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The synthesis and characterization of helical polyaniline in the liquid crystal

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Abstract

The helical polyaniline (PANI) was synthesized through introducing the chiral chemical D-camphor-10-sulfonic acid (D-CSA) into the liquid crystal, which resulted in the typical conical texture of lamellar phase pattern, owing to the reorientation and rearrangement of liquid crystal. The morphology and the structures of helical PANI were characterized through TEM, Uv-vis, FTIR and XRD, and the influence of the factors such as the amount of D-CSA, stirring, the strength of the electric field on PANI was investigated. Besides, according to the electrochemical data of helical PANI, it was obtained the capacitance of helical PANI synthesized in the presence of electric field was higher, compared with other samples.

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Acknowledgement

We thank Cuiying **a, Lili Huang and Meigui Huang for their helpful discussions. The authors would like to acknowledge the financial supports from the Natural Science Foundation of China (grant No. 51963021), the Science Foundation of Yulin Normal University (No. G2019ZK22 and G2019ZK20), and Yulin Normal University Research Grant (grant No. 2019YJKY18, 2019YJKY19 and 2019YJKY17).

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Authors and Affiliations

  1. Guangxi Key Lab of Agricultural Resources Chemistry and Biotechnology, School of Chemistry and Food Science, Yulin Normal University, Yulin, 537000, P. R. China

    Yiqi **g, Rong wang, Cancan Shi, Taiming Shao & Ruijuan Wang

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  1. Yiqi **g
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  2. Rong wang
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  3. Cancan Shi
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Correspondence to Ruijuan Wang.

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**g, Y., wang, R., Shi, C. et al. The synthesis and characterization of helical polyaniline in the liquid crystal. J Polym Res 28, 88 (2021). https://doi.org/10.1007/s10965-021-02446-9

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