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One-step synthesis of reduced graphene oxide and magnetic graphene: characterization and its application in electrochemical detection of lead (II) ions

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Abstract

Herein, reduced graphene oxide (RGO) and magnetic reduced graphene (RGO–MNP) nanosheets were synthesized by using Fe2+ ions via the facile and green method for the first time. Prepared nanomaterials were characterized by UV–Vis, FTIR, Raman, XRD, VSM and TEM techniques. Interaction of RGO, GO, RGO–MNP and GO–MNP nanosheets with two valance metal ions were investigated by tracing square wave voltammetry of a modified carbon paste electrode (CPE) responses. Both modified CPE by RGO–MNP and GO–MNP showed higher response between ions to Pb2+ ion. In optimized experimental and instrumental conditions, a linear calibration curve from 1.0 × 10−9 to 1.0 × 10−3 M Pb2+ with detection limit as 3.07 × 10−9 M Pb2+ was observed for modified CPE by GO–MNP, and two linear calibration curve from 1.0 × 10−9 to 5.0 × 10−6 and from 1.0 × 10−5 to 1.0 × 10−3 M Pb2+ with detection limit as 8.13 × 10−10 M Pb2+ were observed for modified CPE by RGO–MNP. Prepared sensors showed good stability, sensitivity, repeatability and reproducibility in this work.

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Authors and Affiliations

  1. Reactor and Nuclear Safety School, Nuclear Science and Technology Research Institute, Isfahan, Islamic Republic of Iran

    Mojtaba Bagherzadeh

  2. Department of Chemistry, Islamic Azad University of Shahreza, Shahreza, Islamic Republic of Iran

    Mahdi Jabouri-Abassi

  3. Department of Chemistry, Farhangian University, Tehran, Islamic Republic of Iran

    Zakyeh Akrami

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  1. Mojtaba Bagherzadeh
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  2. Mahdi Jabouri-Abassi
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  3. Zakyeh Akrami
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Correspondence to Mojtaba Bagherzadeh.

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10854_2019_2407_MOESM1_ESM.docx

SWVs regarding the interaction of divalent cations with CPE/GO–MNP and CPE/RGO–MNP, Optimization of instrumental conditions, UV–Vis spectra at different deposition time and concentration of RGO, CVs regarding the effect of scan rate on CPE response. Supplementary material 1 (DOCX 1637 kb)

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Bagherzadeh, M., Jabouri-Abassi, M. & Akrami, Z. One-step synthesis of reduced graphene oxide and magnetic graphene: characterization and its application in electrochemical detection of lead (II) ions. J Mater Sci: Mater Electron 30, 20229–20242 (2019). https://doi.org/10.1007/s10854-019-02407-5

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