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Self-Assembly Processes in Aqueous Solutions of Heat-Sensitive Star-Shaped Poly-2-Ethyl-2-Oxazoline

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Fibre Chemistry Aims and scope

Light scattering and turbidimetry methods were used to study the self-assembly of macromolecules of eight-arm star-shaped poly-2-ethyl-2-oxazoline in aqueous solution. A sample with molecular mass 1100 g/mole was studied. The phase separation temperature for this polymer is higher than for stars with arms of poly-2-isopropyl-2-oxazoline, which is a consequence of the higher dehydration temperature of poly-2-ethyl-2-oxazoline. The star-shaped architecture and the presence of a hydrophobic calix[8]arene ring for this polymer were found to have hardly any effect on the low critical solution temperature.

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This study was carried out with the financial support of the Russian Basic Research Fund in the framework of Science Project No. 18-33-00153.

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Authors and Affiliations

  1. Institute of High-Molecular Weight Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    T. Yu. Kirile, M. P. Kurlykin & A. V. Ten’kovtsev

  2. St. Petersburg National Information Technology, Mechanics, and Optics Research University, St. Petersburg, Russia

    A. I. Tobolina & A. P. Filippov

  3. St. Petersburg State University of Technology and Design, St. Petersburg, Russia

    A. A. Elkina

Authors
  1. T. Yu. Kirile
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  2. A. I. Tobolina
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  3. A. A. Elkina
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  4. M. P. Kurlykin
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  5. A. V. Ten’kovtsev
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  6. A. P. Filippov
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Correspondence to T. Yu. Kirile.

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Translated from Khimicheskie Volokna, Vol. 50, No. 3, pp. 103-106, May-June, 2018.

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Kirile, T.Y., Tobolina, A.I., Elkina, A.A. et al. Self-Assembly Processes in Aqueous Solutions of Heat-Sensitive Star-Shaped Poly-2-Ethyl-2-Oxazoline. Fibre Chem 50, 248–251 (2018). https://doi.org/10.1007/s10692-018-9970-7

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  • DOI: https://doi.org/10.1007/s10692-018-9970-7

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