Abstract
Plasma nitriding is a widely used technology to enhance the surface performance and extend the service life of alloy parts. The current research mainly focuses on the influences of time, temperature, gas type and pressure parameters on nitriding behavior, while fewer studies have been conducted on the electric potential. This paper mainly reports the effect of the electric potential on nitriding behavior. Test conditions were set using cathodic, anodic and floating potentials in a plasma nitriding furnace. 2Cr13 stainless steel was nitrided at 450 °C for 5 h in an NH3 atmosphere. The experimental results show that the nitriding treatment can be well performed under the different electric potentials, but differences exist in microstructures, morphologies and performance results of the modified layers. The thickness and hardness values of the nitrided layer are ranked as follows: cathodic > anodic > floating potential. The anodic nitrided surface has an obvious particle deposition layer composed of nitrides and oxides. Electrochemical and tribological experiments show that the corrosion resistance and wear resistance were significantly improved after a nitriding treatment using the three electric potentials. Moreover, the floating nitriding treatment resulted in the best tribological performance and corrosion resistance.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig3_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig4_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig5_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig9_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig10_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig11_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig12_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig13_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs40195-018-0836-z/MediaObjects/40195_2018_836_Fig14_HTML.png)
Similar content being viewed by others
References
Y.X. Wang, Z.B. Chen, C.S. Zhang, Y. You, Acta Metall. Sin. (Engl. Lett.) 31, 371 (2018)
A. Zhecheva, W. Sha, S. Malinov, A. Long, Surf. Coat. Technol. 200, 2192 (2005)
Y. Sun, Wear 362, 105 (2016)
B.C.E.S. Kurelo, G.B. de Souza, S.L.R. da Silva, F.C. Serbena, C.E. Foerster, C. Alves, Appl. Surf. Sci. 349, 403 (2015)
L.A. Espitia, H. Dong, X.Y. Li, C.E. Pinedo, A.P. Tschiptschin, Wear 376–377, 30 (2017)
Y.T. **, D.X. Liu, D. Han, Surf. Coat. Technol. 202, 2577 (2008)
W.Y. Tang, M.H. Chuang, S.J. Lin, J.W. Yeh, Metall. Mater. Trans. A 43, 2390 (2012)
D.X.L.Y.T. **, D. Han, Z.F. Han, Acta Metall. Sin. (Engl. Lett.) 21, 21 (2008)
Q. Wang, C. Huang, L. Zhang, J. Mater. Sci. Technol. 28, 60 (2012)
J.C. Díaz-Guillén, G. Vargas-Gutiérrez, E.E. Granda-Gutiérrez, J.S. Zamarripa-Piña, S.I. Pérez-Aguilar, J. Candelas-Ramírez, L. Álvarez-Contreras, J. Mater. Sci. Technol. 29, 287 (2013)
F. Zhang, M. Yan, J. Mater. Sci. Technol. 30, 1278 (2014)
M. Olzon-Dionysio, M. Campos, M. Kapp, S. de Souza, S.D. de Souza, Surf. Coat. Technol. 204, 3623 (2010)
C.E. Pinedo, S.I.V. Larrotta, A.S. Nishikawa, H. Dong, X.Y. Li, R. Magnabosco, A.P. Tschiptschin, Surf. Coat. Technol. 308, 189 (2016)
C.X. Li, J. Georges, X.Y. Li, Surf. Eng. 18, 453 (2002)
M. Naeem, M. Shafiq, M. Zaka-ul-Islam, A. Ashiq, J.C. Díaz-Guillén, M. Shahzad, M. Zakaullah, Mater. Des. 108, 745 (2016)
Y. Hoshiyama, R. Mizobata, H. Miyake, Surf. Coat. Technol. 307, 1041 (2016)
P. Hubbard, J.G. Partridge, E.D. Doyle, D.G. McCulloch, M.B. Taylor, S.J. Dowey, Surf. Coat. Technol. 204, 1145 (2010)
M. Naeem, M. Shafiq, M. Zaka-ul-Islam, M.I. Bashir, J.C. Díaz-Guillén, C.M. Lopez-Badillo, M. Zakaullah, J. Alloys Compd. 721, 307 (2017)
M.I. Bashir, M. Shafiq, M. Naeem, M. Zaka-ul-Islam, J.C. Díaz-Guillén, C.M. Lopez-Badillo, M. Zakaullah, Surf. Coat. Technol. 327, 59 (2017)
Y. Li, Z. Wang, L. Wang, Appl. Surf. Sci. 298, 243 (2014)
H. Dong, Int. Mater. Rev. 55, 65 (2010)
C.X. Li, T. Bell, Corros. Sci. 48, 2036 (2006)
A. Fossati, F. Borgioli, E. Galvanetto, T. Bacci, Surf. Coat. Technol. 200, 3511 (2006)
F. Borgioli, A. Fossati, E. Galvanetto, T. Bacci, Surf. Coat. Technol. 200, 2474 (2005)
F. Borgioli, A. Fossati, E. Galvanetto, T. Bacci, G. Pradelli, Surf. Coat. Technol. 200, 5505 (2006)
B.C.E.S. Kurelo, G.B. de Souza, S.L. Rutz da Silva, N.d.F. Daudt, C. Alves Jr., R.D. Torres, F.C. Serbena, Surf. Coat. Technol. 275, 41 (2015)
H. Forati Rad, A. Amadeh, H. Moradi, Mater. Des. 32, 2635 (2011)
F. Borgioli, E. Galvanetto, T. Bacci, G. Pradelli, Surf. Coat. Technol. 149, 192 (2002)
H. Martínez, F.B. Yousif, Eur. Phys. J. D 46, 493 (2008)
K. Rusnak, J. Vicek, J. Phys. D Appl. Phys. 26, 585 (1993)
J. Walkowicz, Surf. Coat. Technol. 174–175, 1211 (2003)
H. Michel, T. Czerwiec, M. Gantois, D. Ablitzer, A. Ricard, Surf. Coat. Technol. 72, 103 (1995)
A. Bogaerts, E. Neyts, R. Gijbels, J. van der Mullen, Spectrochim. Acta B 57, 609 (2002)
R. de Sousa, F. de Araujo, K. Ribeiro, T. Dumelow, J. da Costa, C. Alves, Surf. Eng. 24, 52 (2008)
C. Zhao, L.Y. Wang, L. Han, Surf. Eng. 24, 188 (2008)
Y. Li, Y. He, S. Zhang, X. He, W. Wang, B. Hu, Vacuum 146, 1 (2017)
Y. Li, Y. He, J. **u, W. Wang, Y. Zhu, B. Hu, Surf. Coat. Technol. 329, 184 (2017)
Y.T. **, D.X. Liu, D. Han, Appl. Surf. Sci. 254, 5953 (2008)
P. Corengia, G. Ybarra, C. Moina, A. Cabo, E. Broitman, Surf. Coat. Technol. 187, 63 (2004)
Y. Li, Y. He, W. Wang, J. Mao, L. Zhang, Y. Zhu, Q. Ye, J. Mater. Sci. Eng. Perform. 27, 948 (2018)
K.J.B. Ribeiro, R.R.M. de Sousa, F.O. de Araújo, R.A. de Brito, J.C.P. Barbosa, C. Alves Jr., Mater. Sci. Eng. A 479, 142 (2008)
K. Nagatsuka, A. Nishimoto, K. Akamatsu, Surf. Coat. Technol. 205, S295 (2010)
A. Nishimoto, A. Tokuda, K. Akamatsu, Mater. Trans. 50, 1169 (2009)
T. Yamashita, P. Hayes, Appl. Surf. Sci. 254, 2441 (2008)
F.Z. Bouanis, C. Jama, M. Traisnel, F. Bentiss, Corros. Sci. 52, 3180 (2010)
L. Freire, M.J. Carmezim, M.G.S. Ferreira, M.F. Montemor, Electrochim. Acta 55, 6174 (2010)
A. Lippitz, T. Hübert, Surf. Coat. Technol. 200, 250 (2005)
D.J. Li, F. Liu, M.X. Wang, J.J. Zhang, Q.X. Liu, Thin Solid Films 506, 202 (2006)
A. Conde, A.B. Cristóbal, G. Fuentes, T. Tate, J. de Damborenea, Surf. Coat. Technol. 201, 3588 (2006)
F.Z. Bouanis, F. Bentiss, M. Traisnel, C. Jama, Electrochim. Acta 54, 2371–2378 (2009)
J. Baranowska, S.E. Franklin, Wear 264, 899 (2008)
M.F. Yan, R.L. Liu, Surf. Coat. Technol. 205, 345 (2010)
J. Yang, Y. Liu, Z. Ye, D. Yang, S. He, X. Li, Appl. Surf. Sci. 256, 4072 (2010)
Acknowledgements
This project was supported by the National Key Basic Research Program of China (No. 2014CB046404), the Shandong Provincial Natural Science Foundation, China (No. ZR2018MEE016), the Shandong Provincial Key Research and Development Plan, China (No. 2017GGX20140) and the National Natural Science Foundation of China (No. 51301149).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Available online at http://springer.longhoe.net/journal/40195
Rights and permissions
About this article
Cite this article
Li, Y., Zhang, SZ., Qiu, JX. et al. Effect of Electric Potentials on Microstructure, Corrosion and Wear Characteristic of the Nitrided Layer Prepared on 2Cr13 Stainless Steel by Plasma Nitriding. Acta Metall. Sin. (Engl. Lett.) 32, 733–745 (2019). https://doi.org/10.1007/s40195-018-0836-z
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-018-0836-z