Abstract
In the present study, a new, simple, rapid, and environmentally friendly headspace-liquid phase microextraction method followed by gas chromatography–flame ionization detection has been developed for the extraction/preconcentration and determination of 1,4-dioxane from shampoo. The developed procedure is performed in a home-made extraction vessel, connected to a glass vial containing sample and extraction solvent. In this method, an aliquot weight of shampoo is mixed with a binary mixture of n-hexane and dichloromethane (50:50, v/v) as the extractant and the target analyte is extracted during a liquid–liquid extraction procedure. Then a home-made extraction vessel containing a few microliters of a collection/extraction solvent is contacted to a glass vial containing the organic phase obtained from the previous step. By heating 1,4-dioxane is vaporized and enriched in a μL volume of the collection/extraction solvent. Then an aliquot volume of the collected phase is injected into the separation system. The effect of several factors which may influence performance of the method, including kind and volume of the extraction solvents used in both steps, extraction temperature, extraction time, and salt addition were evaluated. Under the optimum extraction conditions, limits of detection and quantification for the target analyte were obtained 0.52 and 1.73 μg kg−1, respectively. Enrichment factor and extraction recovery were 333 and 89 %, respectively. The method precision was evaluated at a concentration of 25 μg kg−1 and relative standard deviation was less than 6.9 % for intra-day (n = 6) and inter-day (n = 4) precisions. Finally, the proposed method has been successfully applied in analysis of 1,4-dioxane in different shampoo samples.
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Abbreviations
- DHS-LPME:
-
Dynamic headspace-liquid phase microextraction
- DMSO:
-
Dimethyl sulfoxide
- EF:
-
Enrichment factor
- ER:
-
Extraction recovery
- FID:
-
Flame ionization detection
- GC:
-
Gas chromatography
- LLE:
-
Liquid–liquid extraction
- LOD:
-
Limit of detection
- LOQ:
-
Limit of quantification
- RSD:
-
Relative standard deviation
- SPE:
-
Solid phase extraction
- SPME:
-
Solid phase microextraction
References
S. Scalia, F. Testoni, G. Frisina, M. Guarneri, J. Soc. Cosmet. Chem. 43, 207–213 (1992)
S.C. Rastogi, Chromatographia 29, 441–450 (1990)
T. Nishimura, S. Lizuka, N. Kibune, M. Ando, J. Health. Sci. 50, 101–107 (2004)
C.T. Derosa, S. Willbur, J. Holler, P. Richter, Y.W. Stevens, Toxicol. Ind. Health 12, 1–43 (1996)
Occupational exposure limits for 1,4-dioxane recommendations of the Scientific Committee for Occupational Exposure Limits (SCOEL) to chemical agents. Office for official publications of the European Communities (2005)
R.E. Black, F.J. Hurley, D.C. Havery, J. AOAC Int. 84, 666–670 (2001)
J.D. Young, W.H. Braun, L.W. Rampy, M.B. Chenoweth, G.E. Blau, J. Toxicol. Environ. Health 3, 507–520 (1997)
J. Matthew, R.C. Zenker, A.B. Morten, J. Environ. Eng. Sci. 20, 423–432 (2003)
G.D. Clayton, F. E. Clayton (eds.), Patty’s Industrial Hygiene and Toxicology, 3rd edn (Wiley, New York, 1982), pp 3947–3956
A. Fairly, E.C. Linton, A.H. Ford-Moore, J. Hyg. 34, 486–501 (1934)
International Agency For Research on Cancer in IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man, International Agency for Research on Cancer (Lyons, France, vol. 11, 1976), pp. 247–256
IARC Monographs on the Evaluation of Carcinogenic Risks to Human, Re-evaluation of Some Organic Chemicals, Hydrazine and Hydrogen Peroxide (World Health Organization, Lyon, vol. 71, 1999), pp. 589–602
National Cancer Institute (NCI) Carcinogenicity Technical Report No. NCL-GC-TR-80 (Bethesda, 2015)
L.M. Sweeney, K.D. Thrall, T.S. Poet, R.A. Corley, T.J. Weber, B.J. Locey, J. Clarkson, Sh Sager, M. Gargas, Toxicol. Sci. 101, 32–50 (2008)
US Department of Health and Human Services, Agency for toxic substances and disease registry: toxicological profile for 1,4-dioxane (draft for public comment) (Atlanta, 2004)
W.M. Draper, J.S. Dhoot, J.W. Remoy, S.K. Perera, Analyst 125, 1403–1408 (2000)
R. Otson, C. Chan, Int. J. Environ. Anal. Chem. 30, 275–287 (1987)
N. Ramirez, R.M. Marce, F. Borrull, Int. J. Environ. Anal. Chem. 91, 911–928 (2011)
M. Li, P. Conlon, S. Fiorenza, S.R.J. Vitale, P.J.J. Alvarez, Ground Water Monit. Rem. 31, 70–76 (2011)
Y.P.T. Bonnie, M. Zulina, M. Halimah, J. Am. Chem. Soc. 91, 1103–1110 (2014)
A.B. Waldman, J. Soc. Cosmet. Chem. 33, 19–25 (1982)
J.J. Robinson, E.W. Ciurczak, J. Soc. Cosmet. Chem. 31, 329–337 (1980)
S. Scalia, J. Pharm. Biomed. Anal. 8, 867–870 (1990)
S.H. Hong, J.B. Lee, S.H. Lee, H.H. Lim, H.S. Shin, J. Anal. Sci. Technol. 27, 22–26 (2014)
Y.M. Park, H. Pyo, S.J. Park, S.K. Park, Anal. Chim. Acta 548, 109–115 (2005)
P.E. Grimett, J.W. Munch, J. Chromatogr. Sci. 47, 31–39 (2009)
M.A. Jochmann, M.P. Kmiecik, D.C. Schmidt, J. Chromatogr. A 1115, 208–216 (2006)
C. Isaacson, T.K.G. Mohr, J.A. Field, Environ. Sci. Technol. 40, 7305–7311 (2006)
G. Ortiz, G.M.T. Tena, J. Chromatogr. A 1101, 32–37 (2006)
C.B. Fuh, M. Lai, H.Y. Tsai, C.M. Chang, J. Chromatogr. A 1071, 141–145 (2005)
P.N. Nomngongo, J.C. Ngila, J. Iran. Chem. Soc. 12, 2141–2147 (2015)
S. Bahar, F. Karami, J. Iran. Chem. Soc. 12, 2213–2220 (2015)
G. Khayatian M. Jodan, S. Hassanpoor, S. Mohebbi, J. Iran. Chem. Soc. (2016) doi:10.1007/s13738-015-0798-2 (Article in press)
H. Sereshti, M. Karimi, J. Iran. Chem. Soc. 11, 1129–1136 (2014)
R.E. Shirey, C.M. Linton, J. Chromatogr. Sci. 44, 444–450 (2006)
W. Yufei, S. Jiawei, W. Li, Chin. J. Chromatogr. 33, 441–445 (2015)
S. Nakamura, S. Daishima, Anal. Chim. Acta 548, 79–85 (2005)
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The authors thank the Research Council of University of Tabriz for financial support and scientific encouragement. The authors declare no conflicts of interest.
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Farajzadeh, M.A., Nassiry, P., Mogaddam, M.R.A. et al. Development of dynamic headspace-liquid phase microextraction method performed in a home-made extraction vessel for extraction and preconcentration of 1,4-dioxane from shampoo. J IRAN CHEM SOC 13, 1385–1393 (2016). https://doi.org/10.1007/s13738-016-0853-7
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DOI: https://doi.org/10.1007/s13738-016-0853-7