑战性. 分子基杂化材料通常是有机和无机成分的杂化混合体. 因此, 可以通过结构构建将多个功能复合在一个材料中. 虽然器件应用需要全温度覆盖, 迄今为止却很少能成功地合成全温度覆盖的多开关响应杂化材料. 在本文中, 动态[(CH3)3NOH]+阳离子和发光中心Mn(II)形成杂化材料[(CH3)3NOH][MnCl3], 该材料在温度刺激下显示出多重响应行为. 温度变化时, [(CH3)3NOH][MnCl3]在全温度范围(低温、室温和高温)下表现出多重介电态及发光**度或峰值变化的开关响应. 这些响应行为是由[(CH3)3NOH]+阳离子和无机骨架的运动或重新取向而触发的. 总之, 这种光电开关材料在多重加密存储和传感设备中具有潜在的应用.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (21991141), the Natural Science Foundation of Zhejiang Province (LZ20B010001), and Zhejiang Normal University.

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Authors and Affiliations

  1. Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nan**g, 211189, China

    Tie Zhang  (张铁), Lulu Chu  (储璐璐), Zhixu Zhang  (张志旭), Jie Li  (**杰), **** Shi  (石萍萍), Qiong Ye  (叶琼) & Da-Wei Fu  (付大伟)

  2. Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, **hua, 321004, China

    Tie Zhang  (张铁), Wanying Zhang  (张婉莹) & Da-Wei Fu  (付大伟)

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  1. Tie Zhang  (张铁)
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  2. Lulu Chu  (储璐璐)
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  3. Zhixu Zhang  (张志旭)
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  4. Jie Li  (**杰)
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  5. Wanying Zhang  (张婉莹)
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  6. **** Shi  (石萍萍)
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  7. Qiong Ye  (叶琼)
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Contributions

Zhang T conceived the experiment, analyzed the data and wrote the paper. Zhang Z and Li J conducted the material characterizations and data analyses. Chu L conducted the material synthesis. Zhang W and Shi P provided suggestions to the final version of the manuscript. Fu DW and Ye Q guided and supervised this work. All authors contributed to the manuscript.

Corresponding authors

Correspondence to Qiong Ye  (叶琼) or Da-Wei Fu  (付大伟).

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Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary information

Supporting data are available in the online version of the paper.

Tie Zhang is a PhD candidate in the group of Prof. Da-Wei Fu at the Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nan**g. His research interest focuses on the molecular perovskite material design with stimulus-response.

Qiong Ye was born in January 1982. She earned her PhD in 2007 from Nan**g University and then held a postdoctoral fellowship of Japan Society for the Promotion of Science (JSPS) in Japan over the next two years. Now she is a professor of Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics in Southeast University, with the main research interests in dielectric, ferroelectric, and ferroelastic materials.

Dawei Fu was born in November 1980. He received his PhD degree from Southeast University in 2012. Since 2013, he has been a professor and doctoral tutor at Southeast University. His current research interest includes designing highperformance molecular dielectric/ferroelectric materials and ferroelectric electroluminescent devices.

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Zhang, T., Chu, L., Zhang, Z. et al. Full-temperature covered switching material with triple optic-dielectric states in a lead-free hybrid perovskite. Sci. China Mater. 63, 2281–2288 (2020). https://doi.org/10.1007/s40843-020-1325-4

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