Abstract
Chromitites associated with intensely altered dunites and harzburgites from fourteen different localities in the Islahiye ophiolites (SE Anatolia) is reported here for the first time. These chromitites were observed as lenticular and banded bodies with disseminated and massive textures and containing magnesiochromite grains with the following composition: Cr2O3 = 58.91–59.74 wt%, Al2O3 = 10.85–11.20 wt%, and TiO2 = 0.09–0.13 wt%. The Mg# [Mg/ (Mg + Fe2+)] values of magnesiochromite from the Islahiye ophiolite range between 0.52 and 0.60 and their Cr# [Cr/ (Cr + Al)] values vary from 0.7802 to 0.7844. These contents vary with a constant pattern, coincident with the estimated parental liquids that have originated from the derivative of a single bulk of boninitic magma together with Al, Ti-poor, and Cr-rich initial contents. The chromitites are serpentinised in almost all parts of the study area, and harzburgite and dunite can be observed in different locations. Although the overall composition of platinum group elements (PGE) in most examined chromitites varies between 97 and 191 ppb, three chromitites from the Islahiye region present enrichments in overall PGE (up to 214 ppb). The mineralogical and geochemical features of chromitites from the Islahiye region exhibit a robust similarity to podiform chromitites in the mantle fragment of supra–subduction zone type ophiolitic bodies. The estimated parental magmas of the investigated chromites are consistent with the differentiation of arc-related melts and do not suggest an oceanic spreading centre tectonic environment. The Islahiye chromites are enriched in IPGE (Ir, Os, Ru), with the occasional presence of Ru and Ir and higher Os contents in chromite. Furthermore, we did not find any platinum group minerals (PGM) associated with the serpentine silicate sample matrix, which would have stated a secondary enrichment in PGEs. All chromitites in the investigated region have high Cr and low Ti values, are defined as magnesiochromite and were crystallised from a characteristic boninitic magma.
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References
Akbulut M (2009) Güneybati Anadolu Kromit Yataklarinin Platin Grubu Element (PGE) Potansiyelleri, Dokuz Eylül Üniversitesi Fen Bilimleri Enstitüsü Doktora Tezi, Ankara, 181 syf (in Turkish with English abstract)
Akmaz RM, Uysal I, Saka S (2014) Compositional variations of chromite and solid inclusions in ophiolitic chromitites from the southeastern Turkey: Implications for chromitite genesis. Ore Geol Rev 58:208–224. https://doi.org/10.1016/j.oregeorev.2013.11.007
Arai S (1992) Chemistry of chromian spinel in volcanic rocks as a potential guide to magma chemistry. Mineral Mag 56:173–184. DOI: https://doi.org/10.1180/minmag.1992.056.383.04
Armstrong JT (1988) Quantitative analysis of silicates and oxide minerals: Comparison of Monte-Carlo, ZAF and Phi-Rho-Z procedures, Microbeam Analysis, 239-246.
Atan OR (1969) Eğribucak-Karacaören (Hassa)-Ceylanlı-Dazevleri (Kırıkhan) arasındaki Amanos dağlarının jeolojisi [The geology of the Amanos mountains among the Eğribucak-Karacaören (Hassa)-Ceylanlı-Dazevleri (Kırıkhan)]. General Directorate of Mineral Research and Exploration (MTA) Publication: 139 (in Turkish with English abstract)
Augé T, Maurizot P (1995) Stratiform and alluvial platinum mineralization in the New Caledonia ophiolite complex. Can Mineral 33:1023–1045
Bacuta GC, Kay RW, Gibbs AK, Lipin BR (1990) Platinum–group element abundance and distribution in chromite deposits of the Acoje block, Zambales ophiolite complex Philippines. J Geochem Explor 37:113–145. https://doi.org/10.1016/0375-6742(90)90086-P
Bağcı U (2013) The geochemistry and petrology of the ophiolitic rocks from the Kahramanmaraş region, Southern Turkey. Turk J Earth Sci 22:536–562. https://doi.org/10.3906/yer-1203-1
Barnes SJ, Roeder PL (2001) The range of spinel compositions in terrestrial mafic and ultramafic rocks. J Petrol 42:2279–2302. https://doi.org/10.1093/petrology/42.12.2279
Bonavia FF, Diella V, Ferrario A (1993) Precambrian podiform chromitites from Kenticha Hill, Southern Ethiopia. Econ Geol 88:198–202. https://doi.org/10.2113/gsecongeo.88.1.198
Çiftçi Y, Dönmez C, Parlak O, Günay K (2019) Chromitite Deposits of Turkey in Tethyan Ophiolites. In: Pirajno F., Ünlü T., Dönmez C., Şahin M. (eds) Mineral Resources of Turkey. Modern Approaches in Solid Earth Sciences, 73–157. https://doi.org/10.1007/978-3-030-02950-0_3
Donovan JJ, Snyder DA, and Rivers ML (1993) An improved interference correction for trace element analysis in microbeam analysis, 2, 23-28.
Dubertret L (1955) Géologie des roches vertes du nord-ouest de la Syrie et du Hatay (Turquie). Notes Mémoires Moyen-Orient 6:227
Engin T, Özkoçak O, Artan U (1986) General geological set ting and character of chromite deposits in Turkey. In: Pe-trascheck W, Karamata S, Kravchenko GG, Johan J, Economou M, Engin T (eds) Chromites. Theophrastus Publ. S.A., Athens, pp 199–228
González-Jiménez JM, Griffin WL, Gervilla F, Proenza JA, O’Reilly SY, Pearson NJ (2014a) Chromitites in ophiolites: how, where, when, why?, Part 1. A review and new ideas on the origin and significance of platinum–group minerals. Lithos 189:127–139. https://doi.org/10.1016/j.lithos.2013.06.016
González-Jiménez JM, Griffin WL, Proenza JA, Gervilla F, O’Reilly SY, Akbulut M, Pearson NJ, Arai S (2014b) Chromitites in ophiolites: how, where, when, why? Part II. The crystallization of chromitites. Lithos 189:140–158. https://doi.org/10.1016/j.lithos.2013.09.008
Graham IT, Franklin BJ, Marshall B (1996) Chemistry and mineralogy of podiform chromitite deposits, Southern NSW, Australia: a guide to their origin and evolution. Mineral Petrol 37:129–150. https://doi.org/10.1007/BF01162355
Harris DC, Cabri LJ (1991) Nomenclature of platinum–group–element alloys: Review and revision. Can Mineral 29:231–237
Hirose K, Kawamoto T (1995) Hydrous partial melting of lherzolite at 1 GPa: The effect of H2O on the genesis of basaltic magmas. Earth and Planetary Science Letters Volume 133:(3–4):463–473. https://doi.org/10.1016/0012-821X(95)00096-U
Kamenetsky VS, Crawford AJ, Meffre S (2001) Factors controlling chemistry of magmatic spinel: an empirical study of associated olivine, Cr–spinel and melt inclusions from primitive rocks. J Petrol 42:655–671. https://doi.org/10.1093/petrology/42.4.655
Kapsiotis A, Grammatikopoulos AT, Tsikouras B, Hatzipanagiotou K, Zaccarini F, Garuti G (2011) Mineralogy, composition and PGM of chromitites from Pefki, Pindos ophiolite complex (NW Greece): evidence for progressively elevated ƒAs conditions in the upper mantle sequence. Mineral Petrol 101:129–150. https://doi.org/10.1007/s00710-010-0140-8
Kozlu-Erdal H, Melcher F (2007a) Mineralogy and geochemistry of platinum-group element enrichments in Berit (Maraş) chromitites, southeastern Turkey. European Geosciences Union General Assembly, abs
Kozlu-Erdal H, Melcher F (2007b) Berit (Kahramanmaraş) metaofiyoliti kromititlerindeki platin grubu elementler ve mineral zenginleşmesinin jeokimyası, mineralojisi ve petrolojisi, Güneydoğu Türkiye. 60. Türkiye Jeoloji KurultayıBildiri Özleri, 16–22 Nisan 2007, Ankara, pp. 205–208. (in Turkish with English abstract)
Leblanc M (1997) Chromitite and ultramafic rock compositional zoning through a paleotransform fault, Poum, New Caledonia. Econ Geol 92:503–504. https://doi.org/10.2113/gsecongeo.92.4.503
MTA (General Directrorate of Mineral Research and Exploration) (2015) Vertical stratigraphic section and Geological Map of Islahiye, Ankara–Turkey
Nurlu N, Parlak O, Robertson AHF, Quadt A (2016) Implications of Late Cretaceous U–Pb zircon ages of granitic intrusions cutting ophiolitic and volcanogenic rocks for the assembly of the Tauride allochton in SE Anatolia (Helete area, Kahramanmaraş region, SE Turkey). Int J Earth Sci 105:283–314. https://doi.org/10.1007/s00531-015-1211-1
Prichard HM, Neary CR, Fisher FC, O’Hara MJ (2008) PGE–rich podiform chromitites in the Al’Ays ophiolite complex, Saudi Arabia: an example of critical mantle melting to extract and concentrate PGE. Econ Geol 103:1507–1529. https://doi.org/10.2113/gsecongeo.103.7.1507
A. H. F., Robertson O., Parlak T., Rízaoğlu Ü., Ünlügenç N., İnan K., Tasli T., Ustaömer (2007) (2007) Tectonic evolution of the South Tethyan ocean: evidence from the Eastern Taurus Mountains (Elaziğ region SE Turkey). Geological Society London Special Publications 272(1) 231-270 10.1144/GSL.SP.2007.272.01.14
Robertson AHF, Ustaömer T (2009) Formation of the Late Palaeozoic Konya Complex and comparable units in southern Turkey by subduction-accretion processes: Implications for the tectonic development of Tethys in the Eastern Mediterranean region. Tectonophysics 473:113–148. https://doi.org/10.1016/j.tecto.2008.10.027
Pagé P, Barnes SJ (2009) Using trace elements in chromites to constrain the origin of podiform chromitites in the Thetford Mines Ophiolite, Quebec, Canada. Econ Geol 104:997–1018. https://doi.org/10.2113/econgeo.104.7.997
Sengör AMC, Yilmaz Y (1981) Tethyan evolution of Turkey: Plate tectonic approach. Tectonopysics 75:181–241. https://doi.org/10.1016/0040-1951(81)90275-4
Stowe CW (1994) Compositions and tectonic settings of chromite deposits through time. Econ Geol 89:528–546. https://doi.org/10.2113/gsecongeo.89.3.528
Su B, Liu X, Chen C, Robinson PT, **ao Y, Zhou M, Bai Y, Uysal İ, Zhang P (2021) A new model for chromitite formation in ophiolites: Fluid immiscibility. Sci China Earth Sci 64:220–230. https://doi.org/10.1007/s11430-020-9690-4
Tanırlı M, Rızaoglu T (2016) Whole–rock and mineral chemistry of mafic cumulates from the Low–Ti ophiolite in the southern part of Kahramanmaras, Turkey, Russian Geology and Geophysics Volume 57, Issue 10, October 2016, pp. 1398–1418. https://doi.org/10.1016/j.rgg.2016.01.018
Uysal I, Akmaz RM, Kapsiotis A, Demir Y, Saka S, Avci E, Müller D (2015) Genesis and geodynamic significance of chromitites from the Orhaneli and Harmancık ophiolites (Bursa, NW Turkey) as evidenced by mineralogical and compositional data. Ore Geol Rev 65:26–41. https://doi.org/10.1016/j.oregeorev.2014.08.006
Uysal I, Sadiklar MB, Tarkian M, Karsli O, Aydin F (2005) Mineralogy and composition of the chromitites and their platinum–group minerals from Ortaca (Muğla SW Turkey): evidence for ophiolitic chromitite genesis. Mineral Petrol 83:219–242. https://doi.org/10.1007/s00710-004-0063-3
Uysal I, Tarkian M, Sadıklar MB, Sen C (2007) Platinum group–elementgeochemistry and mineralogy of ophiolitic chromitites from the Kop Mountains, Northeastern Turkey. Can Mineral 45:355–377. https://doi.org/10.2113/gscanmin.45.2.355
Yang K, Seccombe PK (1993) Platinum–group minerals in the chromitites fromthe Great Serpentinite belt, NSW, Australia. Mineral Petrol 47:263–286. https://doi.org/10.1007/BF01161571
Yilmaz Y, Demirkol C, Yalçin N, Yiğitbaş E, Gürpınar O, Yetiş C, Günay Y, Saritaş B (1984) Amanos Dağlarinin Jeolojisi, II Ofiyolit [The geology of the Amanos mountains, II Ophiolite]. İstanbul Teknik Üniversitesi Mühendislik Fakültesi Publication 351. (in Turkish with English abstract)
Yilmaz Y, Yigitbas E, Genc SC (1993) Ophiolitic and metamorphic ssemblages of Southeast Anatolia and their significance in the geological evolution of the orogenic belt. Tectonics 12:1280–1297. https://doi.org/10.1029/93TC00597
Zhou M, Robinson PT, Su B, Gao J, Li J, Yang J, Malpas J (2014) Compositions of chromite, associated minerals, and parental magmas of podiform chromite deposits: The role of slab contamination of asthenospheric melts in suprasubduction zone environments. Gondwana Res 26:262–283. https://doi.org/10.1016/j.gr.2013.12.011
Acknowledgements
This paper is based on the M.Sc. study of the second author. The authors would like to thank Çukurova University Research Foundation for their support (Project No: FYL-2018-10437; FBA-2021-13093). The authors would like to give special thanks to Dr. Andrew LOCOCK (Alberta University, CANADA) for performing mineral chemistry analyses. The authors are also indebted to the anonymous reviewers and the editor of the journal for their constructive comments and suggestions, which greatly helped to improve the manuscript.
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Nil YAPICI: Conceptualization, data collection, investigation, validation, writing review and editing. Gael Calo sinda NGBANGANDIMBO: Conceptualization, data collection, writing original draft, formal analysis, and methodology. Nusret NURLU: Conceptualization, data collection, writing original draft, formal analysis, and methodology.
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Yapici, N., sinda Ngbangandimbo, G.C. & Nurlu, N. Geodynamic significance and genesis of chromitites from the Islahiye ophiolite (Gaziantep, SE Anatolia) as constrained by platinum group element (PGE) compositions and mineral chemistry characteristics. Acta Geochim 41, 741–752 (2022). https://doi.org/10.1007/s11631-022-00541-2
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DOI: https://doi.org/10.1007/s11631-022-00541-2