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The study of glass transition temperature in Sb–V2O5–TeO2 glasses at different heating rates

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Abstract

The glass transition of xSb–(60 − x)V2O5–40TeO2 glasses with 0 < x <15 (in mol%) at different heating rates (φ = 3–12 K/min) has been studied using differential scanning calorimetry. The glass transition temperature (T g) and crystallization temperature (T cr) of these glasses have been determined. The effects of the heating rate and the Sb content on T g have been discussed. It has been observed that the transition region shifts to higher temperatures when the measuring time is reduced. The compositional dependence of T g has been determined and so an empirical equation has been deduced relating the glass transition temperature with the Sb concentration. Also, the value of glass-forming tendency has been studied for the present glasses.

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References

  1. R N Hampton, W Hong, G A Saunders and R A El-Mallawany Phys. Chem. Glasses 29 100 (1988)

    Google Scholar 

  2. R El-Mallawany J. Mater. Res. 5 2218 (1990)

    Article  ADS  Google Scholar 

  3. R El-Mallawany and I A Ahmed J. Mater. Sci. 43 5131 (2008)

    Article  ADS  Google Scholar 

  4. R El-Mallawany J. Mater. Res. 7 224 (1992)

    Article  ADS  Google Scholar 

  5. M M Elkholy and R El-Mallawany Mater. Chem. Phys. 40 163 (1995)

    Article  Google Scholar 

  6. M M El‐Zaidia, A A Ammar and R A El-Mallawany Phys. Status Solidi (a) 91 637 (1985)

    Article  ADS  Google Scholar 

  7. H Moawad, H Jain, R El-Mallawany, T Ramadan and M El‐Sharbiny J. Am. Ceram. Soc. 85 2655 (2002)

    Article  Google Scholar 

  8. R El-Mallawany and A A El-Moneim Phys. Status Solidi (a) 166 829 (1985)

    Article  ADS  Google Scholar 

  9. J E Stanworth J. Soc. Glass Thechnol. 36 217 (1952)

    Google Scholar 

  10. H Mori, H Matsuno and H Sakata J. Non-Cryst. Solids 276 178 (2000)

    Article  Google Scholar 

  11. D Souri and K Shomalian J. Non-Cryst. Solids 355 1597 (2009)

    Google Scholar 

  12. D Souri and S A Salehizadeh J. Mater. Sci. 44 5800 (2009)

    Article  ADS  Google Scholar 

  13. D Souri J. Phys. D 41 105102 (2008)

    Article  ADS  Google Scholar 

  14. D Souri and M Elahi Phys. Scr. 75.2 219 (2007)

    Article  ADS  Google Scholar 

  15. D Souri J. Non-Cryst. Solids 356 2181 (2010)

    Article  ADS  Google Scholar 

  16. A Ghosh and B K Chaudhuri J. Mater. Sci. 22 2369 (1987)

  17. M Pal, K Hirota, Y Tsujigami and H Sakata J. Phys. D 121 459 (2001)

    Article  ADS  Google Scholar 

  18. A Ghosh J. Appl. Phys. 65 227 (1989)

  19. G S Murugan and Y Ohishi J. Non-Cryst. Solids 341 86 (2004)

    Google Scholar 

  20. S Jayaseelan, P Muralidharan, M Venkateswarlu and N Satyanarayana Mater. Sci. Eng. B 118 136 (2005)

    Article  Google Scholar 

  21. R El-Mallawany, A Abousehly and E Yousef J. Mater. Sci. Lett. 19 409 (2000)

    Article  Google Scholar 

  22. A El-Adawy and R El-Mallawany J. Mater. Sci. Lett. 15 2065 (1996)

    Google Scholar 

  23. A Abdel-Kader, R El-Mallawany and M M Elkholy J. Appl. Phys. 73 71 (1993)

    Article  ADS  Google Scholar 

  24. S Sen and A Ghosh J. Mater. Res. 15 995 (2000)

  25. M A Sidkey, R El-Mallawany, A Abousehly and Y B Saddeek Glass Sci. Technol.: Glastechnische Berichte 75 87 (2002)

    Google Scholar 

  26. G Turky and M Dawy Mater. Chem. Phys. 77 48 (2002)

    Article  Google Scholar 

  27. G W Scherer Relaxation in Glasses and Composites (New York: Wiley) (1986)

    Google Scholar 

  28. E Gerlach The Physics of Selenium and Tellurium (Berlin, New York: Springer) P Grosse (Ed.) (1979)

  29. S G Bishop, U Strom and P C Taylor Phys. Rev. Lett. 34 1346 (1975)

    Article  ADS  Google Scholar 

  30. J Donohue The Structure of the Elements (New York: Wiley) (1974)

  31. CT Moynihan, A J Easteal, J Wilder and J Tucker J. Phys. Chem. 78 2673 (1974)

    Article  Google Scholar 

  32. S R Elliott Physics of Amorphous Materials, 2nd edn. (Essex, UK: Longman Scientific and Technical) (1990)

  33. I Avramov, G Guinev and A C M Rodrigues J. Non-Cryst. Solids 271 12 (2000)

    Article  ADS  Google Scholar 

  34. D Zhu, C S Ray, W Zhou and D E Day J. Mater. Sci. 39 7351 (2004)

    Article  ADS  Google Scholar 

  35. K Sega, Y Kuroda and H Sakata J.Mater. Sci. 33 1303 (1998)

    Article  ADS  Google Scholar 

  36. D Souri, P Azizpour and H Zaliani J. Electron. Mater. 43 3672 (2014)

    Article  ADS  Google Scholar 

  37. D Zhu, C S Ray, W Zhou and D E Day J. Non-Cryst. Solids 319 247 (2003)

    Article  ADS  Google Scholar 

  38. G W Smith, F E Pinkerton and J J Moleski Thermochim. Acta 342 31 (1999)

    Google Scholar 

  39. S Vyazovkin, N Sbirrazzuoli and I Dranca Macromol. Rapid Commun. 25 1708 (2004)

    Article  Google Scholar 

  40. A Abu-Sehly, M Abu El-Oyoun and A A Elabbar Thermochem. Acta 472 25 (2008)

    Google Scholar 

  41. J Rocherull’e, M Matecki and Y Delugeard J. Non-Cryst. Solids 238 51 (1998)

    Article  ADS  Google Scholar 

  42. M Lasocka Mater. Sci. 23 173 (1976)

    Google Scholar 

  43. R N Sinclair, A C Wrigth, B Bachra, Y B Dimitriev, V V Dimitrov and M G Arnaudov J. Non-Cryst. Solids 232–234 38 (1998)

    Article  Google Scholar 

  44. D Souri, M Mohammadi and H Zaliani Electron. Mater. Lett. 10 1103 (2014)

    Article  Google Scholar 

  45. R El-Mallawany J. Mater. Sci.: Mater. Electron. 6 1 (1995)

    Google Scholar 

Download references

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Souri, D. The study of glass transition temperature in Sb–V2O5–TeO2 glasses at different heating rates. Indian J Phys 89, 1277–1281 (2015). https://doi.org/10.1007/s12648-015-0710-z

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