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Syntheses, Crystal Structures and Properties of Two Supramolecular Coordination Polymers with 2,6-Pyridinedicarboxylic Acids and 4,4′-Bis(imidazolyl)biphenyl

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Abstract

Two supramolecular coordination polymers, [Cu(PDA)(4,4′-bibp)]n (1) and [Zn(PDA)(4,4′-bibp)]n (2) (PDA = 2,6-pyridinedicarboxylic acid and 4,4′-bibp = 4,4′-bis(imidazolyl)biphenyl), have been obtained under hydrothermal conditions. The two polymers were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction analysis. The X-ray single crystal analysis revealed that two complexes exhibit different supramolecular architectures. The photocatalytic studies indicate complex 1 is a good candidate for the photocatalytic degradation of methylene blue, rhodamine B and methylene violet. The photoluminescence behaviour of complex 2 was also discussed.

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Acknowledgements

This research was supported by the National Natural Science Foundation of China to C.F. Bi (No. 21371161), the Specialized Research Fund for the Doctoral Program of Higher Education of China (20120132110015).

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Authors and Affiliations

  1. Ocean University of China, Qingdao, Shandong, China

    Zi-Ao Zong, **ang-Min Meng, **n Li, Lian-Sheng Cui & Yu-Hua Fan

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  1. Zi-Ao Zong
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Correspondence to Yu-Hua Fan.

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Zong, ZA., Meng, XM., Li, X. et al. Syntheses, Crystal Structures and Properties of Two Supramolecular Coordination Polymers with 2,6-Pyridinedicarboxylic Acids and 4,4′-Bis(imidazolyl)biphenyl. J Inorg Organomet Polym 26, 519–526 (2016). https://doi.org/10.1007/s10904-016-0338-2

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