Abstract
The dependence of microwave dielectric properties on the isovalent substitution of (Sn 4+1/2 W1/26+)5+ (electronegativity difference from O2−, X = 2.16) and (Ti 4+1/2 W1/26+)5+ (X = 1.95), with higher electronegativity differences than Nb5+ (X = 1.6) at Nb5+-sites of Mg4Nb2O9 ceramics was investigated. As expected from the electronegativity values, the quality factor of the specimens reached the highest value (274000 GHz) at X = 0.05 because Mg4Nb1.95(Sn1/2W1/2)0.05 O9 had a higher average bond valence than the other specimens. The dielectric constants (K) of the specimens were affected by the theoretical dielectric polarizability. The K value of specimens decreased with increasing x because Nb5+ has a higher dielectric polarizability (3.97 Å3) than the substitution ions such as (Sn1/2W1/2)5+ (3.015 Å3) and (Ti1/2W1/2)5+ (3.065 Å3). The effects of the structural characteristics with isovalent substitution on the microwave dielectric properties are also discussed.
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References
D.S. Patel, Int. J. Res. Dev. Technol. 4, 26 (2015).
R.J. Cava, J. Mater. Chem. 11, 54 (2001).
S.-O. Yoon, D.-K. Choi, J.-H. Oh, and S. Kim, J. Korean Ceram. Soc. 55, 364 (2018).
H.J. Jo and E.S. Kim, Ceram. Int. 42, 5479 (2016).
S.H. Kim and E.S. Kim, Ceram. Int. 42, 15035 (2016).
A. Kan and H. Ogawa, J. Alloys Compd. 364, 249 (2004).
A. Kan, H. Ogawa, A. Yokoi, and Y. Nakamura, J. Eur. Ceram. Soc. 27, 2977 (2007).
A. Kan and H. Ogawa, 2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics, IEEE. 519 (2007).
H. Ogawa, H. Taketani, A. Kan, A. Fujita, and G. Zouganelis, J. Eur. Ceram. Soc. 25, 2859 (2005).
A. Kan, H. Ogawa, A. Yokoi, and H. Osato, Jpn. J. Appl. Phys. 42, 6154 (2003).
H.T. Wu and L.X. Li, J. Sol-Gel Sci. Tech. 58, 48 (2011).
J.H. Kim and E.S. Kim, Ceram. Int. 43, S339 (2017).
L. Pauling, J. Am. Chem. Soc. 54, 3570 (1932).
T. Roisnel and J.R. Carvajal, WinPLOTR Mater. Sci. Forum 378–381, 118 (2001).
N. Kumada, K. Taki, and N. Kinomura, Mater. Res. Bull. 37, 1017 (2000).
T. Nishikawa, K. Wakino, H. Tamura, H. Tanaka, and Y. Ishikawa, Microw. Symp. Dig. 87, 277 (1987).
C.B.W. Hakki and P.D. Coleman, Microw. Theory Tech. 8, 402 (1960).
K. Sreedhar and N.R. Pavaskar, Mater. Lett. 53, 452 (2002).
Q. Liao, L. Li, P. Zhang, L. Cao, and Y. Han, Mater. Sci. Eng. B 176, 41 (2011).
Y.B. Chen, Jpn. J. Appl. Phys. 51, 085804 (2012).
D.M. Iddles, A.J. Bell, and A.J. Moulson, J. Mat. Sci. 27, 6303 (1992).
I.D. Brown and D. Altermatt, Acta Crystallogr. B 41, 244–247 (1985).
I.D. Brown and K.U. Kang, Acta Crystallogr. B 32, 1957 (1976).
J. Li, Y. Han, T. Qiu, and C. **, Mater. Res. Bull. 47, 2375 (2012).
R.D. Shannon, Acta Crystallogr. A 32, 751 (1976).
R.D. Shannon, J. Appl. Phys. 73, 348 (1993).
A.J. Bosman and E.E. Havinga, Phys. Rev. 129, 1593 (1963).
P. Liu, E.S. Kim and K.H. Yoon, Jpn. J. Appl. Phys. 40, 5769–5773 (2001).
E.L. Colla, I.M. Reaney, and N Setter, J. Appl. Phys. 74, 3414 (1993).
Acknowledgment
This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science, and Technology (2015R1D1A1A09061528).
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Kim, J.H., Kim, E.S. Effect of Isovalent Substitution on Microwave Dielectric Properties of Mg4Nb2O9 Ceramics. J. Electron. Mater. 48, 2411–2417 (2019). https://doi.org/10.1007/s11664-019-06995-0
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DOI: https://doi.org/10.1007/s11664-019-06995-0