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Structural and magnetic property modification of strontium hexaferrite system using A-site Ca do**

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Abstract

Ca-doped strontium (Sr1-xCaxFe12O19, x = 0.10–0.50) hexaferrite samples were synthesized following the solid-state reaction route. Absence of secondary phases in X-ray data points to a maximum value of Ca solubility in SrM ≈ 50% (at 1200 °C). The doped samples develop preferred orientations (along (006) and (008) crystallographic planes) at highest Ca do** (x = 0.50). XRD confirmed a reduction in `c’ parameter from 23.036 Å to 23.016 Å with variation in x from 0.10–0.50. FESEM micrographs reveal an enhancement in sample density and an increase in the average grain size (≈1.35 μm at x = 0.10 to ≈1.83 μm at x = 0.50). Ms value is maximum (≈ 79.56 emu/g) at x = 0.10 whereas Mr value is maximum (≈ 53.31 emu/g) at x = 0.50. The observed Ms value is the highest amongst the literature reported values for doped and undoped SrM samples. The coercivity decreases from 5032 Oe (at x = 0.00) to 2561 Oe (at x = 0.50).

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Data availability

The data that support the findings of this study are available from the corresponding author on reasonable request. All authors are declared that all data and materials as well as software application or custom code support their published claims and comply with field standards.

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Acknowledgements

The authors also gratefully acknowledge Dr. P.D. Babu, UGC DAE Consortium for Scientific Research, (Mumbai center) for cooperation in magnetic characterization.

Funding

The authors extend their sincere appreciation to Researchers Supporting Project number (RSP2024R391) at King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Department of Physics, Guru Nanak Dev University, Amritsar, 143005, India

    Swati Verma, Anupinder Singh, Paramjit Kaur & Mandeep Singh

  2. Department of Chemistry, Guru Nanak Dev University, Amritsar, 143005, India

    Sachin Kumar Godara

  3. Model Institute of Engineering and Technology, Kot Bhalwal, Jammu, Jammu & Kashmir, 181122, India

    Surinder Singh

  4. Department of Physics and Photonics Sciences, National Institute of Technology, Hamirpur, 177005, India

    Sandeep Sharma

  5. Department of Chemistry, College of Science, King Saud University, 11451, Riyadh, Saudi Arabia

    Jahangeer Ahmed & Saad M. Alshehri

  6. Department of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul, 05006, Republic of South Korea

    Sajjad Hussain

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Contributions

We hereby declare that the below mentioned authors have contributed to the preparation and finalization of our manuscript titled “Structural and Magnetic Property Modification of Strontium Hexaferrite System using A-site Ca do**”. Conceptualization [MS, SV]. Methodology [SV, SKG]. Sample Preparation [SV, SS, PK]. Analysis and Investigation [SV, AS, SS, MS]. Original Draft Preparation [SV]. Writing- Review and editing [SV, JA, MS, SMA, SH]. Supervision [MS].

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Correspondence to Mandeep Singh.

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Verma, S., Singh, A., Godara, S.K. et al. Structural and magnetic property modification of strontium hexaferrite system using A-site Ca do**. J Mater Sci: Mater Electron 35, 516 (2024). https://doi.org/10.1007/s10854-024-12266-4

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