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Destruction Kinetics of 2,4 Dichlorophenol Aqueous Solutions in an Atmospheric Pressure Dielectric Barrier Discharge in Oxygen

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Abstract

The processes of degradation of 2,4-dichlorophenol (2,4-DCP) aqueous solutions under the action of atmospheric pressure of DBD in oxygen were studied. The degradation of 2,4-DCP proceeds efficiently, the degree of decomposition reaching 100%. The degradation kinetics of 2,4-DCP obeys a formal first-order kinetic law on concentration of 2,4-DCP. The effective rate constants depend weakly on the experimental conditions and are equal to ~ 2 s−1. Based on experimental data, the energy efficiency of 2,4-DCP decomposition was determined to be in the range of 0.039–0.173 molecules per 100 eV depending on the experimental conditions. The composition of the products was studied by gas chromatography, chromatography-mass spectrometry, UV/visible spectroscopy, fluorescent methods and some chemical methods. The main decomposition products present in the solution were found to be carboxylic acids, aldehydes and chloride ions, whereas carbon dioxide and molecular chlorine appear in the gas. The results obtained are compared with similar data from other advanced oxidation processes (AOP’s) methods.

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Acknowledgements

This study was carried out in the frame of Project part of State Assignment of the Ministry of Education and Science of the RF, No. 3.1371.2017/4.6.

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Authors and Affiliations

  1. Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Sheremetiev Ave., 7, Ivanovo, Russia, 153000

    Andreiy A. Gushchin, Vladimir I. Grinevich, Valeriy Ya. Shulyk & Elena Yu. Kvitkova

  2. Department of Microelectronic Devices and Materials, Ivanovo State University of Chemistry and Technology, Sheremetiev Ave., 7, Ivanovo, Russia, 153000

    Vladimir V. Rybkin

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  1. Andreiy A. Gushchin
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  2. Vladimir I. Grinevich
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  3. Valeriy Ya. Shulyk
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Correspondence to Vladimir V. Rybkin.

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Gushchin, A.A., Grinevich, V.I., Shulyk, V.Y. et al. Destruction Kinetics of 2,4 Dichlorophenol Aqueous Solutions in an Atmospheric Pressure Dielectric Barrier Discharge in Oxygen. Plasma Chem Plasma Process 38, 123–134 (2018). https://doi.org/10.1007/s11090-017-9857-z

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