Abstract
This paper presents characterization studies of flash point, kinematic viscosity and refractive index for several biodiesel/ diesel blends. Biodiesel is produced from soybean, corn, olive, canola, almond, grape and peanut oils. Regression equations are presented to estimate the kinematic viscosity, refractive index and flash point of the studied biodiesel and their blends with diesel fossil fuel as a function of the blend composition. Moreover, as viscosity and refractive index measurements are simple, fast and require very small volume of samples, a correlation study for the blends is conducted to estimate the flash point from these two properties. It is shown that when kinematic viscosity and refractive index are both used for the estimation of the blends flash point, the \({R}^{2}\) values are higher than those found using simple correlations.
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References
Agarwal AK (2007) Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines. Prog Energy Combust Sci 33(3):233–271
Romano SD, Sorichetti PA (2010) Dielectric spectroscopy in biodiesel production and characterization. Springer, Berlin
Alviso D, Rolon J, Scouflaire P, Darabiha N (2015) Experimental and numerical studies of biodiesel combustion mechanisms using a laminar counterflow spray premixed flame. Fuel 153:154–165
Alviso D, Krauch F, Roman R, Maldonado H, dos Santos RG, Rolon J, Darabiha N (2017) Development of a diesel–biodiesel–ethanol combined chemical scheme and analysis of reactions pathways. Fuel 191:411–426
Alviso D, Costa MW, Backer L, Pepiot P, Darabiha N, dos Santos RG (2020) Chemical kinetic mechanism for diesel/biodiesel/ethanol surrogates using n-decane/methyl-decanoate/ethanol blends. J Braz Soc Mech Sci Eng 42(2):100
Astm d 6751 (2012) standard specification for biodiesel fuel blend stock (b100) for middle distillate fuels
En 14214 (2009) automotive fuels, fatty acid methyl esters (fame) for diesel engines, requirements and test methods
Phoon LY, Mustaffa AA, Hashim H, Mat R (2015) Flash point prediction of tailor-made green diesel blends using unifac-based models. Chem Eng Trans 45:1153–1158
Silitonga A, Masjuki H, Mahlia T, Ong H, Chong W, Boosroh M (2013) Overview properties of biodiesel diesel blends from edible and non-edible feedstock. Renew Sustain Energy Rev 22:346–360
Saxena P, Jawale S, Joshipura MH (2013) A review on prediction of properties of biodiesel and blends of biodiesel. Procedia Eng 51:395–402
Knothe G (2005) Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Process Technol 86(10):1059–1070
Althouse PM, Hunter GW, Triebold HO (1947) Refractive indices of the methyl, propyl, and isopropyl esters of the c6–c18 saturated fatty acids for various temperatures between 20 and 45 c. J Am Oil Chem Soc 24(8):257–259
Santos RC, Vieira RB, Valentini A (2013) Monitoring the conversion of soybean oil to methyl or ethyl esters using the refractive index with correlation gas chromatography. Microchem J 109:46–50
Wazilewski WT, Bariccatti RA, Martins GI, Secco D, de Souza SNM, Rosa HA, Chaves LI (2013) Study of the methyl crambe (crambe abyssinica hochst) and soybean biodiesel oxidative stability. Ind Crops Prod 43:207–212
Alviso D, Zárate C, Krauch F, Artana G, Rolón JC (2019) Light refraction effects in counterflow non-premixed flames. Fuel 236:1423–1431
Merchan-Merchan W, McCollam S, Pugliese JFC (2015) Soot formation in diffusion oxygen-enhanced biodiesel flames. Fuel 156:129–141
Das R, Sharma SK (2017) Fuel characterization and performance parameters analysis of diesel engine using blends of palm biodiesel and tyre pyrolysis oil. J Braz Soc Mech Sci Eng 39(5):1491–1497
Sajjadi B, Raman AAA, Arandiyan H (2016) A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: composition, specifications and prediction models. Renew Sustain Energy Rev 63:62–92
Zaharin M, Abdullah N, Najafi G, Sharudin H, Yusaf T (2017) Effects of physicochemical properties of biodiesel fuel blends with alcohol on diesel engine performance and exhaust emissions: a review. Renew Sustain Energy Rev 79:475–493
Bhuiya M, Rasul M, Khan M, Ashwath N, Azad A, Hazrat M (2016) Prospects of 2nd generation biodiesel as a sustainable fuel-part 2: properties, performance and emission characteristics. Renew Sustain Energy Rev 55:1129–1146
Sakthivel R, Ramesh K, Purnachandran R, Shameer PM (2018) A review on the properties, performance and emission aspects of the third generation biodiesels. Renew Sustain Energy Rev 82:2970–2992
Wakil M, Kalam M, Masjuki HH, Atabani A, Fattah IR (2015) Influence of biodiesel blending on physicochemical properties and importance of mathematical model for predicting the properties of biodiesel blend. Energy Convers Manag 94:51–67
Venkateswarlu K, Murthy B, Subbarao V (2016) An experimental investigation to study the effect of fuel additives and exhaust gas recirculation on combustion and emissions of diesel–biodiesel blends. J Braz Soc Mech Sci Eng 38(3):735–744
Júnior LCSS, Ferreira VP, da Silva JA, Torres EA, Pepe IM (2018) Oxidized biodiesel as a cetane improver for diesel–biodiesel–ethanol mixtures in a vehicle engine. J Braz Soc Mech Sci Eng 40(2):79
Atabani A, Mofijur M, Masjuki H, Badruddin IA, Kalam M, Chong W (2014) Effect of croton megalocarpus, calophyllum inophyllum, moringa oleifera, palm and coconut biodiesel-diesel blending on their physico-chemical properties. Ind Crops Prod 60:130–137
Mofijur M, Masjuki H, Kalam M, Atabani A, Arbab M, Cheng S, Gouk S (2014) Properties and use of moringa oleifera biodiesel and diesel fuel blends in a multi-cylinder diesel engine. Energy Convers Manag 82:169–176
Salaheldeen M, Aroua M, Mariod A, Cheng SF, Abdelrahman MA, Atabani A (2015) Physicochemical characterization and thermal behavior of biodiesel and biodiesel–diesel blends derived from crude moringa peregrina seed oil. Energy Convers Manag 92:535–542
Abu-Hamdeh NH, Alnefaie KA (2015) A comparative study of almond and palm oils as two bio-diesel fuels for diesel engine in terms of emissions and performance. Fuel 150:318–324
Song J, Wei Q (2016) Fuel properties and exhaust emissions of low blending rate soybean oil methyl esters blended with diesel fuel. Energy Sour Part A Recov Util Environ Effects 38(10):1311–1317
Benea B (2016) The influence of the biofuel blends on the energetic and ecological performances of the diesel engine. In: IOP conference series: materials science and engineering, IOP Publishing, vol 147, p 012120
Corach J, Colman M, Sorichetti PA, Romano SD (2017) Kinematic viscosity of soybean biodiesel and diesel fossil fuel blends: estimation from permittivity and temperature. Fuel 207:488–492
Ge JC, Kim HY, Yoon SK, Choi NJ (2018) Reducing volatile organic compound emissions from diesel engines using canola oil biodiesel fuel and blends. Fuel 218:266–274
Nita I, Geacai S, Iulian O (2011) Measurements and correlations of physico-chemical properties to composition of pseudo-binary mixtures with biodiesel. Renew Energy 36(12):3417–3423
Geacai S, Iulian O, Nita I (2015) Measurement, correlation and prediction of biodiesel blends viscosity. Fuel 143:268–274
Cunha CL, Luna AS, Oliveira RC, Xavier GM, Paredes ML, Torres AR (2017) Predicting the properties of biodiesel and its blends using mid-ft-ir spectroscopy and first-order multivariate calibration. Fuel 204:185–194
Colman M, Sorichetti P, Romano S (2018) Refractive index of biodiesel–diesel blends from effective polarizability and density. Fuel 211:130–139
Constantino AF, Cubides-Román DC, dos Santos RB, Queiroz LH Jr, Colnago LA, Neto ÁC, Barbosa LL, Romão W, de Castro EV, Filgueiras PR et al (2019) Determination of physicochemical properties of biodiesel and blends using low-field nmr and multivariate calibration. Fuel 237:745–752
Anawe P, Adewale FJ (2018) Data on physico-chemical, performance, combustion and emission characteristics of persea americana biodiesel and its blends on direct-injection, compression-ignition engines. Data Brief 21:1533–1540
Liaquat A, Masjuki HH, Kalam M, Fattah IR, Hazrat M, Varman M, Mofijur M, Shahabuddin M (2013) Effect of coconut biodiesel blended fuels on engine performance and emission characteristics. Procedia Eng 56:583–590
Habibullah M, Masjuki HH, Kalam M, Ashraful A, Al Mahmud K, Mobarak H (2014) Comparative study of properties and engine performance using blend of palm and coconut biodiesel. In: Applied mechanics and materials, Trans Tech Publ, vol 663, pp 13–18
Habibullah M, Masjuki HH, Kalam M, Fattah IR, Ashraful A, Mobarak H (2014) Biodiesel production and performance evaluation of coconut, palm and their combined blend with diesel in a single-cylinder diesel engine. Energy Convers Manag 87:250–257
Habibullah M, Rizwanul Fattah I, Masjuki H, Kalam M (2015) Effects of palm-coconut biodiesel blends on the performance and emission of a single-cylinder diesel engine. Energy Fuels 29(2):734–743
Woo C, Kook S, Hawkes ER, Rogers PL, Marquis C (2016) Dependency of engine combustion on blending ratio variations of lipase-catalysed coconut oil biodiesel and petroleum diesel. Fuel 169:146–157
Santos AG, Caldeira VP, Souza LD, Oliveira DS, Araujo AS, Luz GE (2016) Study of the thermal stability by thermogravimetry for oil, biodiesel and blend (b10) of different oilseeds. J Therm Anal Calorim 123(3):2021–2028
Vijayaraj K, Sathiyagnanam A (2014) Experimental investigation of methyl ester of cotton seed oil blend with diesel on ci engine. Am J Appl Sci 11(10):1819
Atabani A, Mofijur M, Masjuki H, Badruddin IA, Chong W, Cheng S, Gouk S (2014) A study of production and characterization of manketti (ricinodendron rautonemii) methyl ester and its blends as a potential biodiesel feedstock. Biofuel Res J 1(4):139–146
El-Araby R, Amin A, Morsi AE, El-Ibiari N, El-Diwani G (2018) Study on the characteristics of palm oil–biodiesel–diesel fuel blend. Egypt J Pet 27(2):187–194. https://doi.org/10.1016/j.ejpe.2017.03.002
Khalid A, Tamaldin N, Jaat M, Ali M, Manshoor B, Zaman I (2013) Impacts of biodiesel storage duration on fuel properties and emissions. Procedia Eng 68:225–230
Silitonga A, Ong H, Mahlia T, Masjuki H, Chong W (2013) Characterization and production of ceiba pentandra biodiesel and its blends. Fuel 108:855–858
Mangus M, Kiani F, Mattson J, Tabakh D, Petka J, Depcik C, Peltier E, Stagg-Williams S (2015) Investigating the compression ignition combustion of multiple biodiesel/ulsd (ultra-low sulfur diesel) blends via common-rail injection. Energy 89:932–945
Kwanchareon P, Luengnaruemitchai A, Jai-In S (2007) Solubility of a diesel-biodiesel-ethanol blend, its fuel properties, and its emission characteristics from diesel engine. Fuel 86(7–8):1053–1061
Shahabuddin M, Kalam M, Masjuki H, Bhuiya M, Mofijur M (2012) An experimental investigation into biodiesel stability by means of oxidation and property determination. Energy 44(1):616–622
Mejía J, Salgado N, Orrego C (2013) Effect of blends of diesel and palm-castor biodiesels on viscosity, cloud point and flash point. Ind Crops Prod 43:791–797
mat Yasin MH, Mamat R, Yusop AF, Rahim R, Aziz A, Shah LA (2013) Fuel physical characteristics of biodiesel blend fuels with alcohol as additives. Procedia Eng 53:701–706
Ahmed S, Hassan MH, Kalam MA, Rahman SA, Abedin MJ, Shahir A (2014) An experimental investigation of biodiesel production, characterization, engine performance, emission and noise of brassica juncea methyl ester and its blends. J Clean Prod 79:74–81
Mofijur M, Masjuki HH, Kalam M, Atabani AE, Fattah IR, Mobarak H (2014) Comparative evaluation of performance and emission characteristics of moringa oleifera and palm oil based biodiesel in a diesel engine. Ind Crops Prod 53:78–84
Fattah IR, Masjuki H, Kalam M, Mofijur M, Abedin M (2014) Effect of antioxidant on the performance and emission characteristics of a diesel engine fueled with palm biodiesel blends. Energy Convers Manag 79:265–272
Sanjid A, Masjuki H, Kalam M, Abedin M, Rahman SA (2014) Experimental investigation of mustard biodiesel blend properties, performance, exhaust emission and noise in an unmodified diesel engine. APCBEE Procedia 10:149–153
Imtenan S, Masjuki H, Varman M, Kalam M, Arbab M, Sajjad H, Rahman SA (2014) Impact of oxygenated additives to palm and jatropha biodiesel blends in the context of performance and emissions characteristics of a light-duty diesel engine. Energy Convers Manag 83:149–158
Abedin M, Masjuki H, Kalam M, Sanjid A, Rahman SA, Fattah IR (2014) Performance, emissions, and heat losses of palm and jatropha biodiesel blends in a diesel engine. Ind Crops Prod 59:96–104
Sanjid A, Masjuki H, Kalam M, Rahman SA, Abedin M, Palash S (2014) Production of palm and jatropha based biodiesel and investigation of palm-jatropha combined blend properties, performance, exhaust emission and noise in an unmodified diesel engine. J Clean Prod 65:295–303
Monirul I, Masjuki H, Kalam M, Mosarof M, Zulkifli N, Teoh Y, How H (2016) Assessment of performance, emission and combustion characteristics of palm, jatropha and calophyllum inophyllum biodiesel blends. Fuel 181:985–995
Rajagopal K, Bindu C, Prasad R, Ahmad A (2016) The effect of fatty acid profiles of biodiesel on key fuel properties of some biodiesels and blends. Energy Sour Part A Recov Util Environ Effects 38(11):1582–1590
Mattos RA, Bastos FA, Tubino M (2015) Correlation between the composition and flash point of diesel–biodiesel blends. J Braz Chem Soc 26(2):393–395
Bukkarapu KR, Chakravarthy D (2017) Direct relationships to calculate properties of sunflower biodiesel and diesel blends. Int J Mech Eng Technol (IJMET) 8(4):255–265
Raj Bukkarapu K (2017) Comparative study of different biodiesel–diesel blends. Int J Ambient Energy 40:1–9
Al-Hamamre Z, Al-Salaymeh A (2014) Physical properties of (jojoba oil+ biodiesel),(jojoba oil+ diesel) and (biodiesel+ diesel) blends. Fuel 123:175–188
Yatish K, Lalithamba H, Suresh R, Omkaresh B (2018) Synthesis of biodiesel from garcinia gummi-gutta, terminalia belerica and aegle marmelos seed oil and investigation of fuel properties. Biofuels 9(1):121–128
Hajlari SA, Najafi B, Ardabili SF (2019) Castor oil, a source for biodiesel production and its impact on the diesel engine performance. Renew Energy Focus 28:1–10. https://doi.org/10.1016/j.ref.2018.09.006
Gokdogan O, Eryilmaz T, Kadir Yesilyurt M (2015) Thermophysical properties of castor oil (ricinus communis l.) biodiesel and its blends. CT&F-Ciencia, Tecnología y Futuro 6(1):95–128
Mofijur M, Masjuki H, Kalam M, Atabani A (2013) Evaluation of biodiesel blending, engine performance and emissions characteristics of jatropha curcas methyl ester: Malaysian perspective. Energy 55:879–887
Chen LY, Chen YH, Hung YS, Chiang TH, Tsai CH (2013) Fuel properties and combustion characteristics of jatropha oil biodiesel–diesel blends. J Taiwan Inst Chem Eng 44(2):214–220
Liaquat A, Masjuki H, Kalam M, Varman M, Hazrat M, Shahabuddin M, Mofijur M (2012) Application of blend fuels in a diesel engine. Energy Procedia 14:1124–1133
Palash S, Kalam M, Masjuki H, Arbab M, Masum B, Sanjid A (2014) Impacts of nox reducing antioxidant additive on performance and emissions of a multi-cylinder diesel engine fueled with jatropha biodiesel blends. Energy Convers Manag 77:577–585
Imdadul H, Rashed M, Shahin M, Masjuki H, Kalam M, Kamruzzaman M, Rashedul H (2017) Quality improvement of biodiesel blends using different promising fuel additives to reduce fuel consumption and no emission from ci engine. Energy Convers Manag 138:327–337
Sahoo P, Das L (2009) Process optimization for biodiesel production from jatropha, karanja and polanga oils. Fuel 88(9):1588–1594
Sahu G, Das L, Sharma B, Naik S (2011) Pilot plant study on biodiesel production from karanja and jatropha oils. Asia-Pac J Chem Eng 6(1):38–43
Gautam K, Gupta N, Sharma D (2014) Physical characterization and comparison of biodiesel produced from edible and non-edible oils of madhuca indica (mahua), pongamia pinnata (karanja), and sesamum indicum (til) plant oilseeds. Biomass Convers Biorefinery 4(3):193–200
Lahane S, Subramanian K (2015) Effect of different percentages of biodiesel-diesel blends on injection, spray, combustion, performance, and emission characteristics of a diesel engine. Fuel 139:537–545
Jaichandar S, Annamalai K (2015) Emission and combustion characteristics of pongamia oil methyl ester and its diesel blends in a ci engine. Energy Sour Part A Recov Util Environ Effects 37(14):1473–1478
Gopal KN, Karupparaj RT (2015) Effect of pongamia biodiesel on emission and combustion characteristics of di compression ignition engine. Ain Shams Eng J 6(1):297–305
Sahoo P, Das L, Babu M, Naik S (2007) Biodiesel development from high acid value polanga seed oil and performance evaluation in a ci engine. Fuel 86(3):448–454
Ong HC, Masjuki H, Mahlia T, Silitonga A, Chong W, Leong K (2014) Optimization of biodiesel production and engine performance from high free fatty acid calophyllum inophyllum oil in ci diesel engine. Energy Convers Manag 81:30–40
Fattah IR, Masjuki H, Kalam M, Wakil M, Ashraful A, Shahir SA (2014) Experimental investigation of performance and regulated emissions of a diesel engine with calophyllum inophyllum biodiesel blends accompanied by oxidation inhibitors. Energy Convers Manag 83:232–240
Serin H, Ozcanli M, Kemal Gokce M, Tuccar G (2013) Biodiesel production from tea seed (camellia sinensis) oil and its blends with diesel fuel. Int J Green Energy 10(4):370–377
Candeia R, Silva M, Carvalho Filho J, Brasilino M, Bicudo T, Santos I, Souza A (2009) Influence of soybean biodiesel content on basic properties of biodiesel–diesel blends. Fuel 88(4):738–743
Shehata M, Attia AM, Razek SA (2015) Corn and soybean biodiesel blends as alternative fuels for diesel engine at different injection pressures. Fuel 161:49–58
Soriano NU Jr, Narani A (2012) Evaluation of biodiesel derived from camelina sativa oil. J Am Oil Chem Soc 89(5):917–923
Qi D, Chen H, Geng L, Bian YZ (2010) Experimental studies on the combustion characteristics and performance of a direct injection engine fueled with biodiesel/diesel blends. Energy Convers Manag 51(12):2985–2992
Gülüm M, Bilgin A (2015) Density, flash point and heating value variations of corn oil biodiesel-diesel fuel blends. Fuel Process Technol 134:456–464
Gülüm M, Bilgin A (2018) Regression models for predicting some important fuel properties of corn and hazelnut oil biodiesel–diesel fuel blends. In: Exergetic, energetic and environmental dimensions, Elsevier, pp 829–850
Mert G, Atilla B (2018) Effects of temperature and biodiesel fraction on dynamic viscosities of commercially available diesel fuels and its blends with the highest methyl ester yield corn oil biodisel produced by using koh. In: Exergy for A better environment and improved sustainability 2, Springer, pp 83–102
Fadhil AB, Mohammed HM (2018) Co-solvent transesterification of bitter almond oil into biodiesel: optimization of variables and characterization of biodiesel. Transport 33(3):686–698
Soloiu V, Weaver J, Ochieng H, Vlcek B, Butts C, Jansons M (2013) Evaluation of peanut fatty acid methyl ester sprays, combustion, and emissions, for use in an indirect injection diesel engine. Energy Fuels 27(5):2608–2618
Corach J, Sorichetti P, Romano S (2012) Electrical properties of mixtures of fatty acid methyl esters from different vegetable oils. Int J Hydrog Energy 37(19):14735–14739
Corach J, Sorichetti P, Romano S (2014) Electrical properties of vegetable oils between 20 hz and 2 mhz. Int J Hydrog Energy 39(16):8754–8758
Corach J, Sorichetti PA, Romano SD (2015) Electrical and ultrasonic properties of vegetable oils and biodiesel. Fuel 139:466–471
Astm d445-17 (2017) standard test method for kinematic viscosity of transparent and opaque liquids (and calculation of dynamic viscosity), astm international, west conshohocken, pa
Astm d1218-12(2016) (2016) standard test method for refractive index and refractivedispersion of hydrocarbon liquids, west conshohocken, pa: Astm international
Astm d93 (2003) standard test methods for flash point by pensky–martens closed cup tester
Folayan AJ, Anawe PAL, Aladejare AE, Ayeni AO (2019) Experimental investigation of the effect of fatty acids configuration, chain length, branching and degree of unsaturation on biodiesel fuel properties obtained from lauric oils, high-oleic and high-linoleic vegetable oil biomass. Energy Rep 5:793–806
Alviso D, Artana G, Duriez T (2020) Prediction of biodiesel physico-chemical properties from its fatty acid composition using genetic programming. Fuel 264:116844
En 14103 (2011) Fat and oil derivatives—fatty acid methyl esters (fame)—determination of ester and linolenic acid methyl ester contents
En 14105 (2011) Fat and oil derivatives—fatty acid methyl esters (fame)—determination of free and total glycerol and mono-, di-, triglyceride contents
Chuck CJ, Bannister CD, Hawley JG, Davidson MG, La Bruna I, Paine A (2009) Predictive model to assess the molecular structure of biodiesel fuel. Energy Fuels 23(4):2290–2294
En 14110 (2019) Fat and oil derivatives—fatty acid methyl esters—determination of methanol content
Carareto ND, Kimura CY, Oliveira EC, Costa MC, Meirelles AJ (2012) Flash points of mixtures containing ethyl esters or ethylic biodiesel and ethanol. Fuel 96:319–326
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This work was supported by Project 20020160100084BA of the University of Buenos Aires (UBA), Argentina. The authors thank Eng. Miguel Pellejero (YPF) for the diesel fuel samples.
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Alviso, D., Saab, E., Clevenot, P. et al. Flash point, kinematic viscosity and refractive index: variations and correlations of biodiesel–diesel blends. J Braz. Soc. Mech. Sci. Eng. 42, 347 (2020). https://doi.org/10.1007/s40430-020-02428-w
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DOI: https://doi.org/10.1007/s40430-020-02428-w