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Antioxidant effect of clove oil on biodiesel produced from waste cooking oil

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Abstract

In this study, the natural antioxidant efficiency of the clove oil on the oxidative stability of waste cooking oil biodiesel was investigated. The oxidative stability was determined as for ASTM D7545 standart method for biodiesel added with 1,000, 2,000 and 3,000 ppm of additives by using oxifast device, and compared with the chemical antioxidant butylated hydroxy toluene (BHT) at the same concentrations. Samples were characterized by using Fourier transform infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) techniques. Oxidation stability was determined by using ASTM D7545 by rapid oxidation test method. With the effect of antioxidant addition to biodiesel, the bond vibrations and transmittance % values of the FT-IR peaks changed. The crystallization temperatures (Tcr) of the samples were determined by using a DSC technique. It was concluded that Tcr values of samples with antioxidant were decreased compared to the non-antioxidant biodiesel sample (B100). The order of antioxidant power was B100BHT3 > B100C3 > B100C2 > B100BHT2 > B100C1 > B100BHT1 > B100. The oxidation times were determined as 29, 34, 40, 41, 46, 55, and 60 min respectively. The results show that the crystallization onset temperatures for B100, B100C3, and B100BHT3 were − 51.83, − 54.49, and − 54.15 °C respectively. Addition of natural antioxidant has a positive effect on biodiesel oxidative stability for all concentrations; in addition, natural clove oil showed a similar efficiency with the synthetic chemical antioxidant.

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Acknowledgements

The authors would like to thank Hasan Özcan in Kolza Biodiesel Company in Turkey for supporting WCOME biodiesel and the analysis. The author would like to thank to Dr. Nalan Türköz Karakullukçu in KİTAM, Ondokuz Mayis University, Samsun, Turkey, for the DSC analysis.

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  1. Department of Chemical Engineering, Ondokuz Mayis University, Samsun, Turkey

    Gediz Uğuz

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Uğuz, G. Antioxidant effect of clove oil on biodiesel produced from waste cooking oil. Biomass Conv. Bioref. 13, 367–373 (2023). https://doi.org/10.1007/s13399-021-01679-4

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