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Application of magnetic nanoparticles coated with sodium dodecyl sulfate and modified with 2-(5-bromo-2-pyridylazo)-5-diethyl aminophenol as a novel adsorbent for dispersive-magnetic solid-phase extraction and determination of palladium in soil samples

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Abstract

A rapid, sensitive, precise, and accurate dispersive-magnetic solid-phase extraction technique combined with flame atomic absorption spectrometry was established for pre-concentration and separation of Pd (II) in soil samples. In the developed system, 5-amine-1,10-phenanthroline was used as synergistic complexant; sodium dodecyl sulfate and 2-(5-bromo-2-pyridylazo)-5-diethyl aminophenol ligand coated on magnetic nanoparticles were synthesized by a chemical precipitation method, and then employed as the efficient magnetic adsorbent with good magnetic properties and dispersibility. Various operational parameters affecting the extraction efficiency has been studied and optimized in details. Under the optimum experimental conditions, the detection limit of the mentioned method for palladium ions was 0.12 μg/L, while the relative standard deviation was 1.8%. Finally, the developed method was applied for the analysis of palladium ions in three kinds of soil samples and quantitative recoveries were achieved over the range of 96.7–104.0%. It can be a powerful alternative applied to the determination of traces of Pd ions from various real samples in further researches.

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References

  • Bagheri A, Taghizadeh M, Behbahani M, Asgharinezhad AA, Salarian M, Dehghani A, Ebrahimzadeh H, Amini MM (2012) Synthesis and characterization of magnetic metal-organic framework (MOF) as a novel sorbent, and its optimization by experimental design methodology for determination of palladium in environmental samples. Talanta 99(99):132–139. https://doi.org/10.1016/j.talanta.2012.05.030

    Article  CAS  Google Scholar 

  • Bakircioglu D (2012) Cloud point extraction for the preconcentration of palladium and lead in environmental samples and determination by flow injection flame atomic absorption spectrometry: CPE for preconcentration of Pd and Pb by FI-FAAS. Environ Sci Pollut Res 19(6):2428–2437. https://doi.org/10.1007/s11356-012-0755-x

    Article  CAS  Google Scholar 

  • Bayat M, Shemirani F (2015) Ionic liquid-modified Fe 3 O 4 nanoparticle combined with central composite design for rapid preconcentration and determination of palladium ions. Desalin Water Treat 56(3):814–825. https://doi.org/10.1080/19443994.2014.950987

    Article  CAS  Google Scholar 

  • Birinci E, Gülfen M, Aydın AO (2009) Separation and recovery of palladium(II) from base metal ions by melamine–formaldehyde–thiourea (MFT) chelating resin. Hydrometallurgy 95(1-2):15–21. https://doi.org/10.1016/j.hydromet.2008.04.002

    Article  CAS  Google Scholar 

  • Elci L, Soylak M, Buyuksekerci EB (2003) Separation of gold, palladium and platinum from metallurgical samples using an amberlite XAD-7 resin column prior to their atomic absorption spectrometric determinations. Anal Sci 19(12):1621–1624. https://doi.org/10.2116/analsci.19.1621

    Article  CAS  Google Scholar 

  • Godlewska-Żyłkiewicz B, Leśniewska B, Wawreniuk I (2010) Assessment of ion imprinted polymers based on Pd(II) chelate complexes for preconcentration and FAAS determination of palladium. Talanta 83(2):596–604. https://doi.org/10.1016/j.talanta.2010.10.005

    Article  Google Scholar 

  • Hu Q, Yang X, Huang Z, Chen J, Yang G (2005) Simultaneous determination of palladium, platinum, rhodium and gold by on-line solid phase extraction and high performance liquid chromatography with 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine as pre-column derivatization regents. J Chromatogr A 1094(1-2):77–82. https://doi.org/10.1016/j.chroma.2005.07.090

    Article  CAS  Google Scholar 

  • Jamali MR, Kazemi A (2014) Application of modified nano alumina as a solid phase extraction sorbent for the separation and preconcentration of manganese (II) in milk and water samples and its determination by flame atomic absorption spectrometry. Iranian J Anal Chem 1:36–43

    Google Scholar 

  • Kokya TA, Farhadi K (2009) Optimization of dispersive liquid–liquid microextraction for the selective determination of trace amounts of palladium by flame atomic absorption spectroscopy. J Hazard Mater 169(1-3):726–733. https://doi.org/10.1016/j.jhazmat.2009.04.005

    Article  CAS  Google Scholar 

  • Kovalev IA, Bogacheva LV, Tsysin GI, Formanovsky AA, Zolotov YA (2000) FIA-FAAS system including on-line solid phase extraction for the determination of palladium, platinum and rhodium in alloys and ores. Talanta 52(1):39–50. https://doi.org/10.1016/S0039-9140(00)00314-3

    Article  CAS  Google Scholar 

  • Liao W, Ma Y, Chen A, Yang Y (2015) Preparation of fatty acids coated Fe 3 O 4 nanoparticles for adsorption and determination of benzo(a)pyrene in environmental water samples. Chem Eng J 271:232–239. https://doi.org/10.1016/j.cej.2015.03.010

    Article  CAS  Google Scholar 

  • Mohammadi SZ, Afzali D, Taher MA, Baghelani YM (2010) Determination of trace amounts of palladium by flame atomic absorption spectrometry after ligandless-dispersive liquid–liquid microextraction. Microchim Acta 168(1-2):123–128. https://doi.org/10.1007/s00604-009-0267-7

    Article  CAS  Google Scholar 

  • Özdemir C, Saçmacı Ş, Kartal Ş, Saçmacı M (2014) Determination of gold and palladium in environmental samples by FAAS after dispersive liquid–liquid microextraction pretreatment. J Ind Eng Chem 20(6):4059–4065. https://doi.org/10.1016/j.jiec.2014.01.005

    Article  Google Scholar 

  • Ozturk N, Bulut VN, Duran C, Soylak M (2011) Coprecipitation of palladium(II) with 1,5-diphenylcarbazite–copper(II) and determination by flame atomic absorption spectrometry. Desalination 270(1-3):130–134. https://doi.org/10.1016/j.desal.2010.11.034

    Article  CAS  Google Scholar 

  • Pei L, Zhao E, Feng L (2009) Dispersive liquid–liquid microextraction preconcentration of palladium in water samples and determination by graphite furnace atomic absorption spectrometry. Talanta 77:1854–1857

    Article  Google Scholar 

  • Priya BK, Subrahmanayam P, Suvardhan K, Kumar KS, Rekha D, Rao AV, Rao GC, Chiranjeevi P (2007) Cloud point extraction of palladium in water samples and alloy mixtures using new synthesized reagent with flame atomic absorption spectrometry (FAAS). J Hazard Mater 144(1-2):152–158. https://doi.org/10.1016/j.jhazmat.2006.10.002

    Article  CAS  Google Scholar 

  • Pytlakowska K (2016) Dispersive micro solid-phase extraction of heavy metals as their complexes with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol using graphene oxide nanoparticles. Microchim Acta 183(1):91–99. https://doi.org/10.1007/s00604-015-1596-3

    Article  CAS  Google Scholar 

  • Qi P, Liang Z, wang Y, **ao J, Liu J, Zhou Q, Zheng C, Luo L, Lin Z, Zhu F, Zhang X (2016) Mixed hemimicelles solid-phase extraction based on sodium dodecyl sulfate-coated nano-magnets for selective adsorption and enrichment of illegal cationic dyes in food matrices prior to high-performance liquid chromatography-diode array detection detection. J Chromatogr A 1437:25–36. https://doi.org/10.1016/j.chroma.2016.02.005

    Article  CAS  Google Scholar 

  • Rajabi M, Mohammadi B, Asghari A, Barfi B, Behzad M (2013) Nano-alumina coated with SDS and modified with salicylaldehyde-5-sulfonate for extraction of heavy metals and their determination by anodic strip** voltammetry. J Ind Eng Chem 20:3737–3743

    Article  Google Scholar 

  • Ren C, Li H, Li R, Xu S, Wei D, Kang W, Wang L, Jia L, Yang B, Liu J (2016) Electrocatalytic study of a 1,10-phenanthroline–cobalt(II) metal complex catalyst supported on reduced graphene oxide towards oxygen reduction reaction. RSC Adv 6(40):33302–33307. https://doi.org/10.1039/C6RA04078K

    Article  CAS  Google Scholar 

  • Saçmacı Ş, Kartal Ş (2013) Determination of palladium by on-line flow-injection direct spectrophotometry in environmental samples using 2,2′-furyldioxime as a chelator. Talanta 109:26–30. https://doi.org/10.1016/j.talanta.2013.03.030

    Article  Google Scholar 

  • Sharma RK, Pandey A, Gulati S, Adholeya A (2012) An optimized procedure for preconcentration, determination and on-line recovery of palladium using highly selective diphenyldiketone-monothiosemicarbazone modified silica gel. J Hazard Mater 209-210:285–292. https://doi.org/10.1016/j.jhazmat.2012.01.022

    Article  CAS  Google Scholar 

  • Tahmasebi E, Yamini Y (2014) Polythiophene-coated Fe 3 O 4 nanoparticles as a selective adsorbent for magnetic solid-phase extraction of silver(I), gold(III), copper(II) and palladium(II). Microchim Acta 181(5-6):543–551. https://doi.org/10.1007/s00604-013-1144-y

    Article  CAS  Google Scholar 

  • Tang Q, Wang X, Yu F, Qiao X, Xu Z (2014) Simultaneous determination of ten organophosphate pesticide residues in fruits by gas chromatography coupled with magnetic separation. J Sep Sci 37(7):820–827. https://doi.org/10.1002/jssc.201301161

    Article  CAS  Google Scholar 

  • Tokalıoğlu Ş, Oymak T, Kartal Ş (2004) Determination of palladium in various samples by atomic absorption spectrometry after preconcentration with dimethylglyoxime on silica gel. Anal Chim Acta 511(2):255–260. https://doi.org/10.1016/j.aca.2004.02.015

    Article  Google Scholar 

  • Tong S, Jia Q, Song N, Zhou W, Duan T, Bao C (2011) Determination of gold(III) and palladium(II) in mine samples by cloud point extraction preconcentration coupled with flame atomic absorption spectrometry. Microchim Acta 172(1-2):95–102. https://doi.org/10.1007/s00604-010-0466-2

    Article  CAS  Google Scholar 

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Acknowledgments

This research was supported by the National Natural Science Foundation of China (grant number 21265025) and the Analysis and Testing Foundation (No. 2017M20152118084) of Kunming University of Science and Technology.

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Authors and Affiliations

  1. Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming, 650500, China

    Meng Wang & Yaling Yang

  2. Kunming Energy Conservation Supervision Detachment, Kunming, 650021, China

    Lan Wu

  3. School of Chemistry and Biology, Yunnan Minzu University, Kunming, Yunnan Province, China

    Qiufen Hu

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  1. Meng Wang
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  2. Lan Wu
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  3. Qiufen Hu
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  4. Yaling Yang
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Correspondence to Yaling Yang.

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Responsible editor: Guilherme L. Dotto

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Wang, M., Wu, L., Hu, Q. et al. Application of magnetic nanoparticles coated with sodium dodecyl sulfate and modified with 2-(5-bromo-2-pyridylazo)-5-diethyl aminophenol as a novel adsorbent for dispersive-magnetic solid-phase extraction and determination of palladium in soil samples. Environ Sci Pollut Res 25, 8340–8349 (2018). https://doi.org/10.1007/s11356-017-1126-4

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  • DOI: https://doi.org/10.1007/s11356-017-1126-4

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