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Effect of High-Temperature Deformation on the Physical and Mechanical Properties of In Situ Titanium Composites with Silicide–Boride Reinforcement

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The efficiency of thermomechanical processing was studied to optimize the mechanical properties of cast ternary and multicomponent hypoeutectic titanium-based alloys with silicide–boride reinforcement, produced by electron-beam crucible-skull melting. All the alloys studied exhibit low plasticity in cast state. High-temperature deformation, such as forging of samples heated to 1050°C in air, can significantly enhance the properties of the alloys: the plasticity of ternary Ti–Si–B alloys increases by four to six times (from 0.5 to 2–3%) and their fracture toughness increases by three times (from 11 to 36 MPa ∙ m0.5). The plasticity of the alloys with Zr, Al, and Sn additions increases by one order of magnitude (to 0.2–0.3%) and their fracture toughness by almost twice. The greatest high-temperature creep-rupture resistance at a fracture toughness of 26 MPa ∙ m0.5 is shown by the Ti80Zr1.2Al5.5Sn2.1Si8.7B2.5 alloy: 1038, 887, and 572 MPa at 600, 700, and 800°C, respectively.

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  1. The activities were carried out at the Technical Center of the National Academy of Sciences of Ukraine by V.B. Sobolev (operator).

References

  1. V.I. Mazur, Yu.N. Taran, S.V. Kapustnikova, V.I. Trefilov, S.A. Firstov, and L.D. Kulak, US Patent 5366570, CIC C22C 014/00, Titanium Matrix Composite; the applicant and the patent holder Frantsevich Institute for Problems of Materials Science NASU and National Metallurgy Academy (Dnipropetrovsk, Ukraine), November 22 (1994), p. 27.

    Google Scholar 

  2. V.I. Mazur, Yu.N. Taran, S.V. Kapustnikova, V.I. Trefilov, S.A. Firstov, and L.D. Kulak, US Patent 5624505, CIC C02L 014/00, Titanium Matrix Composite; the applicant and the patent holder Frantsevich Institute for Problems of Materials Science NASU and National Metallurgy Academy (Dnipropetrovsk, Ukraine), April 29 (1997), p. 22.

    Google Scholar 

  3. S.A. Firstov, “Titanium-matrix composites in comparison with ceramic ones,” in: Y.M. Haddad (ed.), Advanced Multilayered and Fibre-Reinforced Composites, Kluwer Academic Pubishers, Dordrecht–Boston–London (1998), pp. 175–186.

  4. T.Ya. Velikanova, A.A. Bondar, L.V. Artyukh, O.N. Senkov, D.B. Miracle, and S.O. Firstov, “Titanium–boride composites: Influence of alloying on constitution and properties of titanium-boride eutectic alloys,” in: Metallic Materials with High Structural Efficiency, Kluwer Academic Publishers, Dordrecht–Boston–London (2004), pp. 259–268.

  5. O.O. Bilous, N.I. Tsyganenko, and M.P. Burka, “Titanium-boride eutectic materials: Effects of vanadium and niobium on high-temperature strength,” High Temp. Mat. Pr. Isr., 83–96 (2005).

  6. N.I. Tsyganenko, A.A. Bondar, and O.O. Bilous, “Effect of do** with p-elements (Al, Si, Ge, Si) and zirconium on the structure and properties of titanium-boride eutectic alloys,” Powder Metall. Met. Ceram., 50, No. 7–8, 491–511 (2011).

    Article  CAS  Google Scholar 

  7. E.C.T. Ramos, G. Silva, A.S. Ramos, and C.F. Nunes, “Microstructure and oxidation behavior of Ti–Si–B alloys,”Mater. Sci. Eng. A, A363, 297–306 (2003).

  8. A.S. Ramos, C.A. Nunes, and G. Rodrigues, “Ti6Si2B, a new ternary phase in the Ti–Si–B system,” Intermetallics, 12, No. 5, 487–491 (2004).

  9. N.I. Levitsky, T.V. Lapshuk, E.A. Matviets, O.O. Belous, Ya.I. Evich, and N.I. Tsyganenko, “Mechanical properties of electron-beam crucible-skull melting Ti–Si–B alloys,” Prots. Lit., No. 1, 54–61 (2013).

  10. M.L. Bernshtein (ed.), Hot Deformation Diagrams and Structure and Properties of Steels: Handbook [in Russian], Metallurgiya, Moscow (1989), p. 543.

  11. M.L. Bernshtein, “Hot plastic deformation and strengthening mechanism of steel in thermomechanical processing,” Stal, No. 2, 157–162 (1972).

    Google Scholar 

  12. V.I. Trefilov, Yu.V. Milman, and S.A. Firstov, Physical Fundamentals of Strength for Refractory Metals [in Russian], Naukova Dumka, Kyiv (1975), p. 315.

  13. V.I. Trefilov (ed.), V.F. Moiseev, E.P. Pechkovskii, I.D. Gornaya, and A.D. Vasiliev, Strain Hardening and Fracture of Polycrystalline Materials [in Russian], 2nd ed., Naukova Dumka, Kyiv (1989), p. 256.

  14. S.A. Firstov, A.D. Vasilyev, L.D. Kulak, D. Miracle, and Yu.N. Podrezov, “Influence of preliminary deformation on strengthening and plastic characteristics of Ti–2% Si–3% Al–5% Zr alloy,” in: ICCE/7, International Conference on Composites Engineering (July 2001), Tenerife (2001), pp. 919–920.

  15. S.A. Firstov, Yu.N. Podrezov, N.N. Kuzmenko, N.I. Danilenko, N.P. Brodnikovskii, and L.D. Kulak, “Effect of plastic deformation on the mechanical properties of eutectic Ti–Al–Si–Zr alloys,” Fiz. Tekh. Vys. Davl., 12, No. 3, 28–37 (2002).

    CAS  Google Scholar 

  16. S.V. Ladokhin, N.I. Levitsky, B. Damkroger, and R. Williamson, “Effect of electromagnetic stirring on electron-beam crucible-skull melting of titanium and its alloys,” Met. Lit. Ukrainy, No. 11–12, 39–43 (1996).

    Google Scholar 

  17. V.A. Borisenko, “General laws of change in the mechanical properties of refractory materials depending on temperature,” Probl. Prochn., No. 8, 58–63 (1975).

    Google Scholar 

  18. R. Hill, The Mathematical Theory of Plasticity, Clarendon Press, Oxford (1983), p. 355.

  19. V.A. Borisenko, Hardness and Strength of Refractory Materials at High Temperatures [in Russian], Naukova Dumka, Kyiv (1984), p. 211.

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Correspondence to A. A. Bondar.

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Translated from Poroshkova Metallurgiya, Vol. 58, Nos. 9–10 (529), pp. 55–68, 2019.

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Bilous, O.O., Bondar, A.A., Kotko, A.V. et al. Effect of High-Temperature Deformation on the Physical and Mechanical Properties of In Situ Titanium Composites with Silicide–Boride Reinforcement. Powder Metall Met Ceram 58, 538–549 (2020). https://doi.org/10.1007/s11106-020-00108-x

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