Abstract
In pursuit of functionality and miniaturization in electronics, 3D integrated packaging requires low-temperature solders. This study explores a novel low-temperature lead-free SnBiIn solder. The solder has an ultimate tensile strength of 43.9 MPa, an elongation after break of 36.5%, and a low melting point of 91.8 °C. It is environmentally friendly with a homogeneous structure. Under controlled conditions of reflow at 150 °C for 5 min, the solder exhibited a solder/Cu(substrate) wetting angle of 32.6° and an average intermetallic compound (IMC) thickness of 2.3 μm—both meeting rigorous electronic industry standards. Furthermore, the Cu/SnBiIn/Cu joint demonstrated a substantial shear strength of 34.4 ± 1 MPa. These results highlight the potential of this lead-free, low-temperature solder for electronic packaging applications.
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The data that support the findings of this study are available from the corresponding author upon reasonable request.
References
H.R. Kotadia, P.D. Howes, S.H. Mannan, A review: on the development of low melting temperature Pb-free solders. Microelectron. Reliab. 54, 1253 (2014). https://doi.org/10.1016/j.microrel.2014.02.025
H.-Y. Huang, C.-W. Yang, Y.-C. Peng, Effects on the microstructure and mechanical properties of Sn-0.7Cu lead-free solder with the addition of a small amount of magnesium. Sci. Eng. Compos. Mater. 23, 641 (2015). https://doi.org/10.1515/secm-2014-0130
W.R. Osório, A. Garcia, Interrelation of wettability–microstructure–tensile strength of lead-free Sn–Ag and Sn–Bi solder alloys. Sci. Technol. Weld. Join. 21, 429 (2016). https://doi.org/10.1080/13621718.2015.1124176
T. An, F. Qin, Effects of the intermetallic compound microstructure on the tensile behavior of Sn3.0Ag0.5Cu/Cu solder joint under various strain rates. Microelectron. Reliab. 54, 932 (2014). https://doi.org/10.1016/j.microrel.2014.01.008
S.Q. Gu, Material innovation opportunities for 3D integrated circuits from a wireless application point of view. MRS Bull. 40, 233 (2015). https://doi.org/10.1557/mrs.2015.9
H.F. Zou, Q.K. Zhang, Z.F. Zhang, Eliminating interfacial segregation and embrittlement of bismuth in SnBi/Cu joint by alloying Cu substrate. Scr. Mater. 61, 308 (2009). https://doi.org/10.1016/j.scriptamat.2009.04.009
F. Wang, H. Chen, Y. Huang, L. Liu, Z. Zhang, Recent progress on the development of Sn–Bi based low-temperature Pb-free solders. J. Mater. Sci. Mater. Electron. 30, 3222 (2019). https://doi.org/10.1007/s10854-019-00701-w
D.L. Han, Y.-A. Shen, S. **, H. Nishikawa, Microstructure and mechanical properties of the In–48Sn–xAg low-temperature alloy. J. Mater. Sci. 55, 10824 (2020). https://doi.org/10.1007/s10853-020-04691-7
S. Liu, S. Xue, P. Xue, D. Luo, Present status of Sn–Zn lead-free solders bearing alloying elements. J. Mater. Sci. Mater. Electron. 26, 4389 (2015). https://doi.org/10.1007/s10854-014-2659-7
M. Deshpande, R. Chaudhari, P. Ramesh Narayanan, H. Kale, Evaluation of shear properties of indium solder alloys for cryogenic applications. J. Mater. Eng. Perform. 30, 7958 (2021). https://doi.org/10.1007/s11665-021-05983-y
K.-K. Xu, L. Zhang, L.-L. Gao, N. Jiang, L. Zhang, S.-J. Zhong, Review of microstructure and properties of low temperature lead-free solder in electronic packaging. Sci. Technol. Adv. Mater. 21, 689 (2020). https://doi.org/10.1080/14686996.2020.1824255
B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent, Microstructural development in equiatomic multicomponent alloys. Mater. Sci. Eng. A (2004). https://doi.org/10.1016/j.msea.2003.10.257
S. Wang, J. Feng, S. Wang, K. Wang, M. Yu, Y. Tian, Interfacial reaction between novel high entropy alloy SnPbInBiSb and Cu substrate. Mater. Lett. 325, 132901 (2022). https://doi.org/10.1016/j.matlet.2022.132901
Y. Liu, L. Pu, Y. Yang, Q. He, Z. Zhou, C. Tan, X. Zhao, Q. Zhang, K.N. Tu, A high-entropy alloy as very low melting point solder for advanced electronic packaging. Mater. Today Adv. 7, 100101 (2020). https://doi.org/10.1016/j.mtadv.2020.100101
R.E. Villarreal-Loya, C.G. Garay-Reyes, A. Martínez-García, X. Atanacio-Sánchez, P.A. Guerrero-Seañez, I. Estrada-Guel, J.M. Mendoza-Duarte, Design of a Multicomponent Alloy for Application in Electronic Components Solder. Microsc Microanal 29, 578 (2023). https://doi.org/10.1093/micmic/ozad067.279
M.L. Huang, Q. Zhou, N. Zhao, L.D. Chen, Interfacial microstructure and mechanical properties of In–Bi–Sn lead-free solder. J. Mater. Sci. Mater. Electron. 24, 2624 (2013). https://doi.org/10.1007/s10854-013-1143-0
L. Pu, Y. Liu, Y. Yang, Q. He, Z. Zhou, X. Zhao, C. Tan, K.N. Tu, Effect of adding Ag to the medium entropy SnBiIn alloy on intermetallic compound formation. Mater. Lett. 272, 127891 (2020). https://doi.org/10.1016/j.matlet.2020.127891
R.E. Villarreal-Loya, C.G. Garay-Reyes, J.M. Mendoza-Duarte, J.L. Hernández-Rivera, J.J. Cruz-Rivera, I. Estrada-Guel, R. Martínez-Sánchez, Ultra-low-temperature lead-free multicomponent alloy solder for application in heat-sensitive electronic components. Mater. Lett. 343, 134342 (2023). https://doi.org/10.1016/j.matlet.2023.134342
Z. Wang, Q.K. Zhang, Y.X. Chen, Z.L. Song, Influences of Ag and in alloying on Sn-Bi Eutectic solder and SnBi/Cu solder joints. J. Mater. Sci. Mater. Electron. 30, 18524 (2019). https://doi.org/10.1007/s10854-019-02206-y
R. Canyook, K. Fakpan, Effect of Cu and Ni Addition on microstructure and wettability of Sn-Zn solders. Key Eng. Mater. 728, 9 (2017)
I. Artaki, A. Jackson, P.T. Vianco, Evaluation of lead- free solder joints in electronic assemblies. J. Electron. Mater. 23, 757 (1994). https://doi.org/10.1007/bf02651370
M.F. Arenas, V.L. Acoff, Contact angle measurements of Sn-Ag and Sn-Cu lead-free solders on copper substrates. J. Electron. Mater. 33, 1452 (2004). https://doi.org/10.1007/s11664-004-0086-x
M.A.A. Mohd Salleh, S.D. McDonald, H. Yasuda, A. Sugiyama, K. Nogita, Rapid Cu6Sn5 growth at liquid Sn/solid Cu interfaces. Scr. Mater. 100, 17 (2015). https://doi.org/10.1016/j.scriptamat.2014.11.039
H. Ma, B. Zhao, G. Wu, Z. Li, Y. Gao, A SnBiAgIn solder alloy with exceptional mechanical properties by rapid quenching. J. Mater. Sci. Mater. Electron. 32, 8167 (2021). https://doi.org/10.1007/s10854-021-05539-9
R. Sayyadi, H. Naffakh-Moosavy, The role of intermetallic compounds in controlling the microstructural, physical and mechanical properties of Cu-[Sn-Ag-Cu-Bi]-Cu solder joints. Sci. Rep. (2019). https://doi.org/10.1038/s41598-019-44758-3
N. Javid, R. Sayyadi, F. Khodabakhshi, Lead-free Sn-based/MW-CNTs nanocomposite soldering: effects of reinforcing content, Ni-coating modification, and isothermal ageing treatment. J. Mater. Sci. Mater. Electron. 30, 4737 (2019). https://doi.org/10.1007/s10854-019-00767-6
S. Phairote Sungkhaphaitoon, Chantaramanee, Effect of Aging temperature on the microstructure and shear strength of SAC0307-0.1Ni lead-free solders in copper joints. Russ. J. Non-ferr. Met. 61, 89 (2020). https://doi.org/10.3103/s1067821220010162
J. Zhou, Y. Sun, F. Xue, Properties of low melting point Sn–Zn–Bi solders. J. Alloys Compd. 397, 260 (2005). https://doi.org/10.1016/j.jallcom.2004.12.052
W.J. Tomlinson, A. Fullylove, Strength of tin-based soldered joints. J. Mater. Sci. 27, 5777 (1992). https://doi.org/10.1007/bf01119737
Funding
This work was supported by Science and Technology Innovation 2025 Major Project of Ningbo (Grant No. 2022Z103).
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All authors contributed to the study conception and design. SZ: Formal Analysis, Writing—Original Draft, Investigation. WL: Resources, Methodology. PL: Investigation, Validation. FL: Supervision, Validation. HX: Methodology, Funding Acquisition. TD: Data Curation, Writing—Review & Editing. All authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Zhang, S., Long, W., Li, P. et al. Low-temperature lead-free SnBiIn solder for electronic packaging. J Mater Sci: Mater Electron 35, 690 (2024). https://doi.org/10.1007/s10854-024-12405-x
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DOI: https://doi.org/10.1007/s10854-024-12405-x