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Syntheses, Structure and Characterization of a New Pb(II) Coordination Polymer Based on 1,10-Phenanthroline Derivative and 5-Hydroxyisophthalic Acid

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Abstract

A new Pb(II) coordination polymer, namely, [Pb2(5-IPA)2(L)2]⋅H2O (1) (L = 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol and 5-H2IPA = 5-hydroxyisophthalic acid), has been synthesized under hydrothermal condition. The complex was characterized by single-crystal X-ray diffraction. 1 shows one-dimensional chain structure. The neighboring chains are extended into a two-dimensional supramolecular layer by π···π interactions. Further, two-dimensional layer structures are joined together by hydrogen-bonding interactions to yield a three-dimensional supramolecular structure. In addition, the thermogravimetric analysis and luminescent property of 1 have been investigated.

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The data underlying this article are available in the article and in its online supplementary material.

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Funding

This research was supported by the National Natural Science Foundation of China (No. 52170080) and the Scientific and Technological Develo** Project of Jilin Province (No. YDZJ202201ZYTS595).

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Contributions

YS: Investigation, Synthesized, Writing—Reviewing, Editing. TF:. Collecting data, Investigation. JN: , Synthesized of ligand, Investigation. JL: Investigation, Collecting data, Validation, XW: Conceptualization, Investigation, Editing. LC: Supervision, Editing.

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Correspondence to **uyan Wang or Limin Chang.

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Song, Y., Fu, T., Ning, J. et al. Syntheses, Structure and Characterization of a New Pb(II) Coordination Polymer Based on 1,10-Phenanthroline Derivative and 5-Hydroxyisophthalic Acid. J Clust Sci 35, 217–223 (2024). https://doi.org/10.1007/s10876-023-02478-9

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