Abstract
Uniform dispersion of ultrafine spherical silver nanoparticles (NPs) was obtained over the surface of Fe3O4@SiO2@KIT-6 core–shell support via functionalization of the mesoporous KIT-6 shell by aminopropyltriethoxysilane, followed by coordination of Ag+ ions and in situ chemical reduction with sodium borohydride. The obtained hybrid material, Fe3O4@SiO2@KIT-6-Ag nanocomposite, was fully characterized by Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, and used as an efficient catalyst for selective reduction of nitroaromatic compounds in aqueous solution at ambient temperature and neutral pH [nine examples, apparent rate constants at 25 °C, k (min−1), 0.112–0.628]. As a non-aromatic example, nitrofurazone which is a cytotoxic antibiotic was also reduced selectively at nitro group without reduction of other functionalities. Fe3O4@SiO2@KIT-6-Ag NPs also showed potential ability to act as catalyst for reduction of nitromethane in aqueous solution which can provide a colorimetric method for detection of nitromethane in solution down to 0.9 × 10−4 mol L−1. Fe3O4@SiO2@KIT-6-Ag nanocomposite was also screened for its antibacterial activity, and satisfactory results were obtained in comparison with drug references including Tetracycline, Chloramphenicol and Cefotaxime as positive controls, on gram negative Escherichia coli and Pseudomonas aeroginosa. Ease of recycling of the Fe3O4@SiO2@KIT-6-Ag is another benefit of this nanocatalyst. Under the optimized conditions, the recycled catalyst showed 15% loss of efficiency after five successive runs.
Graphical Abstract
![](http://media.springernature.com/lw685/springer-static/image/art%3A10.1007%2Fs10562-018-2611-1/MediaObjects/10562_2018_2611_Figa_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10562-018-2611-1/MediaObjects/10562_2018_2611_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10562-018-2611-1/MediaObjects/10562_2018_2611_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10562-018-2611-1/MediaObjects/10562_2018_2611_Fig3_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10562-018-2611-1/MediaObjects/10562_2018_2611_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10562-018-2611-1/MediaObjects/10562_2018_2611_Fig5_HTML.png)
Similar content being viewed by others
![](https://media.springernature.com/w215h120/springer-static/image/art%3A10.1007%2Fs10876-015-0924-4/MediaObjects/10876_2015_924_Fig1_HTML.gif)
References
Alshehri A-H, Jakubowska M, Młożniak A, Horaczek M, Rudka D, Free C, Carey J-D (2012) ACS Appl Mater Interfaces 4:7007–7010
Chen D, Mei X, Ji G, Lu M, **e J, Lu J, Lee J-Y (2012) Angew Chem Int Ed 51:2409–2413
Banerjee P, Satapathy M, Mukhopahayay A, Das P (2014) Bioresour Bioprocess 1:1–10
Zheng K, Setyawati M-I, Lim T-P, Leong D-T, **e J (2016) ACS Nano 10:7934–7942
Sarina S, Waclawik E-R, Zhu H (2013) Green Chem 15:1814–1833
Fuku K, Hayashi R, Takakura S, Kamegawa T, Mori K, Yamashita H (2013) Angew Chem Int Ed 52:7446–7450
Xu L-Q, Yap B-M, Wang R, Neoh K-G, Kang E-T, Fu G-D (2014) Ind Eng Chem Res 53:3116–3124
Zhong C-J, Maye M-M (2001) Adv Mater 13:1507–1511
Canamares M-V, Garcia-Ramos J-V, Gomez-Varga J-D, Domingo C, Sanchez-Cortes S (2005) Langmuir 21:8546–8553
Redmond P-L, Hallock A-J, Brus L-E (2005) Nano Lett 5:131–135
Patel A-C, Li S, Wang X-C, Zhang W-J, Wei Y (2007) Chem Mater 19:1231–1238
Shin K-S, Choi J-Y, Park C-S, Jang H-J, Kim K (2009) Catal Lett 133:1
Zhang P, Shao C, Zhang Z, Zhang M, Mu J, Guo Z, Liu Y (2011) Nanoscale 3:3357–3363
Ji T, Long C, Mu L, Yuan R, Knoblauch M, Bao F-S, Zhu J (2016) Appl Catal B 182:306–315
Horecha M, Kaul E, Horechyy A, Stamm M (2014) J Mater Chem A 2:7431–7438
Naik B, Prasad V-S, Ghosh N-N (2012) Powder Technol 232:1–6
Khdary N-H, Ghanem M-A (2012) J Mater Chem 22:12032–12038
Tang S-C, Vongehr S, Meng X-K (2010) J Phys Chem C 114:977–982
Liu J-J, Wang J, Zhu Z-M, Li L, Guo X-H, Lincoln S-F, Prudhomme R-K (2014) AIChE J 60:1977–1982
Gupta V-K, Mergu N, Kumawat L-K, Singh A-K (2015) Sens Actuators B 207:216–223
Saravanan R, Thirumal E, Gupta V-K, Narayanan V, Stephen A (2013) J Mol Liq 177:394–401
Yola M-L, Gupta V-K, Eren T, Şen A-E, Atar N (2014) Electrochim Acta 120:204–211
Mittal A, Mittal J, Malviya A, Gupta V-K (2010) J Colloid Interface Sci 344:497–507
Gupta V-K, Jain R, Nayak A, Agarwal S, Shrivastava M (2011) Mater Sci Eng C 31:1062–1067
Saleh T-A, Gupta V-K (2012) J Colloid Interface Sci 371:101–106
Saravanan R, Khan M-M, Gupta V-K, Mosquera E, Gracia F, Narayanan V, Stephen A (2015) RSC Adv 5:34645–34651
Devaraj M, Saravanan R, Deivasigamani R, Gupta V-K, Gracia F, Jayadevan S (2016) J Mol Liq 221:930–941
Saravanan R, Karthikeyan S, Gupta V-K, Sekaran G, Narayanan V, Stephen A (2013) Mater Sci Eng C 33:91–98
Saravanan R, Gupta V-K, Prakash T, Narayanan V, Stephen A (2013) J Mol Liq 178:88–93
Gupta V-K, Saleh T-A (2013) Environ Sci Pollut Res Int 20:2828–2843
Saleh T-A, Gupta V-K (2011) J Colloid Interface Sci 362:337–344
Ahmaruzzaman M, Gupta V-K (2011) Ind Eng Chem 50:13589–13613
Mohammadi N, Khani H, Gupta V-K, Amereh E, Agarwal S (2011) J Colloid Interface Sci 362:457–462
Saleh T-A, Gupta V-K (2012) Sep Purif Technol 89:245–251
Karthikeyan S, Gupta V-K, Boopathy R, Titus A, Sekaran G (2012) J Mol Liq 173:153–163
Saravanan R, Karthikeyan N, Gupta V-K, Thirumal E, Thangadurai P, Narayanan V, Stephen A (2013) Mater Sci Eng C 33:2235–2244
Saravanan R, Khan M-M, Gupta V-K, Mosquera E, Gracia F, Narayanan V, Stephen A (2015) J Colloid Interface Sci 452:126–133
Robati D, Mirza B, Rajabi M, Moradi O, Tyagi I, Agarwal S, Gupta V-K (2016) Chem Eng J 284:687–697
Nekouei F, Nekouei S, Tyagi I, Gupta V-K (2015) J Mol Liq 201:124–133
Saravanan R, Gupta V-K, Mosquera E, Gracia F (2014) J Mol Liq 198:409–412
Gupta V-K, Nayak A, Agarwal S, Tyagi I (2014) J Colloid Interface Sci 417:420–430
Saravanan R, Joicy S, Gupta V-K, Narayanan V, Stephen A (2013) Mater Sci Eng C 33:4725–4731
Saleh T-A, Gupta V-K (2014) Adv Colloid Interface Sci 211:93–101
Crini G (2005) Prog Polym Sci 30:38–70
Gupta V-K, Kumar R, Nayak A, Saleh T-A, Barakat M-A (2013) Adv Colloid Interface Sci 193:24–34
Saravanan R, Sacari E, Gracia F, Khan M-M, Mosquera E, Gupta V-K (2016) J Mol Liq 221:1029–1033
Ghaedi M, Hajjati S, Mahmudi Z, Tyagi I, Agarwal S, Maity A, Gupta V-K (2015) Chem Eng J 268:28–37
Khani H, Rofouei M-K, Arab P, Gupta V-K, Vafaei Z (2010) J Hazard Mater 183:402–409
Gupta V-K, Atar N, Yola M-L, Üstündağ Z, Uzun L (2014) Water Res 48:210–217
Gupta V-K, Mergu N, Kumawat L-K, Singh A-K (2015) Talanta 144:80–89
Rajendran S, Khan M-M, Gracia F, Qin J, Gupta V-K, Arumainathan S (2016) Sci Rep 6:31641
Asfaram A, Ghaedi M, Agarwal S, Tyagi I, Gupta V-K (2015) RSC Adv 5:18438–18450
Lee H-Y, An M (2004) Bull Korean Chem Soc 25:1717–1719
Khorshidi A, Ghorbannezhad B (2017) RSC Adv 7:29938–29943
Zhang W, Sun Y, Zhang L (2016) Ind Eng Chem Res 55:12398–12406
Salama N, Banerjeec B, Roya A-S, Mondala P, Roya S, Bhaumikc A, Islama S-M (2014) Appl Catal A 477:184–194
Zhang H, Duan T, Zhu W, Yao W-T (2015) J Phys Chem C 119:21465–21472
Ji T, Chen L, Schmitz M, Bao F-S, Zhu J (2015) Green Chem 17:2515–2523
Davarpanah J, Kiasat A-R (2013) Catal Commun 41:6–11
Lunhong A, **g J (2013) Bioresour Technol 132:374–377
Baruah B, Gabriel G-J, Akbashev M-J, Booher M-E (2013) Langmuir 29:4225–4234
Kurtan U, Amira M-D, Yıldızb A, Baykal A (2016) Appl Surf Sci 376:16–25
Sojoudi M, Shariati Sh, Khabazipour M (2016) Anal Bioanal Chem Res 3:287–298
Shariati Sh, Khabazipour M, Safa F (2017) J Porous Mater 24:129–139
Paul M-F, Paul H-E, Bender R-C, Kopko F, Harrington C-M, Ells V-R, Buzard J-A (1960) Antibiot Chemother 10:287–302
Federal R (2002) Topical nitrofurans; extralabel animal drug use; order of prohibition. Fed Reg 67:5470–5471
Olive P-L (1978) Chem Biol Interact 20:323–331
Bhanudas N, Subhenjit H, Vadakkethonippurathu S-P, Narendra N-G (2011) Catal Commun 12:1104–1108
Chiu C-Y, Chung P-J, Lao K-U, Liao C-W, Huang M-H (2012) J Phys Chem C 116:23757–23763
Guo F, Ni Y, Ma Y, **ang N, Liu C (2014) New J Chem 38:5324–5330
Yang M-Q, Pan X, Zhang N, Xu Y-J (2013) CrystEngComm 15:6819–6828
Acknowledgements
Partial support of this study by research council of university of Guilan is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Ansari, S., Khorshidi, A. & Shariati, S. Synthesis of Ultrafine Silver Nanoparticles on the Surface of Fe3O4@SiO2@KIT-6-NH2 Nanocomposite and Their Application as a Highly Efficient and Reusable Catalyst for Reduction of Nitrofurazone and Aromatic Nitro Compounds Under Mild Conditions. Catal Lett 149, 410–418 (2019). https://doi.org/10.1007/s10562-018-2611-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-018-2611-1