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Dielectric, electrical and impedance study of single perovskite Pb(Ni1/3Mn1/3W1/3)O3

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Abstract

A multiferroic material Pb(Ni1/3Mn1/3W1/3)O3 with ferroelectric and ferromagnetic properties at room temperature is designed for multifunctional applications. A orthorhombic perovskite crystal structure has been assigned for the present perovskite according to the X-ray diffraction patterns. At 1 kHz, dielectric constant (ɛr) increases from 1655 at 298 K to its first maximum 3514 at 457 K referred as magnetic transition. The high values of ɛr in the low frequency range show better dispersion, and with the increase in frequency, a gradual decrease in the ɛr values was observed. The contribution of grain and/or electrode/interface effects in the resistive/capacitive properties was ascertained by the Nyquist plots. An equivalent circuit has been suggested consisting of resistive and capacitive components (R, C, Q) estimates the bulk (grain) and grain boundary resistance and capacitance. The activation energy was found to be greater than 0.2 eV, supporting the conduction mechanism due to hop** of charge carriers.

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References

  1. L Z Wang Functional and Smart Materials (ed.) J G Webster (Wiley Encyclopedia of Electrical and Electronics Engineering) Vol 1, Chapter 1, Section 1, p 11 (1999). https://doi.org/10.1002/047134608X.W7416

  2. T Lottermoser, T Lonkai, U Amann, D Hohlwein, J Ihringer and M Fiebig Nature 430 541 (2004)

    Article  ADS  Google Scholar 

  3. N Hur, S Park, P A Sharma, J S Ahn, S Guha and S-W Cheong Nature 429 392 (2004)

    Article  ADS  Google Scholar 

  4. N A Spaldin, S-W Cheong and R Ramesh Phys. Today 63 38 (2010)

    Article  Google Scholar 

  5. W Eerenstein, N D Mathur and J F Scott Nature 442 759 (2006)

    Article  ADS  Google Scholar 

  6. M Bibes and A Barthelemy Nat. Mater. 7 425 (2008)

    Article  ADS  Google Scholar 

  7. J Zhai, Z **ng, S Dong, J Li and D Viehland Appl. Phys. Lett. 88 62510 (2006)

    Article  Google Scholar 

  8. J R Hattrick-Simpers, L Dai, M Wuttig, I Takeuchi and E Quandt Rev. Sci. Instrum. 78 106103 (2007)

    Article  ADS  Google Scholar 

  9. X Dai, Y Wen, P Li, J Yang and G Zhang Sens. Actuators A Phys. 156 350 (2009)

    Article  Google Scholar 

  10. J Lou, D Reed, M Liu and N X Sun Appl. Phys. Lett. 94 112508 (2009)

    Article  ADS  Google Scholar 

  11. S Dong, J F Li, D Viehland, J Cheng and L E Cross Appl. Phys. Lett. 85 3534 (2004)

    Article  ADS  Google Scholar 

  12. R A Islam and S Priya J. Mater. Sci. 43 3560 (2008)

    Article  ADS  Google Scholar 

  13. J Ryu, S Priya, K Uchino and H-E Kim J. Electroceramics 8 107 (2002)

    Article  Google Scholar 

  14. Y Sasaki, M Yamamoto, A Ochi, T Inoue and S Takahashi Jpn. J. Appl. Phys. 38 5598 (1999)

    Article  ADS  Google Scholar 

  15. J Yoo, K Yoon, Y Lee, S Suh, J Kim and C Yoo Jpn. J. Appl. Phys. 39 2680 (2000)

    Article  ADS  Google Scholar 

  16. S K Sinha, S N Choudhary and R N P Choudhary J. Mater. Sci. 39 315 (2004)

    Article  ADS  Google Scholar 

  17. V L Mathe, K K Patankar, S D Lotke, P B Joshi and S A Patil Bull. Mater. Sci. 25 347 (2002)

    Article  Google Scholar 

  18. C G Koops Phys. Rev. 83 121 (1951)

    Article  ADS  Google Scholar 

  19. F Liang, Z Hui, W Bolin and Y Runzhang Prog. Cryst. Growth Charact. Mater. 40 161 (2000)

    Article  Google Scholar 

  20. A Kumar, B P Singh, R N P Choudhary and A K Thakur J. Alloys Compd. 394 292 (2005)

    Article  Google Scholar 

  21. M Ram J. Alloys Compd. 509 1744 (2011)

    Article  Google Scholar 

  22. A K Jonscher Nature 267 673 (1977)

    Article  ADS  Google Scholar 

  23. A K Jonscher J. Phys. D. Appl. Phys. 32 R57 (1999)

    Article  ADS  Google Scholar 

  24. J Ross Macdonald Solid State Ionics 13 147 (1984)

    Article  Google Scholar 

  25. R Ranjan, R Kumar, N Kumar, B Behera and R N P Choudhary J. Alloys Compd. 509 6388 (2011)

    Article  Google Scholar 

  26. S Sen, R N P Choudhary and P Pramanik Phys. B Condens. Matter 387 56 (2007)

    Article  ADS  Google Scholar 

  27. N Hirose and A R West J. Am. Ceram. Soc. 79 1633 (1996)

    Article  Google Scholar 

  28. M A E-F Gabal, Y M Al Angari and A Y Obaid Comptes Rendus Chim. 16 704 (2013)

    Article  Google Scholar 

  29. A Belboukhari, E Choukri, Y Gagou, R Elmoznine, N Abdelmoula, A Neqali, M El Marssi, H Khemakhem and D Mezzane Superlattices Microstruct. 71 7 (2014)

    Article  ADS  Google Scholar 

  30. Y Zhang, J-P Zhou, Q Liu, S Zhang and C-Y Deng Ceram. Int. 40 5853 (2014)

    Article  Google Scholar 

  31. D C L Vasconcelos, V C Costa, E H M Nunes, A C S Sabioni, M Gasparon and W L Vasconcelos Mater. Sci. Appl. 2 1375 (2011)

    Google Scholar 

  32. M Mahesh Kumar, A Srinivas, S V Suryanarayana, G S Kumar and T Bhimasankaram Bull. Mater. Sci. 21 251 (1998)

    Article  Google Scholar 

  33. M Shi, R Zuo, Y Xu, L Wang, C Gu, H Su, J Zhong and G Yu Ceram. Int. 40 9249 (2014)

    Article  Google Scholar 

  34. P Pahuja, C Prakash and R P Tandon Ceram. Int. 40 5731 (2014)

    Article  Google Scholar 

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Acknowledgements

The present work is funded by the UGC-DAE-CSR, Mumbai (CRS-M-297), and the authors would like to thank Dr. P. D. Babu of UGC-DAE-CSR, Mumbai, and Dr. Raja Kishora Lenka of Powder Metallurgy Division, BARC, Mumbai, for their valuable suggestions and some characterization.

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Authors and Affiliations

  1. P.G. Department of Chemistry, Vikram Deb (Autonomous) College, Jeypore, 764001, India

    Sujit Kumar Dehury

  2. Department of Chemistry, Siksha ‘O’ Anusandhan, Deemed to be University, Khandagiri Square, Bhubaneswar, 751030, India

    Deeptimayee Khatua & P. Ganga Raju Achary

  3. Department of Physics, Siksha ‘O’ Anusandhan, Deemed to be University, Khandagiri Square, Bhubaneswar, India

    R. N. P. Choudhary

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  1. Sujit Kumar Dehury
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  2. Deeptimayee Khatua
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  4. R. N. P. Choudhary
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Correspondence to P. Ganga Raju Achary.

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Dehury, S.K., Khatua, D., Achary, P.G.R. et al. Dielectric, electrical and impedance study of single perovskite Pb(Ni1/3Mn1/3W1/3)O3. Indian J Phys 93, 837–844 (2019). https://doi.org/10.1007/s12648-018-1344-8

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