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Synthesis, characterizations, photo-electrochemical, and physical properties of a new 0D copper(II) complex

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Abstract

A new hybrid single crystal was synthetized by chemical route. The binuclear complex containing N-donor ligand [Cu2(C8H4O5)(C10H8N2)4]·(C8H5O5)2·C8H6O5·5H2O was obtained by the reaction of 5-hydroxyisophthalic acid (5-OH-H2BDC) and 2,2′-bipyridine (2,2′-bipy) with Cu(CH3COO)2·H2O. The structure consists of 3-D supramolecular architecture and the complex was characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, UV–Vis diffuse reflectance, and thermal analysis (TGA/DTA). The diffuse reflectance gives two optical transitions, directly (3.34 eV) and indirectly (2.64 eV) permitted. The transport properties measured up to 400 K indicate semiconducting properties. The permittivity (ε = 850) of the binuclear complex was determined from the dielectric measurements. The capacitance−2–potential (C−2–E) characteristic plotted in Na2SO4 (0.1 M) electrolyte shows n-type conduction with a flat band potential (Efb) of 0.46 VSCE, typical of materials with Cu2+:3d conduction band. The electrochemical impedance spectroscopy studied in a wide frequency range (1 mHz to 105 Hz) indicates the contribution of both bulk and grain boundaries with a constant phase element.

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Data availability

The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors gratefully acknowledge the financial support of the Faculty of Chemistry (Algiers)

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Authors and Affiliations

  1. Crystallography-Thermodynamics Laboratory, Faculty of Chemistry, USTHB, BP 32, 16111, Algiers, Algeria

    F. M. Laoui & F. Balegroune

  2. Research Centre in Analytical Chemistry and Physics (CRAPC), BP384, Bou-Ismail, 42004, Tipaza, RP, Algeria

    F. Saib

  3. UMR CNRS 6521, Univ. Brest (UBO), C.S. 93837–29238, Brest Cedex 3, France

    C. Charles

  4. Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, USTHB, BP 32, 16111, Algiers, Algeria

    M. Trari

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  1. F. M. Laoui
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Contributions

F. M. Laoui contributed to validation, investigation, visualization, resources, writing of the original draft, and writing, reviewing, and editing of the manuscript. F. Balegroune contributed to methodology, validation, writing of the original draft, and writing, reviewing, and editing of the manuscript. F. Saib and M. Trari contributed to methodology, conceptualization, validation, writing of the original draft, writing, reviewing, and editing of the manuscript, visualization, and supervision. C. Charles gathered resources and performed supervision.

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Correspondence to F. M. Laoui.

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Laoui, F.M., Balegroune, F., Saib, F. et al. Synthesis, characterizations, photo-electrochemical, and physical properties of a new 0D copper(II) complex. J Mater Sci: Mater Electron 33, 11701–11711 (2022). https://doi.org/10.1007/s10854-022-08136-6

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