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Poly(o-methoxyaniline) Modified by the Biphasic Ceramic System Na2Ti3O7/ Na2Ti6O13

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Abstract

We probed the structural modifications and electronic behavior of composites obtained from the admixture of a biphasic titanate ceramic system (Na2Ti3O7/Na2Ti6O13) with a poly(o-methoxyaniline, POMA) matrix. The composites were obtained by the addition of Na2Ti3O7/Na2Ti6O13to a POMA matrix in mass concentrations from 0 to 35%. The sodium titanates were synthesized by means of sonochemistry, while the polymer was obtained by conventional chemical polymerization. The structural analysis carried by XRD, FTIR and UV-Vis indicated mostly the presence of POMA, though the titanates could be identified in the composites with higher concentration. The XRD diffractograms showed narrow reflections that could be correlated to the Na2Ti6O13 phase and hydrogen titanates, whose presence indicates a process of partial substitution of H+ for Na+ ions. While the thermal degradation of the polymeric chains starts near 150 °C, the thermogravimetric and differential thermogravimetric (TG/dTG) analysis revealed that the presence of sodium titanates enhances the thermal stability of the composites. Finally, the addition of the biphasic ceramic to the composite increases the electrical resistivity drastically, from ≈ 102 Ω cm in the pure POMA to ≈ 104 Ω cm in the 35% composite.

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Data Availability

The datasets generated during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

This study was partially supported by the “Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES)” - Finance Code 001. The authorswouldliketothank “Fundação de Amparo à Pesquisa do Estado do Amazonas”and“Conselho Nacional de Desenvolvimento Científico e Tecnológico” for their financial support.

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The authors have not disclosed any funding.

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Authors and Affiliations

  1. LPMaT, Departamento de Engenharia de Materiais, Universidade Federal do Amazonas, Manaus, Amazonas, Brazil

    J. P. da Silva & Y. Leyet

  2. Departamento de Física, Universidade Federal do Amazonas, Manaus, Amazonas, Brazil

    S. Costa, E. A. Sanches, M. M. da S. Paula & Y. Leyet

  3. Departamento de Química, Alimentos e Meio Ambiente - DQA, Instituto Federal de Educação, Ciência e Tecnologia do Amazonas, Campus Manaus Centro – CMC, Manaus, Amazonas, Brazil

    F. X. Nobre

  4. Instituto de Desenvolvimento Tecnológico, Manaus, Amazonas, Brazil

    L. Aguilera

  5. Department of Physics, San Diego State University, San Diego, CA, 92182-1233, USA

    M. S. Torikachvili

Authors
  1. J. P. da Silva
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  2. S. Costa
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  5. M. M. da S. Paula
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  6. L. Aguilera
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  7. M. S. Torikachvili
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  8. Y. Leyet
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Contributions

All authors contributed to the study, design, sample preparation, data collection, analysis, and manuscript preparation. All authors read and approved the final version of the manuscript.

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Correspondence to Y. Leyet.

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da Silva, J.P., Costa, S., Nobre, F.X. et al. Poly(o-methoxyaniline) Modified by the Biphasic Ceramic System Na2Ti3O7/ Na2Ti6O13. J Inorg Organomet Polym 33, 1381–1387 (2023). https://doi.org/10.1007/s10904-023-02608-w

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