Abstract
Solid supported catalysts can go a long way in develo** catalyst based technology because of their high efficiency with recyclability and easy separation from the reaction mixture. Immobilizations of homogeneous catalysts through covalent bond with chloromethylated polystyrene cross-linked with divinylbenzene and develop them as environmentally safe heterogeneous catalysts for oxidation reaction have attracted attention in recent years. Recently, effort from our research laboratory was to synthesize new recyclable polymer-supported vanadium complexes based heterogeneous catalysts. Thus, chloromethylated polystyrene cross linked with 5% divinylbenzene was used as support to prepare variety of polymer supported vanadium catalysts. These catalysts have successfully been used for the oxidation and oxidative bromination of various organic substrates. Kee** in mind the industrial usage of these heterogeneous catalysts, the leaching and recycle ability of all polymer-supported catalysts have also been tested. Most catalysts are stable and do not leach during the catalytic reactions.
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Abbreviations
- PS–CH2–Cl:
-
Chloromethylated polystyrene cross-linked with divinyl benzene
- PS–im:
-
Imidazolomethylpolystyrene
- Hhebmz:
-
2-Hydroxyethylbenzimidazole
- Hhmbmz:
-
2-Hydroxymethylbenzimidazole
- Hhpbmz:
-
2-(2-Hydroxyphenyl)benzimidazole
- 2-pybmz:
-
2-(2-Pyridyl)benzimidazole
- 3-pybmz:
-
2-(3-Pyridyl)benzimidazole
- Hpan:
-
1-(2-Pyridylazo)-2-naphthol
- H2fsal–β-ala:
-
Schiff base derived from 3-formylsalicylic acid and β-alanine
- H2fsal–DL-ala:
-
Schiff base derived from 3-formylsalicylic acid and DL-alanine
- H2fsal–L-ile:
-
Schiff base derived from 3-formylsalicylic acid and isoleucine
- H2sal–his:
-
Schiff base derived from salicylaldehyde and histidine
- H2sal–cis:
-
Schiff base derived from salicylaldehyde and cysteine
- H2fsal–amp:
-
Schiff base derived from 3-formylsalicylic acid and 2-amino-2-methylpropanol
- H2fsal–dmen:
-
Schiff base derived from 3-formylsalicylic acid and N,N-dimethyl ethylenediamine
- H2fsal–aepy:
-
Schiff base derived from 3-formylsalicylic acid and 2-aminoethylpyridine
- H2fsal–pa:
-
Schiff base derived from 3-formylsalicylic acid and 3-aminopropanol
- H2fsal–ea:
-
Schiff base derived from 3-formylsalicylic acid and 2-aminoethanol
- H2sal–iah:
-
Schiff base derived from salicylaldehyde and indole-3-acetic hydrazide,
- H2sal–bhz:
-
Schiff base derived from salicylaldehyde and benzoylhydrazide
- H2sal–inh:
-
Schiff base derived from salicylaldehyde and isonicotinoylhydrazide
- H2sal–ohyba:
-
Schiff base derived from salicylaldehyde and o-hydroxybenzylamine
- Hacpy–bhz:
-
Schiff base derived from acetylpyridine and benzoylhydrazide
- Hacpy–nah:
-
Schiff base derived from acetylpyridine and nicotinoylhydrazide
- Hacpy–inh:
-
Schiff base derived from acetylpyridine and isonicotinoylhydrazide
- Hacpy–fah:
-
Schiff base derived from acetylpyridine and 2-furoylhydrazide
- Hbzpy–bhz:
-
Schiff base derived from benzoylpyridine and benzoylhydrazide
- Hbzpy–nah:
-
Schiff base derived from benzoylpyridine and nicotinoylhydrazide
- Hbzpy–inh:
-
Schiff base derived from benzoylpyridine and isonicotinoylhydrazide
- H2salten:
-
Schiff base derived from salicylaldehyde and diethylenetriamine
- H3sal–dahp:
-
Schiff base derived from salicylaldehyde and 1,3-diamino-2-hydroxypropane
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Acknowledgements
M. R. M. thanks the Science and Engineering Research Board (SERB), Department of Science and Technology, Government of India, New Delhi for financial support of the work (Grant Number EMR/2014/000529).
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Maurya, M.R. Vanadium Complexes Based Polymer Supported Catalysts: A Brief Account of Research from Our Group. Top Catal 61, 1500–1513 (2018). https://doi.org/10.1007/s11244-018-1006-2
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DOI: https://doi.org/10.1007/s11244-018-1006-2