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Yolk–shell FeCu/NC electrocatalyst boosting high-performance zinc-air battery

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Abstract

Iron–nitrogen–carbon single-atom catalysts (Fe–N–C SACs) are widely acknowledged for their effective oxygen reduction activity, however, their activity requires further enhancement. Meanwhile, additional structural optimization is necessary to enhance mass transport and achieve higher power density in practical applications. Herein, using ZIF-8 as a template, we synthesized yolk–shell catalysts featuring complex sites of Fe single atoms and Cu nanoclusters (y-FeCu/NC) via partial etching and liquid-phase loading. The synthesized y-FeCu/NC catalyst exhibits high specific surface area and mesoporous volume. Combined with the advantages of highly active sites and yolk–shell structure, the y-FeCu/NC catalyst demonstrated outstanding catalytic performance in the oxygen reduction reaction, achieving a half-wave potential (E1/2) of 0.97 V in 0.1 M KOH. As a practical energy device, Zn-air battery (ZAB) assembled with y-FeCu/NC catalyst achieved a remarkable power density of 356.3 mW·cm−2, representing an improvement of approximately 28.5% compared to its solid FeCu/NC counterpart. Furthermore, it showcased impressive stability, surpassing all control samples.

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Acknowledgements

This work was financially supported by the National Key Research and Development Program of China (No. 2022YFC2105900). The authors thank the Shanghai Synchrotron Radiation Facility (SSRF) for XAS measurement.

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Bei**g University of Chemical Technology, Bei**g, 100029, China

    Chen Liang, Tianyu Zhang, Shilun Sun, Aijuan Han & Junfeng Liu

  2. College of Mathematics & Physics, Bei**g University of Chemical Technology, Bei**g, 100029, China

    Zenghui Qiu & Haijun Xu

  3. Bei**g Bioprocess Key Laboratory, Bei**g University of Chemical Technology, Bei**g, 100029, China

    Zenghui Qiu & Haijun Xu

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  1. Chen Liang
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Correspondence to Zenghui Qiu, Haijun Xu or Junfeng Liu.

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Liang, C., Zhang, T., Sun, S. et al. Yolk–shell FeCu/NC electrocatalyst boosting high-performance zinc-air battery. Nano Res. (2024). https://doi.org/10.1007/s12274-024-6766-3

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