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Resonant electron capture negative ion mass spectrometry: the state of the art and the potential for solving analytical problems

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Russian Chemical Bulletin Aims and scope

Abstract

Resonant electron capture negative ion mass spectrometry (REC NI MS) is a highly informative method of investigation of low-energy electron-molecule reactions, thermochemistry, and kinetics of negative ion formation and decay. The review includes consideration of the physical principles and specific features of the method, a brief historical survey, terminological issues, and an outline of instrumentation. The potential of REC NI MS for solving structural and analytical problems is analyzed and the advantages of the method over classical positive ion MS are demonstrated. The results of analytical studies of organic and organoelement compounds using various types of mass spectrometers are reviewed. The reasons for low adoption of REC NI MS are analyzed and arguments are presented in favor of introducing the method into analytical practice as an additional tool implemented on the available instruments. Prospects for the development and improvement of REC NI MS for solving unconventional problems are discussed.

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Authors and Affiliations

  1. Institute of Molecule and Crystal Physics, Ufa Federal Research Centre of the Russian Academy of Sciences, 151 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. V. Khatymov

  2. D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. G. Terentyev

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Correspondence to R. V. Khatymov or A. G. Terentyev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 605–646, April, 2021.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 19-13-50350 “Expansion”).

This work does not involve human participants and animal subjects.

The authors declare that there is no conflict of interest.

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Khatymov, R.V., Terentyev, A.G. Resonant electron capture negative ion mass spectrometry: the state of the art and the potential for solving analytical problems. Russ Chem Bull 70, 605–646 (2021). https://doi.org/10.1007/s11172-021-3132-4

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