Abstract
With the acceleration of economic development and urbanization, air pollution is becoming increasingly severe in China. The results of a study in 2009 showed that nearly 30% of China’s land area and 500 million people were suffering from haze, especially in the Pan Bohai Sea, the Yangtze River Delta, and the Pearl River Delta. Since the 1970s, China has gradually carried out special research on the acid rain and photochemical smog, revealing that the root cause of these two types of pollution was the regional secondary pollution driven by the atmospheric oxidation. The monitoring results showed that the atmospheric concentration of nitrogen oxides (NOx), sulfur dioxide (SO2), and PM10 had been decreasing to varying degrees; however, the increase of ozone (O3) concentration and the occurrence of haze had not been effectively suppressed. The main driving force behind the conversion of the primary pollutants into the secondary pollutants is the hydroxyl (OH) radical. However, there is a lack of research on the chemical mechanism of the OH radical in complex air pollution currently, which limits our understanding of the causes of secondary pollution.
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Notes
- 1.
One part per trillion (1 ppt) is equal to 1 × 10−12.
- 2.
One part per billion (1 ppb) is equal to 1 × 10−9.
References
Aiken AC, Decarlo PF, Kroll JH et al (2008) O/C and OM/OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry. Environ Sci Technol 42(12):4478–4485
Allan JD, Williams PI, Morgan WT et al (2010) Contributions from transport, solid fuel burning and cooking to primary organic aerosols in two UK cities. Atmos Chem Phys 10(2):647–668
Alves NDO, Brito J, Caumo S et al (2015) Biomass burning in the Amazon region: aerosol source apportionment and associated health risk assessment. Atmos Environ 120:277–285
Andreae MO, Merlet P (2001) Emission of trace gases and aerosols from biomass burning. Global Biogeochem Cy 15(4):955–966
Asman WAH (1998) Factors influencing local dry deposition of gases with special reference to ammonia. Atmos Environ 32(3):415–421
Betha R, Spracklen DV, Balasubramanian R (2013) Observations of new aerosol particle formation in a tropical urban atmosphere. Atmos Environ 71:340–351
Bloss C, Wagner V, Jenkin ME et al (2005) Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons. Atmos Chem Phys 5:641–664
Bouwman AF, Lee DS, Asman WAH et al (1997) A global high-resolution emission inventory for ammonia. Global Biogeochem Cy 11(4):561–587
Breitner S, Liu L, Cyrys J et al (2011) Sub-micrometer particulate air pollution and cardiovascular mortality in Bei**g, China. Sci Total Environ 409:5196–5204
Bruns EA, El Haddad I, Slowik JG et al (2016) Identification of significant precursor gases of secondary organic aerosols from residential wood combustion. Sci Rep 6:27881
Burgard DA, Bishop GA, Stedman DH (2006) Remote sensing of ammonia and sulfur dioxide from on-road light duty vehicles. Environ Sci Technol 40(22):7018–7022
Calvert JG, Su F, Bottenheim JW et al (1978) Mechanism of the homogeneous oxidation of sulfur dioxide in the troposphere. Atmos Environ 12(1–3):197–226
Cao G, Jang M (2007) Effects of particle acidity and UV light on secondary organic aerosol formation from oxidation of aromatics in the absence of NOx. Atmos Environ 41(35):7603–7613
Cao GL, Zhang XY, Gong SL et al (2008) Investigation on emission factors of particulate matter and gaseous pollutants from crop residue burning. J Environ Sci 20(1):50–55
Cao GL, Zhang XY, Wang D et al (2005) Inventory of atmospheric pollutants discharged from biomass burning in China continent. China Environ Sci 25(4):389–393
Chan CK, Yao X (2008) Air pollution in mega cities in China. Atmos Environ 42(1):1–42
Chen J, Li C, Ristovski Z et al (2017) A review of biomass burning: emissions and impacts on air quality, health and climate in China. Sci Total Environ 579:1000–1034
Cheng S, Lang J, Zhou Y et al (2013) A new monitoring-simulation-source apportionment approach for investigating the vehicular emission contribution to the PM2.5 pollution in Bei**g. China Atmos Environ 79:308–316
Chirico R, DeCarlo PF, Heringa MF et al (2010) Impact of aftertreatment deviceson primary emissions and secondary organic aerosol formation potential from in use diesel vehicles: Results from smog chamber experiments. Atmos Chem Phys 10(23):11545–11563
Chow JC, Watson JG, Fujita EM, et al (1994) Temporal and spatial variations of PM2.5 and PM10 aerosol in the Southern California air quality study. Atmos Environ 28(12):2061–2080
Christian TJ, Kleiss B, Yokelson RJ, et al (2003). Comprehensive laboratory measurements of biomass-burning emissions: 1. Emissions from Indonesian, African, and other fuels. J Geophys Res-Atmos 108(D23):4719
Crilley LR, Jayaratne ER, Ayoko GA et al (2014) Observations on the formation, growth and chemical composition of aerosols in an urban environment. Environ Sci Technol 48(12):6588–6596
Crippa M, El Haddad I, Slowik JG et al (2013) Identification of marine and continental aerosol sources in Paris using high resolution aerosol mass spectrometry. J Geophys Res-Atmos 118(4):1950–1963
Cross ES, Sappok AG, Wong VW et al (2015) Load-dependent emission factors and chemical characteristics of IVOCs from a medium-duty diesel engine. Environ Sci Technol 49(22):13483–13491
Crounse JD, Knap HC, Ørnsø KB, et al (2012). Atmospheric fate of methacrolein. 1. Peroxy radical isomerization following addition of OH and O2. J Phys Chem A 116(24):5756–5762
Crounse JD, Nielsen LB, Jørgensen S et al (2013) Autoxidation of organic compounds in the atmosphere. J Phys Chem Lett 4(20):3513–3520
Crounse JD, Paulot F, Kjaergaard HG et al (2011) Peroxy radical isomerization in the oxidation of isoprene. Phys Chem Chem Phys 13(30):13607–13613
Daly HM, Horn AB (2009) Heterogeneous chemistry of toluene, kerosene and diesel soots. Phys Chem Chem Phys 11(7):1069–1076
Deng W, Hu Q, Liu T et al (2017) Primary particulate emissions and secondary organic aerosol (SOA) formation from idling diesel vehicle exhaust in China. Sci Total Enrivon 593–594(1):462–469
Du Q, Zhang C, Mu Y et al (2016) An important missing source of atmospheric carbonyl sulfide: domestic coal combustion. Geophys Res Lett 43(16):8720–8727
Dupart Y, King SM, Nekat B et al (2012) Mineral dust photochemistry induces nucleation events in the presence of SO2. Proc Natl Acad Sci USA 109(51):20842–20847
Edney EO, Kleindienst TE, Jaoui M, et al (2005). Formation of 2-methyl tetrols and 2-methylglyceric acid in secondary organic aerosol from laboratory irradiated isoprene/NOx/SO2/air mixtures and their detection in ambient PM2.5 samples collected in the eastern United States. Atmos Environ 39(29):5281–5289
Fenske JD, Hasson AS, Ho AW et al (2000) Measurement of absolute unimolecular and bimolecular rate constants for CH3CHOO generated by the trans-2-butene reaction with ozone in the gas phase. J Phys Chem A 104(44):9921–9932
Fraser MP, Cass GR (1998) Detection of excess ammonia emissions from in-use vehicles and the implications for fine particle control. Environ Sci Technol 32(8):1053–1057
Fuchs H, Acir IH, Bohn B et al (2014) OH regeneration from methacrolein oxidation investigated in the atmosphere simulation chamber SAPHIR. Atmos Chem Phys 14(4):7895–7908
Fuchs H, Hofzumahaus A, Rohrer F et al (2013) Experimental evidence for efficient hydroxyl radical regeneration in isoprene oxidation. Nat Geosci 6(12):1023–1026
Gentner DR, Isaacman G, Worton DR et al (2012) Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of organic carbon emissions. Proc Natl Acad Sci USA 109(45):18318–18323
Gordon TD, Presto AA, May AA, et al (2014a) Secondary organic aerosol formation exceeds primary particulate matter emissions for light-duty gasoline vehicles. Atmos Chem Phys 14(9):4661–4678
Gordon TD, Presto AA, Nguyen NT, et al (2014b) Secondary organic aerosol production from diesel vehicle exhaust: impact of aftertreatment, fuel chemistry and driving cycle. Atmos Chem Phys 14(9):4643–4659
Han C, Liu Y, He H (2013) Role of organic carbon in heterogeneous reaction of NO2 with soot. Environ Sci Technol 47(7):3174–3181
Han C, Liu Y, Ma J et al (2012) Key role of organic carbon in the sunlightenhanced atmospheric aging of soot by O2. Proc Natl Acad Sci USA 109(52):21250–21255
Hayes PL, Carlton AG, Baker KR et al (2015) Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010. Atmos Chem Phys 15(10):5773–5801
He H, Wang Y, Ma Q et al (2014) Mineral dust and NO2 promote the conversion of SO2 to sulfate in heavy pollution days. Sci Rep 4:4172
He KB, Yang FM, Ma YL, et al (2001) The characteristics of PM2.5 in Bei**g, China. Atmos Environ 35(29):4959–4970
Heard DE, Carpenter LJ, Creasey DJ et al (2004) High levels of the hydroxyl radical in the winter urban troposphere. Geophys Res Lett 31(18):L18112
Hens K, Novelli A, Martinez M et al (2014) Observation and modelling of HOx radicals in a boreal forest. Atmos Chem Phys 14:8723–8747
Hofzumahaus A, Rohrer F, Lu K et al (2009) Amplified trace gas removal in the troposphere. Science 324(5935):1702–1704
Hosseini S, Urbanski SP, Dixit P et al (2013) Laboratory characterization of PM emissions from combustion of wildland biomass fuels. J Geophys Res-Atmos 118(17):9914–9929
Huang X, Song Y, Li MM, et al (2012a) A high-resolution ammonia emission inventory in China. Global Biogeochem Cy 26:GB1030
Huang XF, He LY, Hu M et al (2011) Characterization of submicron aerosols at a rural site in Pearl River Delta of China using an aerodyne high-resolution aerosol mass spectrometer. Atmos Chem Phys 11:1865–1877
Huang Y, Lee SC, Ho KF, et al (2012b) Effect of ammonia on ozone-initiated formation of indoor secondary products with emissions from cleaning products. Atmos Environ 59:224–231
Ianniello A, Spataro F, Esposito G et al (2011) Chemical characteristics of inorganic ammonium salts in PM2.5 in the atmosphere of Bei**g (China). Atmos Chem Phys 11:10803–10822
Jang MS, Czoschke NM, Lee S et al (2002) Heterogeneous atmospheric aerosol production by acid-catalyzed particle-phase reactions. Science 298(5594):814–817
Jaoui M, Edney EO, Kleindienst TE, et al (2008) Formation of secondary organic aerosol from irradiated alpha-pinene/toluene/NOx mixtures and the effect of isoprene and sulfur dioxide. J Geophys Res-Atmos 113(D9)
Jimenez JL, Canagaratna MR, Donahue NM et al (2009) Evolution of organic aerosols in the atmosphere. Science 326(5959):1525–1529
Jokinen T, Sipilä M, Richters S et al (2014) Rapid autoxidation forms highly oxidized RO2 radicals in the atmosphere. Angew Chem Int Edit 53(52):14596–14600
Kamm S, Möhler O, Naumann KH et al (1999) The heterogeneous reaction of ozone with soot aerosol. Atmos Environ 33(28):4651–4661
Kean AJ, Littlejohn D, Ban-Weiss GA et al (2009) Trends in on-road vehicle emissions of ammonia. Atmos Environ 43(8):1565–1570
Kim Oanh NT, Tipayarom A, Bich TL et al (2015) Characterization of gaseous and semi-volatile organic compounds emitted from field burning of rice straw. Atmos Environ 119:182–191
Kirkby J, Curtius J, Almeida J et al (2011) Role of sulphuric acid, ammonia and galactic cosmic rays in atmospheric aerosol nucleation. Nature 476:429–433
Klein F, Farren N, Bozzetti C et al (2016) Indoor terpene emissions from cooking with herbs and pepper and their secondary organic aerosol production potential. Sci Rep 6:36623
Kleindienst TE, Edney EO, Lewandowski M et al (2006) Secondary organic carbon and aerosol yields from the irradiations of isoprene and α-pinene in the presence of NOx and SO2. Environ Sci Technol 40(12):3807–3812
Kolb CE, Cox RA, Abbatt JPD et al (2010) An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds. Atmos Chem Phys 10(21):10561–10605
Kroll JH, Chan AWH, Ng NL et al (2007) Reactions of semivolatile organics and their effects on secondary organic aerosol formation. Environ Sci Technol 41(10):3545–3550
Kroll JH, Donahue NM, Jimenez JL et al (2011) Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol. Nat Chem 3:133–139
Kulmala M, Kontkanen J, Junninen H et al (2013) Direct observations of atmospheric aerosol nucleation. Science 339(6122):943–946
Lee BP, Li YJ, Yu JZ et al (2015) Characteristics of submicron particulate matter at the urban roadside in downtown Hong Kong—overview of 4 months of continuous high-resolution aerosol mass spectrometer measurements. J Geophys Res-Atmos 120(14):7040–7058
Leitte AM, Schlink U, Herbarth O, et al (2011). Size-segregated particle number concentrations and respiratory emergency room visits in Bei**g, China. Environ Health Perspect 119(4):508–513
Lelieveld J, Heintzenberg J (1992) Sulfate cooling effect on climate through incloud oxidation of anthropogenic SO2. Science 258(5079):117–120
Lelièvre S, Bedjanian Y, Pouvesle N et al (2004) Heterogeneous reaction of ozone with hydrocarbon flame soot. Phys Chem Chem Phys 6(6):1181–1191
Li C, Hu Y, Zhang F et al (2017) Multi-pollutant emissions from the burning of major agricultural residues in China and the related health-economic effects. Atmos Chem Phys 17:4957–4988
Li X, Wang S, Duan L et al (2007) Particulate and trace gas emissions from open burning of wheat straw and corn stover in China. Environ Sci Technol 41(17):6052–6058
Li X, Wang S, Duan L et al (2009) Characterization of non-methane hydrocarbons emitted from open burning of wheat straw and corn stover in China. Environ Res Lett 4(4):044015
Lisovskii A, Semiat R, Aharoni C (1997) Adsorption of sulfur dioxide by active carbon treated by nitric acid: I. Effect of the treatment on adsorption of SO2 and extractability of the acid formed. Carbon 35(10–11):1639–1643
Liu Q, Li C, Li Y (2003) SO2 removal from flue gas by activated semi-cokes: 1. The preparation of catalysts and determination of operating conditions. Carbon 41(12):2217–2223
Liu T, Wang X, Hu Q et al (2016) Formation of secondary aerosols from gasoline vehicle exhaust when mixing with SO2. Atmos Chem Phys 16(2):675–689
Liu T, Wang X, Wang B et al (2014) Emission factor of ammonia (NH3) from on-road vehicles in China: tunnel tests in urban Guangzhou. Environ Res Lett 9(6):064027
Liu Y, Liu C, Ma J et al (2010) Structural and hygroscopic changes of soot during heterogeneous reaction with O3. Phys Chem Chem Phys 12(36):10896–10903
Liu Y, Shao M (2007) Estimation and prediction of black carbon emissions in Bei**g City. Chinese Sci Bull 52(9):1274–1281
Lizzio AA, DeBarr JA (1997) Mechanism of SO2 removal by carbon. Energy Fuels 11(2):284–291
Lockhart J, Blitz M, Heard D et al (2013) Kinetic study of the OH+glyoxal reaction: experimental evidence and quantification of direct OH recycling. J Phys Chem A 117(43):11027–11037
Longfellow CA, Ravishankara AR, Hanson DR (2000) Reactive and nonreactive uptake on hydrocarbon soot: HNO3, O3, and N2O5. J Geophys Res-Atmos 105(D19):24345–24350
Lu KD, Hofzumahaus A, Holland F et al (2013) Missing OH source in a suburban environment near Bei**g: observed and modelled OH and HO2 concentrations in summer 2006. Atmos Chem Phys 13(2):1057–1080
Lu KD, Rohrer F, Holland F et al (2012) Observation and modelling of OH and HO2 concentrations in the Pearl River Delta 2006: A missing OH source in a VOC rich atmosphere. Atmos Chem Phys 12(3):1541–1569
McCabe J, Abbatt JPD (2009) Heterogeneous loss of gas-phase ozone on n-hexane soot surfaces: similar kinetics to loss on other chemically unsaturated solid surfaces. J Phys Chem C 113(6):2120–2127
Meng ZY, Lin WL, Jiang XM, et al (2011) Characteristics of atmospheric ammonia over Bei**g, China. Atmos Chem Phys 11(12):6139–6151
Metts T, Batterman S, Fernandes G et al (2005) Ozone removal by diesel particulate matter. Atmos Environ 39(18):3343–3354
Mohr C, DeCarlo PF, Heringa MF et al (2012) Identification and quantification of organic aerosol from cooking and other sources in Barcelona using aerosol mass spectrometer data. Atmos Chem Phys 12(4):1649–1665
Müller JO, Su DS, Jentoft RE et al (2005) Morphology-controlled reactivity of carbonaceous materials towards oxidation. Catal Today 102–103:259–265
Müller JO, Su DS, Wild U et al (2007) Bulk and surface structural investigations of diesel engine soot and carbon black. Phys Chem Chem Phys 9(30):4018–4025
Na K, Song C, Switzer C et al (2007) Effect of ammonia on secondary organic aerosol formation from α-pinene ozonolysis in dry and humid conditions. Environ Sci Technol 41(17):6096–6102
Nakao S, Shrivastava M, Nguyen A et al (2011) Interpretation of secondary organic aerosol formation from diesel exhaust photooxidation in an environmental chamber. Aerosol Sci Technol 45(8):964–972
Nehr S, Bohn B, Fuchs H et al (2011) HO2 formation from the OH plus benzene reaction in the presence of O2. Phys Chem Chem Phys 13(22):10699–10708
Nehr S, Bohn B, Wahner A (2012) Prompt HO2 formation following the reaction of OH with aromatic compounds under atmospheric conditions. J Phys Chem A 116(24):6015–6026
Nehr S, Bohn B, Dorn HP et al (2014) Atmospheric photochemistry of aromatic hydrocarbons: OH budgets during SAPHIR chamber experiments. Atmos Chem Phys 14(13):6941–6952
Nguyen TL, Vereecken L, Peeters J (2010) HOx regeneration in the oxidation of isoprene III: Theoretical study of the key isomerisation of the Z-δ-hydroxyperoxy isoprene radicals. Chem Phys Chem 11:3996–4001
Ni H, Han Y, Cao J et al (2015) Emission characteristics of carbonaceous particles and trace gases from open burning of crop residues in China. Atmos Environ 123:399–406
Nordin E, Eriksson A, Roldin P et al (2013) Secondary organic aerosol formation from gasoline passenger vehicle emissions investigated in a smog chamber. Atmos Chem Phys 13(12):6101–6116
Odum JR, Jungkamp TPW, Griffin RJ, et al (1997a) The atmospheric aerosol-forming potential of whole gasoline vapor. Science 276(5309):96–99
Odum JR, Jungkamp TPW, Griffin RJ, et al (1997b) Aromatics, reformulated gasoline, and atmospheric organic aerosol formation. Environ Sci Technol 31(7):1890–1897
Ortega IK, Kurten T, Vehkamaki H et al (2008) The role of ammonia in sulfuric acid ion induced nucleation. Atmos Chem Phys 8(11):2859–2867
Ou XM, Zhang XL, Chang SY (2010) Scenario analysis on alternative fuel/vehicle for China’s future road transport: life-cycle energy demand and GHG emissions. Energy Policy 38(8):3943–3956
Peeters J, Nguyen TL, Vereecken L (2009) HOx radical regeneration in the oxidation of isoprene. Phys Chem Chem Phys 11(28):5935–5939
Pinder RW, Adams PJ, Pandis SN (2007) Ammonia emission controls as a costeffective strategy for reducing atmospheric particulate matter in the eastern United States. Environ Sci Technol 41(2):380–386
Pirjola L, Dittrich A, Niemi JV et al (2016) Physical and chemical characterization of real-world particle number and mass emissions from city buses in Finland. Environ Sci Technol 50:294–304
Platt SM, El Haddad I, Zardini AA et al (2013) Secondary organic aerosol formation from gasoline vehicle emissions in a new mobile environmental reaction chamber. Atmos Chem Phys 13(18):9141–9158
Praske E, Crounse JD, Bates KH et al (2015) Atmospheric fate of methyl vinyl ketone: Peroxy radical reactions with NO and HO2. J Phys Chem A 119(19):4562–4572
Presto AA, Miracolo MA, Kroll JH et al (2009) Intermediate-volatility organic compounds: a potential source of ambient oxidized organic aerosol. Environ Sci Technol 43(13):4744–4749
Robinson AL, Donahue NM, Shrivastava MK et al (2007) Rethinking organic aerosols: semivolatile emissions and photochemical aging. Science 315(5816):1259–1262
Rogaski CA, Golden DM, Williams LR (1997) Reactive uptake and hydration experiments on amorphous carbon treated with NO2, SO2, O3, HNO3, and H2SO4. Geophys Res Lett 24(4):381–384
Rohrer F, Lu KD, Hofzumahaus A et al (2014) Maximum efficiency in the hydroxyl-radical-based self-cleansing of the troposphere. Nat Geosci 7:559–563
Rubio B, Izquierdo MT (1998) Low cost adsorbents for low temperature cleaning of flue gases. Fuel 77(6):631–637
Sanchis E, Ferrer M, Calvet S et al (2014) Gaseous and particulate emission profiles during controlled rice straw burning. Atmos Environ 98:25–31
Schauer JJ, Fraser MP, Cass GR et al (2002) Source reconciliation of atmospheric gas-phase and particle has epollutants during a severe photochemical smog episode. Environ Sci Technol 36(17):3806–3814
Shah SD, Cocker DR, Miller JW et al (2004) Emission rates of particulate matter and elemental and organic carbon from in-use diesel engines. Environ Sci Technol 38(9):2544–2550
Shilling JE, Chen Q, King SM et al (2009) Loading-dependent elemental composition of α-pinene SOA particles. Atmos Chem Phys 9(3):771–782
Sipila M, Berndt T, Petaja T et al (2010) The role of sulfuric acid in atmospheric nucleation. Science 327(5970):1243–1246
Song C, Na K, Warren B et al (2007) Secondary organic aerosol formation from the photooxidation of p- and o-xylene. Environ Sci Technol 41(21):7403–7408
Stockwell CE, Veres PR, Williams J et al (2015) Characterization of biomass burning emissions from cooking fires, peat, crop residue, and other fuels with high-resolution proton-transfer-reaction time-of-flight mass spectrometry. Atmos Chem Phys 15(2):845–865
Streets DG, Yarber KF, Woo JH et al (2003) Biomass burning in Asia: annual and seasonal estimates and atmospheric emissions. Global Biogeochem Cy 17(4):1099
Sun T, Wang Y, Zhang C et al (2011) The chemical mechanism of the limonene ozonolysis reaction in the SOA formation: a quantum chemistry and direct dynamic study. Atmos Environ 45(9):1725–1731
Sun Y, Wang Z, Fu P, et al (2013) Aerosol composition, sources and processes during wintertime in Bei**g, China. Atmos Chem Phys 13(9):4577–4592
Tan Z, Lu K, Jiang M et al (2018) Exploring ozone pollution in Chengdu, southwestern China: a case study from radical chemistry to O3-VOC-NOx sensitivity. Sci Total Environ 636:775–786
Tian H, Dan Z (2011) Emission inventories of atmospheric pollutants discharged from biomass burning in China. Acta Sci Circum 31(2):349–357
Tkacik DS, Lambe AT, Jathar S et al (2014) Secondary organic aerosol formation from in-use motor vehicle emissions using a potential aerosol mass reactor. Environ Sci Technol 48(19):11235–11242
Tsang SC, Chen YK, Harris PJ et al (1994) A simple chemical method of opening and filling carbon nanotubes. Nature 372:159–162
Vander Wal RL, Tomasek AJ, Pamphlet MI et al (2004) Analysis of HRTEM images for carbon nanostructure quantification. J Nanopart Res 6(6):555–568
Vander Wal RL, Tomasek AJ (2003) Soot oxidation: Dependence upon initial nanostructure. Combust Flame 134(1–2):1–9
Wang HL, Lou SR, Huang C, et al (2014) Source profiles of volatile organic compounds from biomass burning in Yangtze River Delta, China. Aerosol Air Qual Res 14(3):818–828
Wang X, Ding X, Fu X, et al (2012) Aerosol scattering coefficients and major chemical compositions of fine particles observed at a rural site in the central Pearl River Delta, South China. J Environ Sci 24(1):72–77
Weitkamp EA, Sage AM, Pierce JR et al (2007) Organic aerosol formation from photochemical oxidation of diesel exhaust in a smog chamber. Environ Sci Technol 41(20):6969–6975
Welz O, Savee JD, Osborn DL et al (2012) Direct kinetic measurements of criegee intermediate (CH2OO) formed by reaction of CH2I with O2. Science 335(6065):204–207
Wu RR, Wang SN, Wang LM (2015) New mechanism for the atmospheric oxidation of dimethyl sulfide: the importance of intramolecular hydrogen shift in a CH3SCH2OO radical. J Phys Chem A 119(1):112–117
**ao R, Takegawa N, Kondo Y et al (2009) Formation of submicron sulfate and organic aerosols in the outflow from the urban region of the Pearl River Delta in China. Atmos Environ 43(24):3754–3763
Yang F, Tan J, Zhao Q, et al (2011) Characteristics of PM2.5 speciation in representative megacities and across China. Atmos Chem Phys 11(11):5207–5219
Yang W, He H, Ma Q et al (2016) Synergistic formation of sulfate and ammonium resulting from reaction between SO2 and NH3 on typical mineral dust. Phys Chem Chem Phys 18(2):956–964
Ye PL, Ding X, Hakala J et al (2016) Vapor wall loss of semi-volatile organic compounds in a Teflon chamber. Aerosol Sci Technol 50(8):822–834
Yu L, Wang G, Zhang R, et al (2013) Characterization and source apportionment of PM2.5 in an urban environment in Bei**g. Aerosol Air Qual Res 13(2):574–583
Zawadzki J (1978) IR spectroscopy studies of oxygen surface compounds on carbon. Carbon 16(6):491–497
Zawadzki J (1987a) Infrared studies of SO2 on carbons—I. Interaction of SO2 with carbon films. Carbon 25(3):431–436
Zawadzki J (1987b) Infrared studies of SO2 on carbons—II. the SO2 species adsorbed on carbon films. Carbon 25(4):495–502
Zelenay V, Monge ME, D’Anna B, et al (2011) Increased steady state uptake of ozone on soot due to UV/Vis radiation. J Geophys Res-Atmos 116(D11)
Zhang P, Wanko H, Ulrich J (2007) Adsorption of SO2 on activated carbon for low gas concentrations. Chem Eng Technol 30(5):635–641
Zhang Q, He K, Huo H (2012) Policy: cleaning China’s air. Nature 484:161–162
Zhang Q, Stanier CO, Canagaratna MR et al (2004) Insights into the chemistry of new particle formation and growth events in Pittsburgh based on aerosol mass spectrometry. Environ Sci Technol 38(18):4797–4809
Zhang X, Schwantes RH, McVay RC et al (2015) Vapor wall deposition in Teflon chambers. Atmos Chem Phys 15(8):4197–4214
Zhang Y, Dou H, Chang B et al (2008) Emission of polycyclic aromatic hydrocarbons from indoor straw burning and emission inventory updating in China. Ann NY Acad Sci 1140(1):218–227
Zhang Y, Wang X, Wen S et al (2016) On-road vehicle emissions of glyoxal and methylglyoxal from tunnel tests in urban Guangzhou, China. Atmos Environ 127:55–60
Zhang YM, Zhang XY, Sun JY, et al (2011) Characterization of new particle and secondary aerosol formation during summertime in Bei**g, China. Tellus B 63(3):382–394
Zhao X, Wang X, Ding X, et al (2014) Compositions and sources of organic acids in fine particles (PM2.5) over the Pearl River Delta region, south China. J Environ Sci 26(1):110–121
Zhao Y, Liu Y, Ma J et al (2017) Heterogeneous reaction of SO2 with soot: the roles of relative humidity and surface properties of soot in surface sulfate formation. Atmos Environ 152:465–476
Zhao Y, Nguyen NT, Presto AA et al (2015) Intermediate volatility organic compound emissions from on-road diesel vehicles: chemical composition, emission factors, and estimated secondary organic aerosol production. Environ Sci Technol 49(19):11516–11526
Zheng X, Wu Y, Jiang J et al (2015) Characteristics of on-road diesel vehicles: black carbon emissions in Chinese cities based on portable emissions measurement. Environ Sci Technol 49(22):13492–13500
Zhu YJ, Sabaliauskas K, Liu XH et al (2014) Comparative analysis of new particle formation events in less and severely polluted urban atmosphere. Atmos Environ 98:655–664
Zotter P, El-Haddad I, Zhang Y et al (2014) Diurnal cycle of fossil and nonfossil carbon using radiocarbon analyses during CalNex. J Geophys Res-Atmos 119(11):6818–6835
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He, H., Wang, X., Wang, Y., Wang, Z., Liu, J., Chen, Y. (2023). Atmospheric Oxidation and Secondary Particle Formation. In: He, H., Wang, X., Wang, Y., Wang, Z., Liu, J., Chen, Y. (eds) Formation Mechanism and Control Strategies of Haze in China. Advanced Topics in Science and Technology in China, vol 66. Springer, Singapore. https://doi.org/10.1007/978-981-19-6956-0_2
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