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Geochemical study of rare earth elements, uranium and thorium in mylonitic rocks of north Abu Rusheid, Egypt using inductively coupled plasma mass spectrometry

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Abstract

A geochemical study of rare earth elements (REEs), uranium (U), thorium (Th) and major elements was conducted in mylonitic rocks found in north Abu Rusheid, south eastern desert, Egypt, a well-known uranium ore deposit area. The concentrations of REEs, U, and Th were measured using inductively coupled plasma mass spectrometry. ∑REEs varied from 38 to 183 µg/g with a mean value of 90 µg/g. U and Th concentrations varied from 67 to 171 and 98 to 454 µg/g, respectively. The mean value of the U/Th ratio was higher than the upper continental crust value and the mylonitic rocks were concluded to have high U content.

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References

  1. Rollinson HR (1993) Using geochemical data: evaluation, presentation, interpretation. Longman Scientific and Technical, Harlow

    Google Scholar 

  2. Balaram V (2023) Potential future alternative resources for rare earth elements: opportunities and challenges. Minerals 13:425

    Article  CAS  Google Scholar 

  3. Jyothi RK, De Melo LGTC, Santos RM, Yoon H-S (2023) An overview of thorium as a prospective natural resource for future energy. Front Energy Res 11:1132611

    Article  Google Scholar 

  4. Sorimachi A, Sahoo SK, Tokonami S (2009) Generation and control of thoron emanated from lantern mantles. Rev Sci Instrum 80:015104

    Article  PubMed  Google Scholar 

  5. Bowen JH, Woodward BH, Mossler JA, Ingram P, Shelburne JD (1980) Energy dispersive X-ray detection of thorium dioxide. Arch Pathol Lab Med 104:459–461

    CAS  PubMed  Google Scholar 

  6. Degueldre C, Joyce MJ (2020) Evidence and uncertainty for uranium and thorium abundance: a review. Prog Nucl Energy 124:103299

    Article  CAS  Google Scholar 

  7. Pagel M (1982) The mineralogy and geochemistry of uranium, thorium, and rare-earth elements in two radioactive granites of the Vosges, France. Miner Mag 46:149–161

    Article  Google Scholar 

  8. Cole JW, Cashman KV, Rankin PC (1983) Rare-earth element geochemistry and the origin of andesites and basalts of the Taupo volcanic zone, New Zealand. Chem Geol 38:255–274

    Article  CAS  Google Scholar 

  9. Muecke GK, Pride C, Sarkar P (1979) Rare-earth element geochemistry of regional metamorphic rocks. Phys Chem Earth 11:449–464

    Article  Google Scholar 

  10. Kamar MS (2021) Geochemical and mineralogical studies of the mylonite xenoliths and monzogranite rocks at Wadi Abu Rusheid, south eastern desert, Egypt: insights on the genesis of mineralization. Acta Geol Sin 95:1551–1567

    Article  CAS  Google Scholar 

  11. Kamar MS, Ibrahim ME, Dawoud M, Saleh SM (2022) Geochemical characterizations and spectrometric prospecting of the Arabian-Nubian shield: a case study from Abu Rusheid area, south eastern desert of Egypt. Radiochemistry 64:228–243

    Article  CAS  Google Scholar 

  12. Kamar MS, Bakry AR, Yousef LA, Mostafa DA (2020) Radioactivity and mineralogical studies with an emphasis on recovery of thorium from mylonite rocks in the Abu Rusheid area, south eastern desert. Egypt Euro Mediterr J Environ Integr 5:1–15

    Google Scholar 

  13. Fawzy MM, Kamar MS, Saleh GM (2021) Physical processing for polymetallic mineralization of Abu Rusheid mylonitic rocks, south eastern desert of Egypt. Int Rev Appl Sci Eng 12:134–146

    Google Scholar 

  14. Yenisoy-Karakaş S, Gaga EO, Doğangün A, Tuncel SG (2004) Determination of major and rare earth elements in bastnasite ores by ICP-AES. Anal Lett 37:2701–2709

    Article  Google Scholar 

  15. Kritsananuwat R, Sahoo SK, Fukushi M, Chanyotha S (2015) Distribution of rare earth elements, thorium and uranium in gulf of Thailand’s sediments. Environ Earth Sci 73:3361–3374

    Article  CAS  Google Scholar 

  16. Veerasamy N, Sahoo SK, Murugan R, Kasar S, Inoue K, Fukushi M, Natarajan T (2021) ICP-MS measurement of trace and rare earth elements in beach placer-deposit soils of Odisha, east coast of India, to estimate natural enhancement of elements in the environment. Molecules 26:7510

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  17. Kon Y, Hirata T (2015) Determination of 10 major and 34 trace elements in 34 GSJ geochemical reference samples using femtosecond laser ablation ICP-MS. Geochem J 49:351–375

    Article  CAS  Google Scholar 

  18. Sindern S (2017) Analysis of rare earth elements in rock and mineral samples by ICP-MS and LA-ICP-MS. Phys Sci Rev 2:20160066

    Google Scholar 

  19. Khaleal FM, Saleh GM, Lasheen ESR, Alzahrani AM, Kamh SZ (2022) Exploration and petrogenesis of corundum-bearing pegmatites: a case study in Migif–Hafafit area. Egypt Front Earth Sci 10:869828

    Article  Google Scholar 

  20. Fritz H, Abdelsalam M, Ali KA, Bingen B, Collins AS, Fowler AR, Ghebreab W, Hauzenberger CA, Johnson PR, Kusky TM, Macey P (2013) Orogen styles in the east African orogen: a review of the neoproterozoic to cambrian tectonic evolution. J Afr Earth Sci 86:65–106

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  21. Somboon S, Kavasi N, Sahoo SK, Inoue K, Arae H, Tsuruoka H, Shimizu H, Fukushi M (2018) Radiocesium and 40K distribution of river sediments and floodplain deposits in the Fukushima exclusion zone. J Environ Radioact 195:40–53

    Article  CAS  PubMed  Google Scholar 

  22. Kasar S, Murugan M, Arae H, Aono T, Sahoo SK (2020) A microwave digestion technique for the analysis of rare earth elements, thorium and uranium in geochemical certified reference materials and soils by inductively coupled plasma mass spectrometry. Molecules 25:5178

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. Veerasamy N, Kasar S, Murugan R, Inoue K, Natarajan T, Ramola RC, Fukushi M, Sahoo SK (2023) 234U/238U disequilibrium and 235U/238U ratios measured using MC-ICP-MS in natural high background radiation are soils to understand the fate of uranium. Chemosphere 232:138217

    Article  Google Scholar 

  24. Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59:1217–1232

    Article  CAS  Google Scholar 

  25. Li C, Zhang Z, ** C, Cheng M, Wang H, Huang J, Algeo TJ (2020) Spatiotemporal evolution and causes of marine euxinia in the early cambrian Nanhua basin (south China). Palaeogeogr Palaeoclimatol Palaeoecol 546:109676

    Article  Google Scholar 

  26. Nesbitt HW, Young GM (1982) Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature 299:715–717

    Article  CAS  Google Scholar 

  27. Yan D, Chen D, Wang Z, Li J, Yang X, Zhang B (2019) Climatic and oceanic controlled deposition of late ordovician-early silurian black shales on the north yangtze platform, south China. Mar Pet Geol 110:112–121

    Article  CAS  Google Scholar 

  28. Fedo CM, Wayne Nesbitt H, Young GM (1995) Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology 23:921–924

    Article  CAS  Google Scholar 

  29. Nesbitt HW, Young GM (1984) Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geochim Cosmochim Acta 48:1523–1534

    Article  CAS  Google Scholar 

  30. Condie KC, Sinha AK (1996) Rare earth and other trace element mobility during mylonitization: a comparison of the Brevard and Hope Valley shear zones in the Appalachian Mountains, USA. J Metamorph Geol 14:213–226

    Article  CAS  Google Scholar 

  31. Islam R, Ghosh SK, Vyshnavi S, Sundriyal YP (2011) Petrography, geochemistry and regional significance of crystalline klippen in the Garhwal Lesser Himalaya, India. J Earth Syst Sci 120:489–501

    Article  CAS  Google Scholar 

  32. Adams JA, Weaver CE (1958) Thorium-to-uranium ratios as indicators of sedimentary processes: example of concept of geochemical facies. Am Assoc Pet Geol Bull 42:387–430

    CAS  Google Scholar 

  33. Masuda A, Nakamura N, Tanaka T (1973) Fine structures of mutually normalized rare-earth patterns of chondrites. Geochim Cosmochim Acta 37:239–248

    Article  CAS  Google Scholar 

  34. Piper DZ, Bau M (2013) Normalized rare earth elements in water, sediments, and wine: identifying sources and environmental redox conditions. Am J Anal Chem 4:69–83

    Article  Google Scholar 

  35. Sun Y, Shu L, Guo J, Zhu W, Zhang X, Chen X, Wang F, Faure M (2003) Tectono-geochemistry analyses of fault rocks in shear zone of metamorphic core complex in north Jiangxi, China. Prog Nat Sci 13:367–373

    CAS  Google Scholar 

  36. Sadeghi M, Arvanitidis N, Ladenberger A (2020) Geochemistry of rare earth elements in bedrock and till, applied in the context of mineral potential in Sweden. Minerals 10:365

    Article  CAS  Google Scholar 

  37. Bao Z, Zhao Z (2008) Geochemistry of mineralization with exchangeable REY in the weathering crusts of granitic rocks in south China. Ore Geol Rev 33:519–535

    Article  Google Scholar 

  38. Constantopoulos J (1988) Fluid inclusions and rare earth element geochemistry of fluorite from south-central Idaho. Econ Geol 83:626–636

    Article  CAS  Google Scholar 

  39. Kanazawa Y, Kamitani M (2006) Rare earth minerals and resources in the world. J Alloys Compd 408:1339–1343

    Article  Google Scholar 

Download references

Acknowledgements

One of the authors (SS) is thankful to the Tokyo Metropolitan Government, Tokyo, Japan for the award of a doctoral fellowship through the “Tokyo Global Partner Scholarship Program” at Tokyo Metropolitan University. This research was partially supported by the JSPS core-to-core program (Grant Number: JPJSCCB20210008).

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Authors and Affiliations

  1. Tokyo Metropolitan University, 7-2-10 Higashiogu, Arakawa-ku, Tokyo, 116-8551, Japan

    Sara Sakr & Kazumasa Inoue

  2. Department of Physics, Minia University, El-Minia, Egypt

    Sara Sakr

  3. Institute for Radiological Sciences, National Institutes for Quantum Sciences and Technology (QST), 4-9-1 Anagawa, Inage-ku, Chiba, 263-8555, Japan

    Sara Sakr, Hideki Arae & Sarata Kumar Sahoo

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  1. Sara Sakr
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  2. Kazumasa Inoue
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Correspondence to Sarata Kumar Sahoo.

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Sakr, S., Inoue, K., Arae, H. et al. Geochemical study of rare earth elements, uranium and thorium in mylonitic rocks of north Abu Rusheid, Egypt using inductively coupled plasma mass spectrometry. J Radioanal Nucl Chem 333, 3269–3277 (2024). https://doi.org/10.1007/s10967-023-09257-w

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