Abstract
Aniline and its derivate are critical environmental pollutants, and thus, the introduction of an eco-friendly catalyst for removing them is an important research future. The ZnO supported on the ball-mill prepared clinoptilolite nanoparticles (CNPs) was prepared via an ion-exchange process followed by the calcination process. The amount of loaded ZnO in the ZnO-CNP (CZ) samples varied as 0.54, 0.63, 0.72, and 0.86 meq/g as the Zn(II) concentration in the ion-exchange solution varied from 0.1 to 0.5 M. The ZnO-CNP catalyst was briefly characterized by XRD, FTIR, and DRS techniques. The pHpzc value for the various ZnO-CNPs was about 7.1 that had no change with the ZnO loading. By applying the Scherrer equation on the XRD results, a nano-dimension of about 50 nm was obtained for the catalyst. Bandgap energy of the ZnO-CNP samples was estimated by applying the Kubelka-Munk equation on the DRS reflectance spectra. The value for the CZ2 catalyst was about 3.64 eV. The supported ZnO-CNP sample was then used in the photodegradation of 2,4-dichloroaniline (DCA). Raw zeolite showed a relatively low photocatalytic activity. The degradation efficiency was followed by recording the absorbance of the DCA solution by UV-Vis spectrophotometer. The effects of the essential critical operating factors on the degradation efficiency were kinetically studied by applying the Hinshelwood equation to the results. The ZnO-CNP catalyst with 2 w% ZnO showed the best photocatalytic rate in the optimal conditions of 0.75 g/L, CDCA: 15 ppm, and the initial pH: 5.8. Finally, HPLC analysis of the blank and the photodegraded DCA solutions at 180 and 300 min confirmed 74 and 87% of DCA molecules were degraded during these times. The results confirm that supported ZnO onto clinoptilolite caused enhanced photocatalytic activity because the zeolite internal electrical field prevents the e−/h+ recombination.
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References
Abbasi M, Nazifi SMR, Nazifi ZS, Massah AR (2017) Synthesis, characterization and in vitro antibacterial activity of novel phthalazine sulfonamide derivatives. J Chem Sci 129(8):1257–1266
Aghdasi S, Shokri M (2016) Photocatalytic degradation of ciprofloxacin in the presence of synthesized ZnO nanocatalyst: the effect of operational parameters. Iran J Catal 6(5):481–487
Ahmad Bhat S, Zafar F, Hossain Mondal A, Kareem A, UllahMirza A, Khan S, Mohammad A, RizwanulHaq Q, Nishat N (2020) Photocatalytic degradation of carcinogenic Congo red dye in aqueous solution, antioxidant activity and bactericidal effect of NiO nanoparticles. J Iran Chem Soc 17:215–227
Akyuz M, Ata S (2006) Simultaneous determination of aliphatic and aromatic amines in water and sediment samples by ion-pair extraction and gas chromatography–mass spectrometry. J Chromatogr A 1129:88–94
Arabpour N, Nezamzadeh-Ejhieh A (2015) Modification of clinoptilolitenano-particles with iron oxide: increased composite catalytic activity for photodegradation of cotrimaxazole in aqueous suspension. Mater Sci Semicond Process 31:684–692
Arunkumar M, Samson Nesaraj A (2020) Photocatalytic degradation of malachite green dye using NiAl2O4 and Co doped NiAl2O4 nanophotocatalysts prepared by simple one pot wet chemical synthetic route. Iran J Catal 10(3):235–245
Assi N, Tehrani MS, AberoomandAzar P, Husain Syed W (2017) Microwave-assisted sol–gel synthesis of Fe2.9O4/ZnO core/shell nanoparticles using ethylene glycol and its use in photocatalytic degradation of 2-nitrophenol. J Iran Chem Soc 14:221–232
Azimi S, Nezamzadeh-Ejhieh A (2015) Enhanced activity of clinoptilolite-supported hybridized PbS–CdS semiconductors for the photocatalytic degradation of a mixture of tetracycline and cephalexin aqueous solution. J Molecul Catal A: Chem 408:152–160
Balakrishnan M, John R (2020) Properties of sol-gel synthesized multiphase TiO2 (AB)-ZnO (ZW) semiconductor nanostructure: an effective catalyst for methylene blue dye degradation. Iran J Catal 10(1):1–16
Behin J, Ghadamnan E, Kazemian H (2019) Recent advances in the science and technology of natural zeolites in Iran. Clay Miner 54:131–144
Bindu P, Thomas S (2014) Estimation of lattice strain in ZnO nanoparticles: X-ray peak profile analysis. J Theoretical Appl Phys 8:123–134
Bordbar M, Vasegh Seyed M, Jafari S, Yeganeh Faal A (2015) Optical and photocatalytic properties undoped and Mn-doped ZnO nanoparticles synthesized by hydrothermal method: effect of annealing temperature. Iran J Catal 5(2):135–141
Bordbar M, Forghani-pilerood S, Yeganeh-Faal A (2016) Enhanced photocatalytic activity of sonochemical derived ZnO via the co-do** process. Iran J Catal 6(5):415–421
Bunluesak T, Phuruangrat A, Teppetcharat J, Patiphatpanya P, Dumrongrojthanath P, Thongtem S, Thongtem T (2020) Enhanced visible-light-driven Pd/Bi2WO6 heterojunctions used for photodegradation of rhodamine B. J Iran Chem Soc 18:1103–1111. https://doi.org/10.1007/s13738-020-02095-7
Chahkandi M, SaadatdarArami Seyedeh R, Mirzaei M, Mahdavi B, Hosseini-Tabar Seyed M (2019) A new effective nano-adsorbent and antibacterial material of hydroxyapatite. J Iran Chem Soc 16:695–705
Derikvandi H, Nezamzadeh-Ejhieh A (2017) Increased photocatalytic activity of NiO and ZnO in photodegradation of a model drug aqueous solution: effect of coupling, supporting, particles size and calcination temperature. J Hazard Mater 321:629–638
Derikvandi H, Vosough M, Nezamzadeh Ejhieh A (2020) A comprehensive study on the enhanced photocatlytic activity of a double-shell mesoporousplasmonic Cu@Cu2O/SiO2 as a visible-light driven nanophotocatalyst. Environ Sci Pollut Res 27:27582–27597. https://doi.org/10.1007/s11356-020-08817-x
Dharmraj Khairnar S, Rajendra Patil M, Shankar Shrivastava V (2018) Hydrothermally synthesized nanocrystalline Nb2O5 and its visible-light photocatalytic activity for the degradation of congo red and methylene blue. Iran J Catal 8(2):143–150
Dianat S (2018) Visible light induced photocatalytic degradation of direct red 23 and direct brown 166 by InVO4-TiO2 nanocomposite. Iran J Catal 8(2):121–132
Divband B, Jodaie A, Khatmian M (2019) Enhancement of photocatalytic degradation of 4-nitrophenol by integrating Ag nanoparticles with ZnO/HZSM-5 nanocomposite. Iran J Catal 9:63–70
Ehsani A, Asgari R, Rostami-Vartooni A, Mohammad Shiri H, Yeganeh Faal (2016) A, Facile and green synthesis of CuO nanoparticles and electrocatalytic activity of CuO nanoparticles/conductive polymer composite film. Iran J Catal 6(3):269–274
Eslami A, Oghazyan A, Sarafraz M (2018) Magnetically separable MgFe2O4 nanoparticle for efficient catalytic ozonation of organic pollutants. Iran J Catal 8(2):95–102
Faghihian H, Talebi M, Pirouzi M (2008) Adsorption of nitrogen from natural gas by clinoptilolite. J Iran Chem Soc 5:394–399
Fulazzaky MA, Majidnia Z, Idris A (2017) Mass transfer kinetics of Cd(II) ions adsorption by titania polyvinylalcohol-alginate beads from aqueous solution. Chem Eng J 308:700–709
Ghattavi S, Nezamzadeh-Ejhieh A (2019) A brief study on the boosted photocatalytic activity of AgI/WO3/ZnO in the degradation of Methylene Blue under visible light irradiation. Desal Water Treat 166:92–104
Giahi M, Hoseinpour Dargahi A (2016) Photocatalytic degradation of phenylephrine hydrochloride in aqueous solutions by synthesized SnO2-doped ZnO nanophotocatalyst. Iran J Catal 6(4):381–387
Habibi MH, Askari E (2011) Photocatalytic degradation of an azo textile dye with manganese-doped ZnO nanoparticles coated on glass. Iran J Catal 1:41–44
aHassani A, Eghbali P, Metin Ö (2018), Sonocatalytic removal of methylene blue from water solution by cobalt ferrite/mesoporous graphitic carbon nitride (CoFe2O4/mpg-C3N4) nanocomposites: response surface methodology approach, Environ Sci Pollut Res 25: 32140–32155.
bHassani A, Eghbali P, Kakavandi B, Lin K Y A, Ghanbari F (2020) Acetaminophen removal from aqueous solutions through peroxymonosulfate activation by CoFe2O4/mpg-C3N4 nanocomposite: insight into the performance and degradation kinetics. Environ Technol Innov 20: 101127.
Honarmand M, Golmohammadi M, Hafezi-bakhtiari J (2020) Synthesis and characterization of SnO2 NPs for photodegradation of eriochrome black-T using response surface methodology. Environ Sci Pollut Res 28:7123–7133. https://doi.org/10.1007/s11356-020-11086-3
Huang Y, Xu H, Luo D, Guo Q (2019) Visible light-driven flower-like Bi/BiOClxBr(1−x)heterojunction with excellent photocatalytic performance. J Iran Chem Soc 16:2743–2275
aIazdani F, Nezamzadeh-Ejhieh A (2020) Photocatalytic kinetics of 2,4-dichloroaniline degradation by NiO-clinoptilolite nanoparticles, Spectrochim. Acta Part A: Mol Biomol Spect 119228.
bIazdani F, Nezamzadeh-Ejhieh A (2021) Supported cuprous oxide-clinoptilolite nanoparticles: brief identification and the catalytic kinetics in the photodegradation of dichloroaniline, Spectrochim. Acta Part A: Mol Biomol Spect 250 (2021) 119348.
Javad Kalbasi R, Massah R, Daneshvarnejad B (2012) Preparation and characterization of bentonite/PS-SO3H nanocomposites as an efficient acid catalyst for the Biginelli reaction. Appl Clay Sci 55:1–9
Karimi Shamsabadi M, Behpour M (2021) Fabricated CuO–ZnO/nanozeolite X heterostructure with enhanced photocatalytic performance: mechanism investigation and degradation pathway. Mater Sci Eng B 269:115170
Karimi Shamsabadi M, Behpour M, Kazemi Babaheidari A, Saberi Z (2017) Efficiently enhancing photocatalytic activity of NiO-ZnO doped onto nanozeoliteX by synergistic effects of p-n heterojunction, supporting and zeolite nanoparticles in photo-degradation of Eriochrome Black T and Methyl Orange. J Photochem Photobiol A Chem 346:133–143
dKarimi-Maleh H, Ganesh Kumar B, Rajendran S, Qin J, Vadivel S, Durgalakshmi D, Gracia F, Soto-Moscoso M, Orooji Y, Karimi F (2020a) Tuning of metal oxides photocatalytic performance using Ag nanoparticles integration, J Mol Liq 314: 113588.
eKarimi-Maleh H, Shafieizadeh M, Taher M A, Opoku F, Kiarii E M, Govender P P, Ranjbari S, Rezapour M, Orooji Y (2020b) The role of magnetite/graphene oxide nano-composite as a high-efficiency adsorbent for removal of phenazopyridine residues from water samples, an experimental/theoretical investigation, J Mol Liq 298: 112040.
aKarimi-Maleh H, Ranjbari S, Tanhaei B, Ayati A, Orooji Y, Alizadeh M, Karimi F, Salmanpour S, Rouhi J, Sillanpää M, Sen F (2021a) Novel 1-butyl-3-methylimidazolium bromide impregnated chitosan hydrogel beads nanostructure as an efficient nanobio-adsorbent for cationic dye removal: Kinetic study, Environ Res 195: 110809.
bKarimi-Maleh H, Lütfi Yola M, Atar N, Orooji Y, Karimi F, Senthil Kumar P, Rouhi J, Baghayeri M (2021b) A novel detection method for organophosphorus insecticide fenamiphos: molecularly imprinted electrochemical sensor based on core-shell Co3O4@MOF-74 nanocomposite, J Colloid Interface Sci 592: 174–185.
cKarimi-Maleh H, Ayati A, Ghanbari S, Orooji Y, Tanhaei B, Karimi F, Alizadeh M, Rouhi J, Fu L, Sillanpää M (2021c) Recent advances in removal techniques of Cr(VI) toxic ion from aqueous solution: a comprehensive review, J Mol Liq 329: 115062.
fKarimi-Maleh H, Ayati A, Davoodi R, Tanhaei B, Karimi F, Malekmohammadi S, Orooji Y, Fu L, Sillanpää M (2021d) Recent advances in using of chitosan-based adsorbents for removal of pharmaceutical contaminants: a review, J Clean Prod 291: 125880.
Khanmohammadi M, Rahbar Shahrouzi J, Rahmani F (2020) Insights into mesoporous MCM-41-supported titania decorated with CuO nanoparticles for enhanced photodegradation of tetracycline antibiotic. Environ Sci Pollut Res 28:862–879. https://doi.org/10.1007/s11356-020-10546-0
Khodadadi B, Bordbar M (2016) Sonochemical synthesis of undoped and Co-doped ZnO nanostructures and investigation of optical and photocatalytic properties. Iran J Catal 6(1):37–42
Khozeymeh Nezhad M, Aghaei H (2021) Tosylated cloisite as a new heterofunctional carrier for covalent immobilization of lipase and its utilization for production of biodiesel from waste frying oil. Renew Energy 164:876–888
Koc SO, Koseoglu K, Galioglu S, Akata B, Salamov BG (2016) Effects of pressure and electricfield on the charge transport mechanisms in the silver-modified-zeolite porous microstructure. Microporous Mesoporous Mater 223:18–26
aMajidnia Z, Fulazzaky M A (2016) Photoreduction of Pb(II) ions from aqueous solution by titania polyvinylalcohol–alginate beads, J Taiwan Inst Chem Eng 66: 88-96.
bMajidnia Z, Fulazzaky M A (2017) Photocatalytic reduction of Cs(I) ions removed by combined maghemite-titania PVA-alginate beads from aqueous solution, J Environ Manag 191: 219-227.
Massah AR, Azadi D, Aliyan H, Momeni AR, Naghash HJ, Kazemi F (2008) An efficient method for the synthesis of N-Acylsulfonamides: one-pot sulfonylation and acylation of primary arylamines under solvent-free conditions. Monatsh Chem 139:233–240
Massah AR, Javad Kalbasi R, Kaviyani S (2013) Synthesis, characterization, and application of a manganese Schiff base complex containing heterogeneous hybrid catalyst. RSC Adv 3:12816–12825
Matei E, Enculescu M, Preda N, Enculescu I (2012) ZnO morphological, structural and optical properties control by electrodeposition potential sweep rate. Mater Chem Phys 134:988–993
Millot Y, Man P. P, Springuel-Huet M, Fraissard J (2004) Quantification of electric-field gradients in the supercage of HY, steam-dealuminated Y and lanthanum-exchanged Y zeolites by 129Xe and 131Xe NMR or physisorbed xenon gas, Stud Surf Sci Catal 154, Part B: 1400-1405.
Mohamed JafferSadiq M, Samson Nesaraj A (2014) Reflux condensation synthesis and characterization of Co3O4 nanoparticles for photocatalytic applications. Iran J Catal 4(4):219–226
Mohammadi V, Tabatabaee M, Fadaei A, Mirhoseini Seyed A (2020) Comparing activated carbon and magnetic activated carbon in removal of linear alkylbenzenesulfonate from aqueous solution by heterogeneous catalytic ozonation process. Iran J Catal 10(3):209–218
Mortazavi S, Aghaei A (2020) Make proper surfaces for immobilization of enzymes: immobilization of lipase and α-amylase on modified Na-sepiolite. Int J Biol Macromol 164:1–12
Movahedi M, Mahjoub AR, Janitabar-Darzi S (2009) Photodegradation of Congo red in aqueous solution on ZnO as an alternative catalyst to TiO2. J Iran Chem Soc 6:570–577
Muhammad W, Ullah N, Haroon M, Haider Abbasi B (2019) Optical, morphological and biological analysis of zinc oxide nanoparticles (ZnO NPs) using Papaversomniferum. L RSC Adv 9:29541–29548
Naderi Asrami P, Karimi-Maleh H (2021) A critical review on the use of potentiometric based biosensors for biomarkers detection. Biosens Bioelectron 184:113252
Naderpour H, Noroozifar M, Khorasani-Motlagh M (2013) Photodegradation of methyl orange catalyzed by nanoscalezerovalent iron particles supported on natural zeolite. J Iran Chem Soc 10:471–479
Nagaraju G, Udayabhanu S, Prashanth SA, Shastri M, Yathish KV, Anupama C, Rangappa D (2017) Electrochemical heavy metal detection, photocatalytic, photoluminescence, biodiesel production and antibacterial activities of Ag–ZnO nanomaterial. Mater Res Bull 94:54–63
Nezamzadeh-Ejhieh A, Salimi Z (2011) Solar photocatalytic degradation of o-phenylenediamine by heterogeneous CuO/X zeolite catalyst. Desalination 280:281–287
Nezamzadeh-Ejhieh A, Zabihi-Mobarakeh H (2014) Heterogeneous photodecolorization of mixture of methylene blue and bromophenol blue using CuO-nano-clinoptilolite. J Ind Eng Chem 20:1421–1431
Ng Y-C (2011) Shamsuddin M, Solid state morphology and band gap studies of ETS-10 supported CdS nanoparticles. J Iran Chem Soc 8:S28–S33
Nobahari MH, Golikand AN, Bagherzadeh M (2017) Synthesis and characterization of Pt3Co bimetallic nanoparticles supported on MWCNT as an electrocatalyst for methanol oxidation. Iran J Catal 7(4):327–335
Norouzi Esfahani R, Khaghani S, Azizi A, Gomarian M (2020) Facile and eco-friendly synthesis of TiO2 NPs using extracts of Verbascumthapsus plant: an efficient photocatalyst for reduction of Cr(VI) ions in the aqueous solution. J Iran Chem Soc 17:205–213
Nosuhi M, Nezamzadeh-Ejhieh A (2018) An indirect application aspect of zeolite modified electrodes for voltammetric determination of iodate. J Electroanal Chem 810:119–128
Olad A, Khatamian M, Naseri B (2011) Removal of toxic hexavalent chromium by polyaniline modified clinoptilolite nanoparticles. J Iran Chem Soc 8:S141–S151
Omrani N, Nezamzadeh-Ejhieh A, Alizadeh M (2019) Brief study on the kinetic aspect of photodegradation of sulfasalazine aqueous solution by cuprous oxide/cadmium sulfide nanoparticles. Desal Water Treat 162:290–302
Palma TL, Vieira B, Nunes J, Lourenço JP, Monteiro OC, Costa MC (2020) Photodegradation of chloramphenicol and paracetamol using PbS/TiO2 nanocomposites produced by green synthesis. J Iran Chem Soc 2020:2013–2031. https://doi.org/10.1007/s13738-020-01906-1
Pande UC, Dwivedi AH (2011) Methylene blue sensitized photodechlorination of isomeric mono- and dichloroanilines via molecular complex formation mechanism. E-J Chem 8:1086–1093
Pankaj R, Parwaz Khan AA, Singh A (2020) Construction of carbon nanotube mediated Fe doped graphitic carbon nitride and Ag3VO4 based Z-scheme heterojunction for H2O2 assisted 2, 4 dimethyl phenol photodegradation. Sep Purif Technol 247:116957
Pouretedal HR, Sohrabi AM (2016) Photosensitization of TiO2 by ZnS and bromothymol blue and its application in photodegradation of para-nitrophenol. J Iran Chem Soc 13:73–79
Pouretedal HR, Fallahgar M, Pourhasan FS, Nasiri M (2017) Taguchi optimization of photodegradation of yellow water of trinitrotoluene production catalyzed by nanoparticles TiO2/N under visible light. Iran J Catal 7(4):317–326
Pourshirband N,a Nezamzadeh-Ejhieh A (2020) Experimental design on determination of Sn(II) by the modified carbon paste electrode with Fe(II)-exchanged clinoptilolite nanoparticles, Solid State Sci 99: 106082.
Pourshirband N,b Nezamzadeh-Ejhieh A, Mirsattari Seyed N (2020), The coupled AgI/BiOI catalyst: synthesis, brief characterization, and study of the kinetic of the EBT photodegradation, Chem Phys Lett 761 (2020) 138090.
Pourshirband N, Nezamzadeh-Ejhieh A, Mirsattari Seyed N (2021) The CdS/g-C3N4 nano-photocatalyst: brief characterization and kinetic study of photodegradation and mineralization of methyl orange. Spectrochim Acta Part A: Mol Biomol Spect 248:119110
Rahimi B, Jafari N, Abdolahnejad A, Farrokhzadeh H, Ebrahimi A (2019) Application of efficient photocatalytic process using a novel BiVO/TiO2-NaY zeolite composite for removal of acid orange 10 dye in aqueous solutions: Modeling by response surface methodology (RSM). J Environ Chem Eng 7:103253
Rappoport Z.Z (2007) The chemistry of anilines: Part 1. The Chemistry of Functional Group Series, Wiley, New York.
Rashmi BN, Harlapur Sujatha F, Avinash B, Ravikumar CR, Nagaswarupa HP, Anil Kumar MR, Gurushantha K, Santosh MS (2020) Facile green synthesis of silver oxide nanoparticles and their electrochemical, photocatalytic and biological studies. Inorg Chem Commun 111:107580
Rostami-Vartooni A, Moradi-Saadatmand A, Bagherzadeh M, Mahdavi M (2019) Green synthesis of Ag/Fe3O4/ZrO2nanocomposite using aqueous Centaureacyanus flower extract and its catalytic application for reduction of organic pollutants. Iran J Catal 9:27–35
Segundo IR, Freitas E, Landi S Jr, Costa Manuel FM, Carneiro JO, Smart (2019) Photocatalytic and self-cleaning asphalt mixtures: a literature review. Coatings 9:696 (1-22 pages). https://doi.org/10.3390/coatings9110696
Seiied Bonakdar AP, Vafaei F, Farokhpour M, Nasr Esfahani MH, Massah AR (2017) Synthesis and anticancer activity assay of novel chalcone-sulfonamide derivatives, Iran. J Pharm Sci 16(2):565–568
Senobari S, Nezamzadeh Ejhieh A (2018) A p-n junction NiO-CdS nanoparticles with enhanced photocatalytic activity: a response surface methodology study. J Mol Liq 257:173–183
Shabani L, Aliyan H (2016) Synthesis and photocatalytic activity of nanosized modified mesocellulous silica foams (MCFs) with PW12 and vanadium oxide. Iran J Catal 6(3):221–228
Shah S, Hao C (2016) Density functional theory study of direct and indirect photodegradation mechanisms of sulfameter. Environ Sci Pollut Res 23:19921–19930
Shahwan T, Zünbül B, Tunusoğlu O, Eroğlu AE (2005) AAS, XRPD, SEM/EDS, and FTIR characterization of Zn2+ retention by calcite, calcite–kaolinite, and calcite–clinoptilolite minerals. J Colloid Interface Sci 286:471–478
Sharifian S, Nezamzadeh Ejhieh A (2016) Modification of carbon paste electrode with Fe(III)-clinoptilolite, nano-particles for simultaneous voltammetric determination of acetaminophen and ascorbic acid. Mater Sci Eng C 58:510–520
Sheetal S, Dutta V, Raizada P, Hosseini-Bandegharaei A, Singh P, Nguyen V-H (2021) Tailoring cadmium sulfide-based photocatalytic nanomaterials for water decontamination: a review. Environ Chem Lett 19:271–306
Sobhani-Nasab A, Eghbali-Aranib M, Hosseinpour-Mashkani Seyed M, Ahmadi F, Rahimi-Nasrabadi M, Ameri V (2020) Eco-friendly preparation and characterization of CuMn2O4 nanoparticles with the green cap** agent and their photocatalytic and photovoltaic applications. Iran J Catal 10(2):91
SowriBabu K, Ramachandra Reddy A, Sujatha C, Venugopal Reddy K, Mallika AN (2013) Synthesis and optical characterization of porous ZnO. J Adv Ceram 2:260–265
TalatMehrabad J, Partovi M, Arjomandi Rad F, Khalilnezhad R (2019) Nitrogen doped TiO2 for efficient visible light photocatalytic dye degradation. Iran J Catal 9(3):233–239
Thirumalai K, Balachandran S, Swaminathan M (2016) Superior photocatalytic, electrocatalytic, and self-cleaning applications of Fly ash supported ZnOnanorods. Mater Chem Phys 183:191–200
Vafayi L, Gharibe S (2015) Enhancement of photocatalytic activity of ZnO–SiO2 by nano-sized Pt for efficient removal of dyes from wastewater effluents. Iran J Catal 5(4):365–371
Vishal D, Sharma S, Raizada P, Hosseini-Bandegharaei A, Kaushal J, Singh P (2020) Fabrication of visible light active BiFeO3/CuS/SiO2 Z-scheme photocatalyst for efficient dye degradation. Mater Lett 270:127693
Yousefi F, Nezamzadeh-Ejhieh A (2020) Photodegradation of phenazopyridine in an aqueous solution by CdS-WO3 nanocomposite. Desal Water Treat 182:299–308
Yuonesi M, Pakdel A (2010) Effect of low concentration of nickel on structural and optical properties of ZnO nanofilms. Physica B 405:2083–2087
Zarei E, Jamali MR, Bagheri J (2018) Formaldehyde measurement based on its electrocatalytic oxidation by Ni-TiO2 nanoparticles/chitosan modified carbon paste electrode as an effective method. Iran J Catal 8(3):165–177
Zebardast M, FallahShojaei A, Tabatabaeian K (2018) Enhanced removal of methylene blue dye by bimetallic nano-sized MOF-5s. Iran J Catal 8(4):297–309
Zh B, Lin S (2009) Effects of 3,4-dichloroaniline on testicle enzymes as biological markers in rats. Biomed Environ Sci 22:40–43
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The authors thank Mohammad Alizadeh and Mohammad Hossein Kazemzadeh for performing instrumental analysis of the samples as experts in laboratory analysis in Shahreza Branch, Islamic Azad University, Isfahan, Iran. The authors also thank the university president for supporting this work.
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Alireza Nezamzadeh-Ejhieh: conceptualization, methodology, supervision, software, writing- reviewing and editing, validation, formal analysis, supervision; Fereshteh Iazdani: data curation, writing- original draft, visualization, investigation, resources, investigation.
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Iazdani, F., Nezamzadeh-Ejhieh, A. The photocatalytic rate of ZnO supported onto natural zeolite nanoparticles in the photodegradation of an aromatic amine. Environ Sci Pollut Res 28, 53314–53327 (2021). https://doi.org/10.1007/s11356-021-14544-8
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DOI: https://doi.org/10.1007/s11356-021-14544-8