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Synthesis of biohybrid magnetic chitosan-polyvinyl alcohol/MgO nanocomposite blend for remazol brilliant blue R dye adsorption: solo and collective parametric optimization

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Abstract

In this work, a new quadruple nanocomposite of chitosan/polyvinyl alcohol/magnesium oxide/Fe3O4 (Chit-PVA/MgO/Fe3O4) was prepared for the adsorption of remazol brilliant blue R (RBBR) dye in batch process. Several advanced analytical techniques including BET, XRD, FTIR, SEM–EDX, potentiometric titrations, and pHpzc were performed for characterizing of the synthesized nanocomposite (Chit-PVA/MgO/Fe3O4). A multi-step experimental design was derived from response surface methodology (RSM) for optimizing the factors affecting RBBR dye adsorption, namely A: dose (0.02–0.1 g), B: pH (4–10), C: temperature (30–60 °C), and time D: (10–60 min). The obtained kinetic data and adsorption isotherm for the studied Chit-PVA/MgO/Fe3O4-RBBR system followed pseudo-second-order and Langmuir isotherm model, respectively. The maximum adsorption capacity of Chit-PVA/MgO/Fe3O4 toward RBBR was found to be 163.7 mg/g. The adsorption mechanism of RBBR dye by Chit-PVA/MgO/Fe3O4 possibly comprises an electrostatic interaction, hydrogen bonding, n-π interactions, and Yoshida H-bonding. This work reveals that Chit-PVA/MgO/Fe3O4 nanocomposite is an efficient and recoverable biohybrid adsorbent with a great ability to remove organic dye from an aqueous environment.

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Acknowledgements

The authors would like to acknowledge Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, for facilitating this research work. The authors would like to thank the Research Management Center (RMC), Universiti Teknologi MARA (UiTM) for supporting this research by Strategic Research Partnership (SRP) grant (100-RMC 5/3/SRP (052/2021)).

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Authors and Affiliations

  1. Faculty of Applied Sciences, Universiti Teknologi MARA, 40450, Shah Alam, Selangor, Malaysia

    Ali H. Jawad

  2. Department of Chemical Engineering, College of Engineering, Qatar University, P.O. Box: 2713, Doha, Qatar

    B. H. Hameed

  3. Department of Medical Instrumentation Engineering, Al-Mansour University College, Baghdad, Iraq

    Ahmed Saud Abdulhameed

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  1. Ali H. Jawad
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  3. Ahmed Saud Abdulhameed
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Correspondence to Ali H. Jawad.

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Jawad, A.H., Hameed, B.H. & Abdulhameed, A.S. Synthesis of biohybrid magnetic chitosan-polyvinyl alcohol/MgO nanocomposite blend for remazol brilliant blue R dye adsorption: solo and collective parametric optimization. Polym. Bull. 80, 4927–4947 (2023). https://doi.org/10.1007/s00289-022-04294-z

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