Abstract
The red mud was activated by an acid leaching and reprecipitation approach to be used as NH3-SCR catalyst. The effect of acid concentration on the leaching rates of Fe, Ti, Al, Ca and Na was investigated, specifically, the interaction between Fe and Ti components in the obtained red mud-based catalysts was concerned. With the acid concentration increasing (below 3.1 mol/L), more Fe and Ti are leached out, meanwhile, Ti can be incorporated into Fe2O3 phase and the crystallite size of Fe2O3 becomes smaller, and the obtained catalyst exhibits better low-temperature activity and SO2 resistance. The HRM3.1 catalyst obtained at the acid concentration of 3.1 mol/L possesses strongest reducibility, largest amount of surface chemisorbed oxygen and medium surface acidity. The in-situ DRIFTS results show that more NO can be adsorbed and oxidized over the HRM3.1 catalyst to generate more nitrate species, even though in the presence of SO2, alleviating the suppression of SO2 on the NH3-SCR reaction, and thus the SO2 tolerance is enhanced.
Graphical Abstract
Similar content being viewed by others
References
Xu JQ, Chen GR, Guo F, **e JQ (2018) Chem Eng J 353:507–518. https://doi.org/10.1016/j.cej.2018.05.047
Cai M, Bian X, **e F, Wu WY, Cen P (2021) ChemistrySelect 6:12331–12341. https://doi.org/10.1002/slct.202101358
Shi ZW, Peng QG, E JQ, **e B, Wei J, Yin RX, Fu G (2023) Fuel 331: 125885. https://doi.org/10.1016/j.fuel.2022.125885.
Han L, Cai S, Gao M, Hasegawa J, Wang P, Zhang J, Shi L, Zhang D (2019) Chem Rev 119:10916–10976. https://doi.org/10.1021/acs.chemrev.9b00202
Liu XY, Wang PL, Shen YJ, Bi SY, Ren W, Zhang DS (2022) ACS Catal 12:11306–11317. https://doi.org/10.1021/acscatal.2c02699
Hu WW, He JB, Liu XY, Yu HJ, Jia XY, Yan TT, Han LP, Zhang DS (2022) Environ Sci Technol 56:5170–5178. https://doi.org/10.1021/acs.est.1c08715
Liu XY, Wang PL, Shen YJ, Zheng LR, Han LP, Deng J, Zhang JP, Wang AY, Ren W, Gao F, Zhang DS (2022) Environ Sci Technol 56:11646–11656. https://doi.org/10.1021/acs.est.2c01812
Qi XR, Han LP, Deng J, Lan TW, Wang FL, Shi LY, Zhang DS (2022) Environ Sci Technol 56:5840–5848. https://doi.org/10.1021/acs.est.2c00944
Wu JH, ** SL, Wei XD, Gu FJ, Han Q, Lan YX, Qian CL, Li JQ, Wang XR, Zhang R, Qiao WM, Ling LC, ** ML (2021) Chem Eng J 412: 128712. https://doi.org/10.1016/j.cej.2021.128712.
Chen JW, Wang Y, Liu ZM (2023) J Environ Sci 127:628–640. https://doi.org/10.1016/j.jes.2022.06.027
Mi HC, Yi LS, Wu Q, **a J, Zhang BH (2022) Waste Manage Res 40:1594–1607. https://doi.org/10.1177/0734242X221107987
Das B, Mohanty K (2019) Renew Energy 143:1791–1811. https://doi.org/10.1016/j.renene.2019.05.114
Wang MF, Liu XM (2021) J Hazard Mater 408:124420. https://doi.org/10.1016/j.jhazmat.2020.124420
Wang SH, ** HX, Deng Y, **ao YD (2021) J Cleaner Prod 289:125136. https://doi.org/10.1016/j.jclepro.2020.125136
Khairul M, Zanganeh J, Moghtaderi B (2019) Conserv Recycl 141:483–498. https://doi.org/10.1016/j.resconrec.2018.11.006
Li CM, Zeng H, Liu PL, Yu J, Yan BH, Shi QL, Lu CM, Crittenden J (2020) J Hazard Mater 394:122536. https://doi.org/10.1016/j.jhazmat.2020.122536
Gao C, Yang GP, Wang D, Gong ZQ, Zhang X, Wang B, Peng Y, Li JH, Lu CM, Crittenden J (2020) Chemosphere 257:127215. https://doi.org/10.1016/j.chemosphere.2020.127215
Zhang X, Xuan Y, Wang B, Gao C, Niu SL, Zhao GJ, Wang D, Li JH, Lu CM, Crittenden JC (2022) Front Environ Sci Eng 16(7):88
Lin HF, Abubakar A, Li CM, Li YJ, Wang C, Yu J, Gao SQ (2019) Roy Soc Open Sci 6:191183. https://doi.org/10.1098/rsos.191183
Lin HF, Abubakar A, Li CM, Li YJ, Wang C, Gao SQ, Liu ZE, Yu J (2020) Catal Lett 150:702–712. https://doi.org/10.1007/s10562-019-02953-x
Gong ZQ, Ma J, Wang D, Niu SL (2022). Front Environ Sci Eng. https://doi.org/10.1007/s11783-021-1447-x
Wang B, Ma J, Wang D, Gong ZQ, Shi QL, Gao C, Lu CM, Crittenden J (2021) Catal Today 376:247–254. https://doi.org/10.1016/j.cattod.2020.05.036
Chen QZ, Zhang X, Li B, Niu SL, Zhao GJ, Wang D, Peng Y, Li JH, Lu CM, Crittenden J (2021) Front Environ Sci Eng 15(5):92. https://doi.org/10.1007/s11783-020-1337-7
Qi L, Sun ZG, Tang Q, Wang J, Huang TZ, Sun CZ, Gao F, Tang CJ, Dong L (2020) J Hazard Mater 396:122459. https://doi.org/10.1016/j.jhazmat.2020.122459
Zhang SQ, Zhang C, Wang Q, Ahn WS (2019) Ind Eng Chem Res 58:22857–22865. https://doi.org/10.1021/acs.iecr.9b04383
Liu FD, He H, Zhang C (2008) Chem Commun 2043–2045. https://doi.org/10.1039/B800143J.
Liu FD, He H, Ding Y, Zhang CB (2009) Appl Catal B 93:194–204. https://doi.org/10.1016/j.apcatb.2009.09.029
Liu FD, He H (2010) J Phys Chem C 114:16929–16936. https://doi.org/10.1021/jp912163k
Liu FD, He H, Zhang CB, Feng ZC, Zheng LR, **e YN, Hu TD (2010) Appl Catal B 96:408–420. https://doi.org/10.1016/j.apcatb.2010.02.038
Liu FD, He H, Zhang CB, Shan WP, Shi XY (2011) Catal Today 175:18–25. https://doi.org/10.1016/j.cattod.2011.02.049
Qu WY, Chen YX, Huang ZW, Gao JY, Zhou MJ, Chen JX, Li C, Ma Z, Chen JM, Tang XF (2017) Environ Sci Technol Lett 4:246–250. https://doi.org/10.1021/acs.estlett.7b00124
Chen JX, Qu WY, Chen YX, Liu XN, Jiang XM, Wang H, Zong YH, Ma Z, Tang XF (2018) Chem Cat Chem 10:4683–4688. https://doi.org/10.1002/cctc.201801169
Khaleel A, Parvin M, AlTabaji M, Al-zamly A (2018) J Solid State Chem 175:91–97. https://doi.org/10.1016/j.jssc.2018.01.008
Liu FD, He H, Lian ZH, Shan WP, **e LJ, Asakura K, Yang WW, Deng H (2013) J Catal 175:340–351. https://doi.org/10.1016/j.jcat.2013.08.003
Han L, Gao M, Hasegawa J, Li S, Shen Y, Li H, Shi L, Zhang D (2019) Catalysts Environ Sci Technol 53:6462–6473. https://doi.org/10.1021/acs.est.9b00435
Wang H, Yang MH, ** SL, Zhang R, Li WF, Wang Y, Huo WY, Wang XR, Qiao WM, Ling LC, ** ML (2021) ChemistrySelect 6:3642–3655. https://doi.org/10.1002/slct.202100242
Li WF, ** SL, Zhang R, Wei YB, Wang JC, Yang S, Wang H, Yang MH, Liu Y, Qiao WM, Ling LC, ** ML (2020) RSC Adv 10:12908–12919. https://doi.org/10.1039/d0ra01654c
Yang MH, Wang H, ** SL, Zhang R, Wang Y, Huo WY, Wang XR, ** ML, Qiao WM, Ling LC (2021) Catal Sci Technol 11:2057–2072. https://doi.org/10.1039/D0CY02006K
Han Q, ** SL, Wang JT, Wang JC, Sun PF, Zhou Y, Wang XR, Zhang R, Qiao WM, Ling LC, ** MJ (2022) J Phys Chem Solids 167:110782. https://doi.org/10.1016/j.jpcs.2022.110782
Wei YB, ** SL, Zhang R, Li WF, Wang JC, Yang S, Wang H, Yang MH, Liu Y, Qiao WM, Ling LC, ** ML (2020) Materials 13:475. https://doi.org/10.3390/ma13020475
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Pure Appl Chem 57:603–619. https://doi.org/10.1351/pac198557040603
Li J, Lu GZ, Wu GS, Mao DS, Wang YQ, Guo Y (2012) Catal Sci Technol 2:1865–1871. https://doi.org/10.1039/C2CY20118F
Jampaiah D, Velisoju VK, Devaiah D, Singh M, Mayes ELH, Coyle VE, Reddy BM, Bansal V, Bhargava SK (2019) Appl Surf Sci 473:209–221. https://doi.org/10.1016/j.apsusc.2018.12.048
Song BY, Li C, Zhang XF, Gao R, Cheng XL, Deng ZP, Xu YM, Huo LH, Gao S (2022) J Mater Chem A 10:14411–14422
Li L, Wu Y, Hou X, Chu B, Nan B, Qin Q, Fan M, Sun C, Li B, Dong L, Dong L (2019) Ind Eng Chem Res 58:849–862. https://doi.org/10.1021/acs.iecr.8b05066
Tang C, Wang H, Dong S, Zhuang J, Qu Z (2018) Catal Today 307:2–11. https://doi.org/10.1016/j.cattod.2017.06.005
Zhao L, Li X, Quan X, Chen G (2011) Environ Sci Technol 45:5373–5379. https://doi.org/10.1021/es200784e
Wu Q, Gao H, He H (2006) J Phys Chem B 110:8320–8324. https://doi.org/10.1021/jp060105+
Xu W, He H, Yu Y (2009) J Phys Chem C 113:4426–4432. https://doi.org/10.1021/jp8088148
Gao S, Wang P, Yu F, Wang H, Wu Z (2016) Catal Sci Technol 6:8148–8156. https://doi.org/10.1039/C6CY01502F
** RB, Liu Y, Wang Y, Cen WL, Wu ZB, Wang HQ, Weng XL (2014) Appl Catal B 148–149:582–588. https://doi.org/10.1016/j.apcatb.2013.09.016
Waqif M, Bazin P, Saur O, Lavalley JC, Blanchard G, Touret O (1997) Appl Catal B 11:193–205. https://doi.org/10.1016/S0926-3373(96)00040-9
Wei L, Cui SP, Guo HX, Ma XY, Zhang LJ (2016) J Mole Catal A 421:102–108. https://doi.org/10.1016/j.molcata.2016.05.013
Hadjiivanov K, Avreyska V, Klissurski D, Marinovai T (2002) Langmuir 18:1619–1625. https://doi.org/10.1021/la0110895
Wei L, Cui SP, Guo H, Ma X, Zhang L (2016) J Mol Catal A 421:102–108. https://doi.org/10.1016/j.molcata.2016.05.013
Funding
Funding was provided by the Young and Middle-aged Science and Technology Talent Development Fund of Shanghai Institute of Technology (No. ZQ2023-9) and National Natural Science Foundation of China (No. U1710252).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Wang, X., Zhou, Y., **, S. et al. The Recycle of Red Mud as NH3-SCR Catalyst by Acid Pretreatment: Insight into the Interaction Between Iron and Titanium Species. Catal Lett 154, 1738–1754 (2024). https://doi.org/10.1007/s10562-023-04402-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-023-04402-2