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Effect of Pt/HZSM-5 dealumination by high temperature reduction on glycerol oxidation

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Abstract

Glycerol oxidation was investigated using as catalyst an acid zeolite (H-ZSM-5) impregnated with different contents of Pt (1 and 3 wt%), and H2O2 and air as oxidants. Catalysts were characterized by XRD, XRF, FT-IR, 27Al MAS NMR, N2 adsorption, NH3-TPD, XPS and TEM. After calcination, catalysts were reduced at 1000 °C under H2 and this treatment lead to some dealumination that influenced catalyst acidity. The influence of acidity was evaluated in glycerol oxidation. All tested catalysts were able to oxidize glycerol, and the main products were 1,3-dihydroxyacetone, glyceric acid and glyceraldehyde.

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Abbreviations

GLY:

Glycerol

GLYA:

Glyceric acid

DHA:

Dihydroxyacetone

TART:

Tartronic acid

GLYCA:

Glycolic acid

GLYOX:

Glyoxylic acid

OXA:

Oxalic acid

βPY:

β-Hydroxypyruvic acid

GLYALD:

Glyceraldehyde

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Acknowledgements

We gratefully acknowledge financial support of CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico) and FAPERJ (Fundação de Apoio à Pesquisa do Estado do Rio de Janeiro). Chaline Detoni thanks CNPq (BOLSA ATRAÇÃO DE JOVENS TALENTOS) and FAPERJ (Bolsa de pós doutorado Nota 10) for the Postdoctoral scholarships. We also acknowledge Laboratório Multiusuário de RMN de Sólidos Profa. Adelina Costa Neto (LABRMN-1) for the NMR analysis, Greentec for textural analysis, Prof. Cláudio J.A. Mota for HZSM-5 sample and Laboratório de Espectroscopia de Fotoelétrons na Região de Raio-X – XPS (IQ-UFRJ).

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  1. Escola de Química, Centro de Tecnologia, Universidade Federal do Rio de Janeiro, Bloco E, sala 206, Rio de Janeiro, RJ, CEP 21941-909, Brazil

    Chaline Detoni, Aline Raymundo Pereira da Silva & Mariana M. V. M. Souza

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  1. Chaline Detoni
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  2. Aline Raymundo Pereira da Silva
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  3. Mariana M. V. M. Souza
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Correspondence to Mariana M. V. M. Souza.

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Detoni, C., da Silva, A.R.P. & Souza, M.M.V.M. Effect of Pt/HZSM-5 dealumination by high temperature reduction on glycerol oxidation. J Porous Mater 27, 707–717 (2020). https://doi.org/10.1007/s10934-019-00851-6

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