SpringerLink
Log in

Structure and magnetic analyses of hexaferrite Sr1−xLaxFe22+Fe163+O27 prepared via the solid-state reaction

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

W-type ferrite Sr1−xLaxFe22+Fe163+O27 (x = 0.00, 0.05, 0.08, 0.10, 0.13 and 0.15) powders and magnets were prepared via the solid-state reaction in nitrogen. Phase components of the powder samples were examined by X-ray diffraction (XRD). XRD results demonstrated the appearance of pure phase hexagonal crystal structure and calculate the lattice constants c and a, c/a ratio, cell volume (Vcell), X-ray density (dX-ray) and crystallite size (D) parameters according to XRD data. Scanning electron microscopy (SEM) was used to observe the morphology of the magnets. SEM analyses revealed the hexagonal morphology of the ferrites. The magnetic characteristics of magnetic powders were measured by a vibrating sample magnetometer (VSM), and the magnetic characteristics of magnets were also measured by a permanent magnetic measuring equipment. The results indicate that, the synthesized samples with a low coercive force value and a considerable saturation magnetization are best able to make optical read-out of the magnetic storage information in erasable video and audio discs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. R.C. Pullar, Hexagonal ferrites: a review of the synthesis, properties and applicatios of hexaferrite ceramics. Prog. Mater. Sci. 57, 1191–1334 (2012)

    Article  Google Scholar 

  2. Y. Slimani, A. Baykal, A. Manikandan, Effect of Cr3+ substitution on AC susceptibility of Ba hexaferrite nanoparticles. J. Magn. Magn. Mater. 458, 204–212 (2018)

    Article  Google Scholar 

  3. Y. Slimani, A. Baykal, M. Amir et al., Substitution effect of Cr3+ on hyperfine interactions, magnetic and optical properties of Sr-hexaferrites. Ceram. Int. 44, 15995–16004 (2018)

    Article  Google Scholar 

  4. S. Asiri, S. Güner, A. Demir et al., Synthesis and magnetic characterization of Cu substituted barium hexaferrites. J. Inorg. Organomet. Polym. 28, 1065–1071 (2018)

    Article  Google Scholar 

  5. G.F.M. Pires Júnior, H.O. Rodrigues, J.S. Almeida et al., Study of the dielectric and magnetic properties of Co2Y, Y-type hexaferrite (Ba2Co2Fe12O22) added with PbO and Bi2O3 in the RF frequency range. J. Alloy. Compd. 493, 326–334 (2010)

    Article  Google Scholar 

  6. M. Ahmad, M. Ahmad, I. Ali et al., Temperature dependent structural and magnetic behavior of Y-type hexagonal ferrites synthesized by sol–gel autocombustion. J. Alloy. Compd. 651, 749–755 (2015)

    Article  Google Scholar 

  7. M. Ahmad, I. Ali, R. Grössinger, Effects of divalent ions substitution on the microstructure, magnetic and electromagnetic parameters of Co2W hexagonal ferrites synthesized by sol–gel method. J. Alloy. Compd. 579, 57–64 (2013)

    Article  Google Scholar 

  8. M.A. Ahmed, N. Okasha, M. Oaf, R.M. Kershi. The role of Mg substitution on the microstructure and magnetic properties of BaCoZn W-type hexagonal ferrites. J. Magn. Magn. Mater. 314, 128–134 (2007)

    Article  Google Scholar 

  9. G.R. Gordani, M. Mohseni et al., Microstructure, magnetic and microwave absorptive behavior of doped W-type hexaferrite nanoparticles prepared by co-precipitation method. Mater. Res. Bull. 76, 187–194 (2016)

    Article  Google Scholar 

  10. D.M. Hemeda, A. Al-Sharif, O.M. Hemeda, Effect of Co substitution on the structural and magnetic properties of Zn–W hexaferrite. J. Magn. Magn. Mater. 315, L1–L7 (2007)

    Article  Google Scholar 

  11. L.A. Bashkirov, G.P. Dudchik, T.A. But’ko et al., Barium–strontium and nickel–cobalt solid-state interdiffusion between hexagonal W-ferrites BaM2Fe16O27and SrM2Fe16O27 (M = Ni2+, Co2+). Inorg. Mater. 39, 525–529 (2003)

    Article  Google Scholar 

  12. D. Lisjak, A. Žnidaršič, A. Sztanislav, M. Drofenik, A two-step synthesis of NiZn–W hexaferrites. J. Eur. Ceram. Soc. 28, 2057–2062 (2008)

    Article  Google Scholar 

  13. P.S. Sawadh, D.K. Kulkarni, Magnetic and electrical studies CU2-W ferrite. Mater. Chem. Phys. 63, 170–173 (2000)

    Article  Google Scholar 

  14. L.X. Wang, J. Song, Q.T. Zhang et al., The microwave magnetic performance of Sm3+ doped BaCo2Fe16O27. J. Alloys. Compd. 481, 863–866 (2009)

    Article  Google Scholar 

  15. Y.F. Wu, Y. Huang, L. Niu et al., Pr3+-substituted W-type barium ferrite: preparation and electromagnetic properties. J. Magn. Magn. Mater. 324, 616–621 (2012)

    Article  Google Scholar 

  16. J.J. Xu, H.F. Zou, H.Y. Li et al., Influence of Nd3+ substitution on the microstructure and electromagnetic properties of barium W-type hexaferrite. J. Alloys. Compd. 490, 552–556 (2010)

    Article  Google Scholar 

  17. A. Manikandan, E. Manikandan, B. Meenatchi et al., Rare earth element (REE) lanthanum doped zinc oxide (La: ZnO) nanomaterials: synthesis structural optical and antibacterial studies. J. Alloys Compd. 723, 1155–1161 (2017)

    Article  Google Scholar 

  18. K. Elayakumar, A. Dinesh, A. Manikandan et al., Structural, morphological, enhanced magnetic properties and antibacterial biomedical activity of rare earth element (REE) Cerium (Ce3+) doped CoFe2O4 nanoparticles. J. Magn. Magn. Mater. (2018). https://doi.org/10.1016/j.jmmm.2018.09.089

    Google Scholar 

  19. R. Bomila, S. Srinivasan, S. Gunasekaran, A. Manikandan, Enhanced photocatalytic degradation of methylene blue dye, opto-magnetic and antibacterial behaviour of pure and La-doped ZnO nanoparticles. J. Supercond. Nov. Magn. 31, 855–864 (2018)

    Article  Google Scholar 

  20. C. Sasikala, G. Suresh, N. Durairaj et al., Chemical, morphological, structural, optical, and magnetic propertiesof transition metal titanium (Ti)-doped LaFeO3 nanoparticles. J. Supercond. Nov. Magn. (2018). https://doi.org/10.1007/s10948-018-4879-1

    Google Scholar 

  21. M.J. Iqbal, R.A. Khan, Enhancement of electrical and dielectric properties of Cr doped BaZn2 W-type hexaferrite for potential applications in high frequency devices. J. Alloys Compd. 478, 847–852 (2009)

    Article  Google Scholar 

  22. M.J. Iqbal, Farooq, Impact of Pr-Ni substitution on the electrical and magnetic properties of chemically derived nanosized hexaferrites. J. Alloys Compd. 505, 560–567 (2010)

    Article  Google Scholar 

  23. M.M.L. Sonia, S. Anand, V. Maria Vinosel et al., Effect of lattice strain on structure, morphology and magneto-dielectric properties of spinel NiGdxFe2−xO4 ferrite nano-crystallites synthesized by sol-gel route. J. Magn. Magn. Mater. 466, 238–251 (2018)

    Article  Google Scholar 

  24. A.T. Ravichandran, J. Srinivas, R. Karthick et al., Facile combustion synthesis, structural, morphological, optical and antibacterial studies of Bi1−xAlxFeO3 (0.0 ≤ x ≤ 0.15) nanoparticles. Ceram. Int. 44, 13247–13252 (2018)

    Article  Google Scholar 

  25. Y. Slimani, H. Güngüneş, M. Nawaz,et al, Magneto-optical and microstructural properties of spinel cubic copper ferrites with Li-Al co-substitution. Ceram. Int. 44, 14242–14250 (2018)

    Article  Google Scholar 

  26. S. Asiri, M. Sertkol, S. Guner et al., Hydrothermal synthesis of CoyZnyMn1−2yFe2O4 nanoferrites: magnetooptical investigation. Ceram. Int. 44, 5751–5759 (2018)

    Article  Google Scholar 

  27. F.K. Lotgering, P.H.G.M. Vromans, M.A.H. Huyberts, Permanent-magnet material obtained by sintering the hexagonal ferrite W = BaFe18O27. J. Appl. Phys. 51, 5913–5918 (1980)

    Article  Google Scholar 

  28. T.R. Wagner, Preparation and crystal structure analysis of magnetoplumbite-type BaGa12O19. J. Solid State Chem. 136, 120–124 (1998)

    Article  Google Scholar 

  29. F.R. Lv, X.S. Liu, S.J. Feng, Microstructure and magnetic properties of W-type hexagonal ferrites Ba1−xSrxFe2 2+Fe16 3+O27. Mater. Lett. 157, 277–280 (2015)

    Article  Google Scholar 

  30. G. Albanese, M. Carbucicchio, G. Asti, Spin-order and magnetic properties of BaZn2Fe16O27(Zn2-W) hexagonal ferrite. Appl. Phys. 11, 81–88 (1976)

    Article  Google Scholar 

  31. S. Ram, J.C. Joubert, Synthesis and magnetic properties of SrZn2-W type hexagonal ferrites using a partial 2Zn2+ → Li + Fe3+ substitution: a new series of permanent magnets materials. J. Magn. Magn. Mater. 99, 133–144 (1991)

    Article  Google Scholar 

  32. A.P. Liplot, A. Gerard, F. Grandjean, Analysis of the superexchange interactions paths in the W-hexagonal ferrites. IEEE Trans. Magn. 18, 1463–1465 (1982)

    Article  Google Scholar 

  33. A. Godlyn Abraham, A. Manikandan, E. Manikandan et al., Enhanced opto-magneto properties of NixMg1−xFe2O4 (0.0 ≤ x ≤ 1.0) ferrites nano-catalysts. J. Nanoelectron. Optoelectron. 12, 1326–1333 (2017)

    Article  Google Scholar 

  34. E. Hema, A. Manikandan, P. Karthika et al., Magneto-optical properties of reusable spinel NixMg1−xFe2O4(0.0 ≤ x ≤ 1.0) nano-catalysts. J. Nanosci. Nanotechnol. 16, 7325–7336 (2016)

    Article  Google Scholar 

  35. A. Godlyn Abraham, A. Manikandan, E. Manikandan,et al, Enhanced magneto-optical and photo-catalytic properties of transition metal cobalt (Co2+ ions) doped spinel MgFe2O4 ferrite nanocomposites. J. Magn. Magn. Mater. 452, 380–388 (2018)

    Article  Google Scholar 

  36. C. Sasikala, N. Durairaj, I. Baskaran et al., Transition metal titanium (Ti) doped LaFeO3 nanoparticles for enhanced optical structural and magnetic properties. J. Alloys Compd. 712, 870–877 (2017)

    Article  Google Scholar 

  37. R. Rajendran, R. Muralidharan, R.S. Gopalakrishnan et al., Controllable synthesis of single-crystalline Fe3O4 nanorice by a one-pot, surfactant-assisted hydrothermal method and its properties. Eur. J. Inorg. Chem. 2011, 5384–5389 (2011)

    Article  Google Scholar 

  38. Y.J. Yang, F.H. Wang et al., Influence of Nd-NbZn co-substitution on structural, spectral and magnetic properties of M-type calcium-strontium hexaferrites Ca0.4Sr0.6−xNdxFe12.0−x(Nb0.5Zn0.5)xO19. J.Alloys Compd. 765, 616–623 (2018)

    Article  Google Scholar 

  39. I. Khan, I. Sadiq, M.N. Ashiq et al., Role of Ce–Mn substitution on structural, electrical and magnetic properties of W-type strontium hexaferrites. J.Alloys Compd. 509, 8042–8046 (2011)

    Article  Google Scholar 

  40. J. Tang, X.S. Liu, et.al. Microstructure and characterization of W-type hexaferrite Ba1−xLaxFe2 2+Fe16 3+O27 prepared by solid state method. J.Magn.Magn.Mater. 452, 352–359 (2018)

    Article  Google Scholar 

  41. R.G. Gholam, M. Marzieh et al., Microstructure, magnetic and microwave absorptive behavior of doped W-type hexaferrite nanoparticles prepared by co-precipitation method. Mater. Res. Bull. 76, 187–194 (2016)

    Article  Google Scholar 

  42. C.A. Stergious, G. Litsardakis, Electromagnetic properties of Ni and La doped strontium hexaferrites in the microwave region. J.Alloys Compd. 509, 6609–6615 (2011)

    Article  Google Scholar 

  43. Y.J. Yang, X.S. Liu, D.L. **, The impact of the iron content on the microstructure and magnetic properties of M-type ferrites Sr0.45Ca0.25La0.30FexCo0.25O19. Mater. Sci. Eng. B 186, 106–111 (2014)

    Article  Google Scholar 

  44. K. Huang, X.S. Liu, F.G. Lucia et al., Structure, magnetic and magneto-optical properties of La-Ca-Co substituted strontium ferrites. Mater. Technol. 32, 85–89 (2017)

    Article  Google Scholar 

Download references

Acknowledgements

This work was funded by the National Natural Science Foundation of China (Nos. 51472004, 51272003).

Author information

Authors and Affiliations

  1. Engineering Technology Research Center of Magnetic Materials, School of Physics & Materials Science, Anhui University, Hefei, 230601, People’s Republic of China

    ** Tang, **ansong Liu, Xucai Kan & Khalid Mehmood Ur Rehman

  2. Public Experimental Teaching Center, Panzhihua University, Panzhihua, 617000, People’s Republic of China

    Dan Li

  3. Computational Physics Key Laboratory of Sichuan Province, School of Physics and Electronic Engineering, Yibin University, Yibin, 644007, People’s Republic of China

    Yujie Yang

Authors
  1. ** Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. **ansong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yujie Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xucai Kan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Khalid Mehmood Ur Rehman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to **ansong Liu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tang, J., Liu, X., Li, D. et al. Structure and magnetic analyses of hexaferrite Sr1−xLaxFe22+Fe163+O27 prepared via the solid-state reaction. J Mater Sci: Mater Electron 30, 284–291 (2019). https://doi.org/10.1007/s10854-018-0291-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-0291-7

Search

Navigation