SpringerLink
Log in

Mononuclear copper(II) complexes containing chelating ligand of 2-methyl-N-(pyridine-2-yl-methyl)propane-2-amine as chromotropic probes

  • Original Paper
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

The synthesis of two mononuclear copper(II) complexes of formula [L2CuX]X where L is a bidentate ligand of N-(pyridin-2-yl-methyl)propane-2-amine and X = Cl, 1 and Br, 2, is reported. Both complexes are fully characterized by elemental analysis, spectroscopic techniques (IR, UV–Vis, and EPR), thermal analysis, conductance measurements, and single-crystal X-ray structure determination. The structures of both complexes are similar and display a distorted square–pyramidal arrangement around copper(II) ion. The chromotropism behavior of the complexes, including thermo- and halochromism, was investigated. The complexes demonstrated strongly pronounced reversible thermochromism in solution due to dissociation and re-coordination of halide and bidentate ligands. Their halochromism was investigated in pH range of 3.0–11.0 by visible absorption spectroscopy. Their reversible color variations from blue to colorless attributed to the deprotonation and protonation of the bidentate ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Scheme 3
Fig. 6
Scheme 4
Fig. 7

Similar content being viewed by others

References

  1. W. Linert. Y. Fukuda, A. Camard, Coord. Chem. Rev. 218, 113–152 (2001)

    Article  CAS  Google Scholar 

  2. Y. Fukuda, Inorganic chromotropism Springer, Berlin, 2007

    Book  Google Scholar 

  3. C.F. Zhu, A.B. Wu, Thermochim. Acta 425, 7–12 (2005)

    Article  CAS  Google Scholar 

  4. A. Hamberger, A.M. Popa, R.M. Rossi, D.R. Kattnig, D. Hinderberger, K. Landfester, D. Crespy, J. Mater. Chem. 22, 9909–9920 (2012)

    Article  CAS  Google Scholar 

  5. V.N. Khrustalev, S.O. Kostenko, M.I. Buzin, A.A. Korlyukov, Y.V. Zubavichus, M.A. Kurykin, M.Y. Antipin, Inorg. Chem. 51, 10590–10602 (2012)

    Article  CAS  PubMed  Google Scholar 

  6. H. Golchoubian, L. Rostami, J. Coord. Chem. 70, 3660–3676 (2017)

    Article  CAS  Google Scholar 

  7. L. Stryer, Biochemistry, 3rd Ed. New York: Freeman; 1988

    Google Scholar 

  8. F. Cheng, N. Tang, J. Chen, F. Wang, L. Chen, Inorg. Chem. Commun. 14, 852–855 (2011)

    Article  CAS  Google Scholar 

  9. P. Bamfield, Chromic phenomena: technological applications of color chemistry Springer, Berlin, 2002, p. 8

    Google Scholar 

  10. H. Golchoubian, E. Rezaee, G. Bruno, H.A. Rudbari, Inorg. Chim. Acta 366, 290–297 (2011)

    Article  CAS  Google Scholar 

  11. H. Golchoubian, R. Samimi, Polyhedron 128, 68–75 (2017)

    Article  CAS  Google Scholar 

  12. H. Golchoubian, M. Tarahomi, E. Rezaee, G. Bruno, Polyhedron 85, 635–642 (2015)

    Article  CAS  Google Scholar 

  13. SAINT, Software for the CCD Detector System, (version 7.06A), Bruker AXS (Inc, Madison, Wisconsin, 2005)

  14. M.C. Burla, R. Caliandro, M. Camalli, B. Carrozzini, G.L. Cascarano, L. De Caro, C. Giacovazzo, G. Polidori, R. Spagna, J. Appl. Cryst. 38, 381–388 (2005)

    Article  CAS  Google Scholar 

  15. G.M. Sheldrick, SHELXL-2014/7: program for the solution of crystal structures (University of Göttingen, Göttingen, 2014)

    Google Scholar 

  16. G.M. Sheldrick, Acta Cryst. C71, 3–8 (2015)

    Google Scholar 

  17. A.W. Addison, T.N. Rao, J. Reedijk, J. van Rijn, G.C. Verschoor, J. Chem. Soc. Dalton Trans. 1349–1356 (1984)

  18. S.Q. Bai, E.Q. Gao, Z. He, C.J. Fang, C.H. Yan, New J. Chem. 29, 935–941 (2005)

    Article  CAS  Google Scholar 

  19. T. Pandiyan, H.J. Guadalupe, J. Cruz, S. Bernès, V.M. Ugalde-Salvdivar, Eur. J. Inorg. Chem. 21, 3274–3285 (2008)

    Article  CAS  Google Scholar 

  20. Cambridge Structural Database System, Cambridge Crystallographic Data Centre, University Chemical Laboratory, Cambridge, UK

  21. C. Tsiamis, M. Themeli, Inorg. Chim. Acta 206, 105–115 (1993)

    Article  CAS  Google Scholar 

  22. W.J. Geary, Coord. Chem. Rev. 7, 81–122 (1971)

    Article  CAS  Google Scholar 

  23. C.J. Williams, H. Morris, J. Svorec, M. Valková, M. Valko, J. Moncol, M. Mazur, F. Valach, M. Melnik, J. Mol. Struct. 659, 53–60 (2003)

    Article  CAS  Google Scholar 

  24. V. Sakaguchi, A.W. Addison, J. Chem. Soc. Dalton Trans. 600–608 (1979)

  25. J. Losada, I. Del Peso, L. Beyer, Inorg. Chim. Acta 321, 107–115 (2001)

    Article  CAS  Google Scholar 

  26. D. Kivelson, R. Neiman, J. Chem. Phys. 35, 149–155 (1961)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We are grateful for the financial support of the University of Mazandaran of the Islamic Republic of Iran.

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Mazandaran, Babol-sar, 47416-95447, Iran

    Roya Nazari & Hamid Golchoubian

  2. Dipartimento di Chimica Inorganica, Università di Messina, Vill. S. Agata, Salita Sperone 31, 98166, Messina, Italy

    Giuseppe Bruno

Authors
  1. Roya Nazari
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hamid Golchoubian
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Giuseppe Bruno
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hamid Golchoubian.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nazari, R., Golchoubian, H. & Bruno, G. Mononuclear copper(II) complexes containing chelating ligand of 2-methyl-N-(pyridine-2-yl-methyl)propane-2-amine as chromotropic probes. J IRAN CHEM SOC 16, 1041–1052 (2019). https://doi.org/10.1007/s13738-018-01577-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-018-01577-z

Keywords

Search

Navigation