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Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

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Abstract

Two energetic salts, DPHT DNS H2O(1) and DHT 2DNS 2H2O(2)[DPHT=3-(3,5-dimethyl-1H-pyrazol-1-yl)-6-hydrazinyl-1,2,4,5-tetrazine; DHT=3,6-dihydrazinyl-1,2,4,5-tetrazine], were synthesized from S-tetrazine with 3,5-dinitrosalicylic acid(DNS). Compounds 1 and 2 were structurally characterized by elemental analysis, infra-red spectroscopy, and single-crystal X-ray diffraction. The thermal behavior of the title compounds was studied by differential scanning calorimetry(DSC) and thermogravimetry(TG). The non-isothermal decomposition kinetics of compound 2 were investigated. The self-accelerating decomposition temperature, thermal ignition temperature, and critical temperatures of thermal explosion were obtained to evaluate the thermal safety of compound 2. The results show compounds 1 and 2 decompose at 150.8 and 179.2 °C, respectively. The TSADT and Tb of compound 2 are higher than those of DHT, which indicates compound 2 is a potential candidate for energetic materials that have good thermal stability.

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Authors and Affiliations

  1. School of Chemical Engineering, Northwest University, **’an, 710069, P. R. China

    **ang Chen, Tian Zeng, Cong Zhang, Zhaoqi Guo, Shuailei Li, Tao Mai & Haixia Ma

  2. College of Chemistry and Materials Science, Northwest University, **’an, 710069, P. R. China

    Rong Gao

Authors
  1. **ang Chen
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  2. Tian Zeng
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  3. Cong Zhang
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  4. Zhaoqi Guo
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  5. Shuailei Li
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  6. Tao Mai
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  7. Rong Gao
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  8. Haixia Ma
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Corresponding author

Correspondence to Haixia Ma.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21673179, 21504067) and the National Students’ Innovation and Entrepreneurship Training Program, China(No.201710697038).

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Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid

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Chen, X., Zeng, T., Zhang, C. et al. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid. Chem. Res. Chin. Univ. 34, 959–964 (2018). https://doi.org/10.1007/s40242-018-8169-z

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  • DOI: https://doi.org/10.1007/s40242-018-8169-z

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