Abstract
The xBa0.5Sr0.5TiO3–(1 − x)NaPO3 (x = 0–0.20 mol%) glasses were prepared by the conventional melt-quenching method. The amorphous state of the samples was verified by X-ray diffraction. The density, molar volume, glass transition temperature (T g), micro-hardness and the crystallization temperature (T c) are determined for each glass. It is found that they depend strongly on the chemical composition of the glasses. The results of the micro-hardness show an increase in the H v parameter with the Ba0.5Sr0.5TiO3 content. The crystallization of glasses is made by submitting samples to heat treatments, and the crystallized phases are identified by XRD. The kinetic of the crystallization is carried out by thermal analysis using DSC technique. The mechanism of crystallization is proposed according to the determined activation energy (E a) and the Avrami parameter (n). The structural approach of the glasses was realized out by IR spectroscopy. This technique has highlighted the co-existence of different phosphate and titanium structural units in the glassy-matrix.
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Jones R, Zurcher P, Chu P, Taylor DJ, Lii YT, Jiang B, Maniar PD, Gillespie SJ. Memory applications based on ferroelectric and high-permittivity dielectric thin films. Microelectron Eng. 1995;29:3–10.
MuÈcklich F, Janocha H. Smart materials: the IQ of materials in systems. Z Metallkd. 1996;873:57–364.
Sinouh H, Bih L, Azrour M, ElBouari A, Benmokhtar S, Manoun B, Belhorma B, Baudin T, Berthet P, Haumont R, Solas D. Elaboration and structural characterization of glasses inside the ternary SrO-TiO2-P2O5 system. J Phys Chem Solids. 2012;73:961–8.
Yadav AK, Gautam C. Successive relaxor ferroelectric behavior in La modified (Ba, Sr)TiO3 borosilicate glass ceramics. J Mater Sci Mater Electron. 2014;25:3532–6.
Herczog A. Microcrystalline BaTiO3 by crystallization from glass. J Am Ceram Soc. 1964;47:107–15.
Ulrich DR. High dielectric thick films from screened circuit capacitors. Solid State Technol. 1969;12:30–8.
Sigaev VN, Sarkisov PD, Stefanovich SY, Pernice P, Aronne A. Glass ceramic textures based on new ferroelectric complex oxides. Ferroelectrics. 1999;233:165–85.
Houng B, Kim CY, Haun MJ. Densification, crystallization, and electrical properties of lead zirconate titanate glass-ceramics. IEEE T Ultrason Ferr. 2000;47:808–18.
Duan F, Fang C, Ding Z, Zhu H. Properties and applications of a piezoelectric glass-crystalline phase composite in the BaO–SrO–TiO2–SiO2 system. Mat Lett. 1998;34:184–7.
Lurie KA, Yakovlev VV. Method of control and optimization of microwave heating in waveguide systems. IEEE Trans Mag. 1999;35:1777–80.
Ruiz-Valdés JJ, Gorokhovsky AV, Escalante-Garcìa JI, Mendoza-Suárez G. Glass-ceramic materials with regulated dielectric properties based on the system BaO–PbO–TiO2–B2O3–Al 2O3. J Eur Ceram Soc. 2004;24:1505–8.
Shannon RD. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A. 1976;32:751–67.
Brow RK. Review: the structure of simple phosphate glasses. J Non-Cryst Solids. 2000;263–264:1–28.
Shaw CM, Shelby JE. Preparation and properties of stannous fluorophosphate glasses. Phys Chem Glasses. 1988;29:49–53.
Brow RK, Kirkpatrick RJ, Turner GL. Local structure of xAl2O3·(1−x) NaPO3 glasses: an NMR and XPS study. J Am Ceram Soc. 1990;73:2293–300.
Donald IW. Preparation, properties and chemistry of glass- and glass-ceramic-to-metal seals and coatings. J Mater Sci. 1993;28:2841–86.
Sinouh H, Bih L, El Bouari A, Baudin T, Berthet P, Haumont R, Solas D. Glass and glass-ceramics along the SrTiO3–NaPO3 line. MATEC Web Conf. 2013;5:1–3.
Yamane M, Mackenzie JD. Vicker’s hardness of glass. J Non-Cryst Solids. 1974;15:153–64.
Sinouh H, Bih L, El Bouari A, Azrour M, Manoun B, Lazor P. BaO effect on the thermal properties of the phosphate glasses inside the Na2O–SrO–TiO2–B2O3–P2O5 system. J Phys Chem Solids. 2014;405:33–8.
Kissinger HE. Variation of peak temperature with heating rate in differential thermal analysis. J Res Natl Bur Stand. 1956;57:217–21.
Yinnon H, Uhlmann DR. Applications of thermoanalytical techniques to the study of crystallization kinetics in glass-forming liquids, part I: theory. J Non-Cryst Solids. 1983;54:253–75.
Aly KA, Saddeek YB, Dahshan A. Structure and crystallization kinetics of manganese lead tellurite glasses. J Therm Anal Calorim. 2015;119:1215–24.
Ivanović VDZ, Tosić MB, Grujić SR, Matijasević SD, Stojanović JN, Nikolić JD, Smiljanic SV. DTA study of the crystallization of Li2O–Nb2O5–SiO2–TiO2 glass. J Therm Anal Calorim. 2015;119:1653–61.
Arya SK. Singh K, Thermal and kinetic parameters of 30Li2O–55B2O3–5ZnO–xTiO2–(10-x)V2O5 glasses (0 ≤ x ≤ 10). J Therm Anal Calorim. 2015;122:189–95.
Zemenová P, Kral R, Nitsch K, Knizek K, Cihlar A, Bystrický A. Characterization and crystallization kinetics of Er-doped Li2O–Y2O3–P2O5 glass studied by non-isothermal DSC analysis. J Therm Anal Calorim. 2016;125:1431–8.
Augis JA, Bennett JE. Calculation of Avrami parameters for heterogeneous solid state reactions using a Modified Kissinger’s method. J Therm Anal Calorim. 1978;13:283–92.
Avrami M. Kinetics of phase change. I General theory. J Phys Chem. 1939;7:1103–12.
Avrami M. Kinetics of phase change. II. Transformation-time relations for random distribution of nuclei. J Phys Chem. 1940;8:212–24.
Avrami M. Kinetics of phase change. III. Granulation, phase change, and microstructure. J Phys Chem. 1941;9:177–84.
Tosic MB, Dimitrijevic RZ, Mitrovic MM. The crystallization of calcium phosphate glass with the ratio [CaO]/[P2O5]<1. J Mater Sci. 2003;38:1983–94.
Higazy AA, Bridge B. Infrared spectra of the vitreous system Co3O4–P2O5 and their interpretation. J Mater Sci. 1985;20:2345–58.
Selvaraj LJ, Rao KJ. Role of lead in lead phosphomolybdate glasses and a model of structural units. J Non-Cyst Solids. 1988;104:300.
Efimov AM. IR fundamental spectra and structure of pyrophosphate glasses along the 2ZnO·P2O5–2Me2O·P2O5 join (Me being Na and Li). J Non-Cryst Solids. 1997;209:209–26.
Yung SW, Shih PY, Chin TS. Crystallization kinetics of a low melting PbO–ZnO–P2O5 glass. Mater Chem Phys. 1998;57:111–6.
Shih PY, Yung SW, Chin TS. FTIR and XPS studies of P2O5–Na2O–CuO glasses. J Non-Cryst Solids. 1999;244:211–22.
Hudgens JJ, Martin SW. Glass transition and infrared spectra of low-alkali, anhydrous lithium phosphate glasses. J Am Ceram Soc. 1993;76:1691–6.
Meyer K. Structural characterisation of binary magnesium ultraphosphate glasses by vibrational spectroscopy. Phys Chem Glasses. 2001;42:79–87.
Metwalli E, Brow RK. Modifier effects on the properties and structures of aluminophosphate glasses. J Non-Cryst Solids. 2001;289:113–22.
Kamitsos EI, Kapoutsis JA, Chryssikos GD, Hutchinson JM, Pappin AJ, Ingram MD, Duffy JA. Infrared study of AgI containing superionic glasses. Phys Chem Glasses. 1995;36:141–9.
Laudisio D, Catauro M, Aronne A, Pernice P. Glass transition temperature and devitrification behaviour of lithium-titanium-germanate glasses. Thermochim Acta. 1997;294:173–8.
Wu HF, Lin CC, Shen P. Structure and dissolution of CaO–ZrO2–TiO2–Al2O3–B2O3–SiO2 glass (II). J Non-Cryst Solids. 1997;209:76–86.
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The authors would like to thank the Swedish Research Council for the financial support of this work.
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Sinouh, H., Bih, L., Manoun, B. et al. Thermal analysis and crystallization of the glasses inside the BaO–SrO–TiO2–NaPO3 system. J Therm Anal Calorim 128, 883–890 (2017). https://doi.org/10.1007/s10973-016-5986-5
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DOI: https://doi.org/10.1007/s10973-016-5986-5