Abstract
The invention of quantum cascade laser (QCL) technology rejuvenates the spectroscopic monitoring of trace gas species providing an unprecedented access to the ‘molecular fingerprint region’ covering mid-infrared (mid-IR) spectral range of 3–25 μm. The recent technological advancements of QCL fulfil all the critical parameters as an ideal optical source of a portable and field-deployable mid-IR spectrometer for trace gas analysis in real time. Hence, QCL-based spectroscopic techniques have now widely been employed in various fields covering molecular spectroscopy, atmospheric and environmental trace gas sensing, medical diagnostics, chemical and explosive analysis, industrial process control, and many more. In this chapter, we first discuss various critical features of an optical source for trace gas sensing applications with subsequent brief mention of different mid-IR sources prior to the QCL. Thereafter, the importance of trace gas analysis in environmental and biomedical sciences has been presented in short, followed by a historic overview of QCL. Finally, we focus on the applications of QCL-based spectroscopic techniques in the field of atmospheric and biomedical sciences.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
I.E. Gordon, L.S. Rothman, C. Hill, R.V. Kochanov, Y. Tan, P.F. Bernath, M. Birk, V. Boudon, A. Campargue, K.V. Chance et al., J. Quant. Spectrosc. Radiat. Transf. 203, 3–69 (2017)
A. Kosterev, G. Wysocki, Y. Bakhirkin, S. So, R. Lewicki, M. Fraser, F. Tittel, R.F. Curl, Appl. Phys. B 90(2), 165–176 (2008)
F.K. Tittel, D. Richter, A. Fried, Mid-infrared laser applications in spectroscopy, in Solid-State Mid-Infrared Laser Sources, ed. by I.T. Sorokina, K.L. Vodopyanov (Springer, Berlin, 2003), pp. 458–529
S. Welzel, New Enhanced Sensitivity Infrared Laser Spectroscopy Techniques Applied to Reactive Plasmas and Trace Gas Detection (Logos Verlag Berlin GmbH, 2009)
S. Welzel, R. Engeln, J. Röpcke, Quantum cascade laser based chemical sensing using optically resonant cavities, in Cavity-Enhanced Spectroscopy and Sensing, ed. by G. Gagliardi, H.P. Loock (Springer, Berlin, 2014), pp. 93–142
J. Faist, F. Capasso, D.L. Sivco, C. Sirtori, A.L. Hutchinson, A.Y. Cho, Science 264(5158), 553–556 (1994)
R.P. Wayne, Chemistry of Atmospheres, 3rd edn. (Oxford University Press, 2000)
R. Goody, Principles of Atmospheric Chemistry and Physics (Oxford University Press, 1995)
G.P. Brasseur, J.J. Orlando, G.S. Tyndall, Atmospheric Chemistry and Global Change (Oxford University Press, 1999)
R.E. Hester, R.M. Harrison (eds.), Volatile Organic Compounds in the Atmosphere, no. 4 (Royal Society of Chemistry, 1995)
M.Z. Jacobson, Atmospheric Pollution: History, Science, and Regulation (Cambridge University Press, 2002)
R. Atkinson, Atmos. Environ. 34(12–14), 2063–2101 (2000)
T. Mathew, P. Pownraj, S. Abdulla, B. Pullithadathil, Diagnostics 5(1), 27–60 (2015)
C. Wang, P. Sahay, Sensors 9(10), 8230–8262 (2009)
A.S. Modak, J. Breath Res. 1(1), 014003 (2007)
T.H. Risby, F.K. Tittel, Opt. Eng. 49(11), 111123 (2010)
A. Amann, W. Miekisch, J. Schubert, B. Buszewski, T. Ligor, T. Jezierski, J. Pleil, T. Risby, Ann. Rev. Anal. Chem. 7, 455–482 (2014)
J. Faist, C. Sirtori, F. Capasso, L. Pfeiffer, K.W. West, Appl. Phys. Lett. 64(7), 872–874 (1994)
L. Esaki, R. Tsu, IBM J. Res. Dev. 14(1), 61–65 (1970)
R. Kazarinov, R.A. Suris, Sov. Phys.-Semicond. 5(4), 707–709 (1971)
N. Bandyopadhyay, S. Slivken, Y. Bai, M. Razeghi, Appl. Phys. Lett. 100(21), 212104 (2012)
R. Colombelli, F. Capasso, C. Gmachl, A.L. Hutchinson, D.L. Sivco, A. Tredicucci, M.C. Wanke, A.M. Sergent, A.Y. Cho, Appl. Phys. Lett. 78(18), 2620–2622 (2001)
Y. Bai, S.R. Darvish, S. Slivken, W. Zhang, A. Evans, J. Nguyen, M. Razeghi, Appl. Phys. Lett. 92(10), 101105 (2008)
A. Lyakh, C. Pflügl, L. Diehl, Q.J. Wang, F. Capasso, X.J. Wang, J.Y. Fan, T. Tanbun-Ek, R. Maulini, A. Tsekoun, R. Go et al., Appl. Phys. Lett. 92(11), 111110 (2008)
D. Hofstetter, M. Beck, T. Aellen, J. Faist, U. Oesterle, M. Ilegems, E. Gini, H. Melchior, Appl. Phys. Lett. 78(14), 1964–1966 (2001)
M. Rochat, D. Hofstetter, M. Beck, J. Faist, Appl. Phys. Lett. 79(26), 4271–4273 (2001)
J. Faist, C. Gmachl, F. Capasso, C. Sirtori, D.L. Sivco, J.N. Baillargeon, A.Y. Cho, Appl. Phys. Lett. 71(7), 986 (1997)
K. Namjou, S. Cai, E.A. Whittaker, J. Faist, C. Gmachl, F. Capasso, D.L. Sivco, A.Y. Cho, Opt. Lett. 23(3), 219–221 (1998)
S.W. Sharpe, J.F. Kelly, J.S. Hartman, C. Gmachl, F. Capasso, D.L. Sivco, J.N. Baillargeon, A.Y. Cho, Opt. Lett. 23(17), 1396–1398 (1998)
J.S. Li, W. Chen, H. Fischer, Appl. Spectrosc. Rev. 48(7), 523–559 (2013)
S. Blaser, D.A. Yarekha, L. Hvozdara, Y. Bonetti, A. Muller, M. Giovannini, J. Faist, Appl. Phys. Lett. 86(4), 041109 (2005)
C. Gmachl, D.L. Sivco, R. Colombelli, F. Capasso, A.Y. Cho, Nature 415(6874), 883 (2002)
R. Maulini, M. Beck, J. Faist, E. Gini, Appl. Phys. Lett. 84(10), 1659–1661 (2004)
G. Wysocki, R.F. Curl, F.K. Tittel, R. Maulini, J.M. Bulliard, J. Faist, Appl. Phys. B 81(6), 769–777 (2005)
C. Peng, G. Luo, H.Q. Le, Appl. Opt. 42(24), 4877–4882 (2003)
G. Maisons, P.G. Carbajo, M. Carras, D. Romanini, Opt. Lett. 35(21), 3607–3609 (2010)
D.J. Hamilton, A.J. Orr-Ewing, Appl. Phys. B 102(4), 879–890 (2011)
G.N. Rao, A. Karpf, Appl. Opt. 49(26), 4906–4914 (2010)
C.C. Harb, T.K. Boyson, A.G. Kallapur, I.R. Petersen, M.E. Calzada, T.G. Spence, K.P. Kirkbride, D.S. Moore, Opt. Express 20(14), 15489–15502 (2012)
S. Maithani, A. Maity, M. Pradhan, Chem. Phys. 522, 123–128 (2019)
Y.A. Bakhirkin, A.A. Kosterev, C. Roller, R.F. Curl, F.K. Tittel, Appl. Opt. 43(11), 2257–2266 (2004)
G.N. Rao, A. Karpf, Appl. Opt. 50(13), 1915–1924 (2011)
D. Hofstetter, M. Beck, J. Faist, M. Nägele, M.W. Sigrist, Opt. Lett. 26(12), 887–889 (2001)
M.G. Da Silva, H. Vargas, A. Miklós, P. Hess, Appl. Phys. B 78(6), 677–680 (2004)
A. Elia, C.D. Franco, V. Spagnolo, P.M. Lugarà, G. Scamarcio, Sensors 9(4), 2697–2705 (2009)
W. Liu, L. Wang, L. Li, J. Liu, F.-Q. Liu, Z. Wang, Appl. Phys. B 103(3), 743–747 (2011)
R. Lewicki, G. Wysocki, A.A. Kosterev, F.K. Tittel, Opt. Express 15(12), 7357–7366 (2007)
V. Spagnolo, A.A. Kosterev, L. Dong, R. Lewicki, F.K. Tittel, Appl. Phys. B 100(1), 125–130 (2010)
L. Dong, R. Lewicki, K. Liu, P.R. Buerki, M.J. Weida, F.K. Tittel, Appl. Phys. B 107(2), 275–283 (2012)
H. Ganser, M. Horstjann, C.V. Suschek, P. Hering, M. Mürtz, Appl. Phys. B 78(3–4), 513–517 (2004)
H. Sabana, T. Fritsch, M. Boyomo Onana, O. Bouba, P. Hering, M. MŘrtz, Appl. Phys. B 96(2–3), 535–544 (2009)
P. Kluczynski, S. Lundqvist, J. Westberg, O. Axner, Appl. Phys. B 103(2), 451–459 (2011)
G. Wysocki, A.A. Kosterev, F.K. Tittel, Appl. Phys. B 80(4–5), 617–625 (2005)
G. Hancock, J.H. Van Helden, R. Peverall, G.A.D. Ritchie, R.J. Walker, Appl. Phys. Lett. 94(20), 201110 (2009)
A. Maity, M. Pal, S. Maithani, G.D. Banik, M. Pradhan, Laser Phys. Lett. 15(4), 045701 (2018)
D. Weidmann, F.K. Tittel, T. Aellen, M. Beck, D. Hofstetter, J. Faist, S. Blaser, Appl. Phys. B 79(7), 907–913 (2004)
J. Vanderover, M.A. Oehlschlaeger, Appl. Phys. B 99(1–2), 353–362 (2010)
L. Joly, V. Zéninari, B. Parvitte, D. Weidmann, D. Courtois, Y. Bonetti, T. Aellen, M. Beck, J. Faist, D. Hofstetter, Appl. Phys. B 77(6–7), 703–706 (2003)
L. Wang, T.R. Sharples, Appl. Phys. B 108(2), 427–435 (2012)
G. Gagliardi, F. Tamassia, P. De Natale, C. Gmachl, F. Capasso, D.L. Sivco, J.N. Baillargeon, A.L. Hutchinson, A.Y. Cho, Eur. Phys. J. D-Atom., Mol., Opt. Plasma Phys. 19(3), 327–331 (2002)
B. Tuzson, J. Mohn, M.J. Zeeman, R.A. Werner, W. Eugster, M.S. Zahniser, D.D. Nelson, J.B. McManus, L. Emmenegger, Appl. Phys. B 92(3), 451 (2008)
M.R. McCurdy, Y. Bakhirkin, G. Wysocki, R. Lewicki, F.K. Tittel, J. Breath Res. 1(1), 014001 (2007)
X. Chao, J.B. Jeffries, R.K. Hanson, Appl. Phys. B 106(4), 987–997 (2012)
G.D. Stancu, N. Lang, J. Röpcke, M. Reinicke, A. Steinbach, S. Wege, Chem. Vap. Deposition 13(6–7), 351–360 (2007)
J. Röpcke, G. Lombardi, A. Rousseau, P.B. Davies, Plasma Sourc. Sci. Technol. 15(4), S148 (2006)
A.A. Kosterev, R.F. Curl, F.K. Tittel, C. Gmachl, F. Capasso, D.L. Sivco, J.N. Baillargeon, A.L. Hutchinson, A.Y. Cho, Opt. Lett. 24(23), 1762–1764 (1999)
G.W. Santoni, B.H. Lee, J.P. Goodrich, R.K. Varner, P.M. Crill, J.B. McManus, D.D. Nelson, M.S. Zahniser, S.C. Wofsy, J. Geophys. Res.: Atmos. 117(D10) (2012)
S. Eyer, B. Tuzson, M.E. Popa, C. Van Der Veen, T. Röckmann, M. Rothe, W.A. Brand, R. Fisher, D. Lowry, E.G. Nisbet et al., Atmos. Measur. Tech. 9, 263–280 (2016)
A. Maity, M. Pal, G.D. Banik, S. Maithani, M. Pradhan, Laser Phys. Lett. 14(11), 115701 (2017)
M. Pal, A. Maity, M. Pradhan, Laser Phys. 28(10), 105702 (2018)
B. Tuzson, R.V. Hiller, K. Zeyer, W. Eugster, A. Neftel, C. Ammann, L. Emmenegger, Atmos. Measur. Tech. 3(6), 1519–1531 (2010)
G. Gagliardi, S. Borri, F. Tamassia, F. Capasso, C. Gmachl, D.L. Sivco, J.N. Baillargeon, A.L. Hutchinson, A.Y. Cho, Isot. Environ Health Stud. 41(4), 313–321 (2005)
P.S. Kroon, A. Hensen, H.J.J. Jonker, M.S. Zahniser, W.H van’T Veen, A.T. Vermeulen, Biogeosciences 4(5), 715–728 (2007)
E. Díaz-Pinés, B. Wolf, R. Kiese, K. Butterbach-Bahl, EGU General Assembly Conference Abstracts, vol. 14, Vienna, Austria, p. 7171 (2012)
I. Mappé, L. Joly, G. Durry, X. Thomas, T. Decarpenterie, J. Cousin, N. Dumelie, E. Roth, A. Chakir, P.G. Grillon, Rev. Sci. Instrum. 84(2), 023103 (2013)
F.M. Couto, M.S. Sthel, M.P.P. Castro, M.G. Da Silva, M.V. Rocha, J.R. Tavares, C.F.M. Veiga, H. Vargas, Appl. Phys. B 117(3), 897–903 (2014)
J. Mohn, B. Tuzson, A. Manninen, N. Yoshida, S. Toyoda, W.A. Brand, L. Emmenegger, Atmos. Measur. Tech. 5(7), 1601–1609 (2012)
S.C. Wofsy, Philos. Trans. R. Soc. A: Math., Phys. Eng. Sci. 369(1943), 2073–2086 (2011)
A. PM Michel, P.Q. Liu, J.K. Yeung, P. Corrigan, M.L. Baeck, Z. Wang, T. Day, F. Moshary, C.F. Gmachl, J.A. Smith, Opt. Eng. 49(11), 111125 (2010)
G.D. Banik, A. Maity, S. Som, M. Pal, M. Pradhan, Laser Phys. 28(4), 045701 (2018)
M. Pal, S. Maithani, A. Maity, M. Pradhan, J. Anal. Atom. Spectrometry (2019)
H. Moser, W. Pölz, J.P. Waclawek, J. Ofner, B. Lendl, Anal. Bioanal. Chem. 409(3), 729–739 (2017)
H. Moser, A. Genner, J. Ofner, C. Schwarzer, G. Strasser, B. Lendl, Opt. Express 24(6), 6572–6585 (2016)
W.H. Weber, J.T. Remillard, R.E. Chase, J.F. Richert, F. Capasso, C. Gmachl, A.L. Hutchinson, D.L. Sivco, J.N. Baillargeon, A.Y. Cho, Appl. Spectrosc. 56(6), 706–714 (2002)
H. Sumizawa, H. Yamada, K. Tonokura, Appl. Phys. B 100(4), 925–931 (2010)
A. De, G.D. Banik, A. Maity, M. Pal, M. Pradhan, Opt. Lett. 41(9), 1949–1952 (2016)
R. Lewicki, J.H. Doty, R.F. Curl, F.K. Tittel, G. Wysocki, Proc. Natl. Acad. Sci. 106(31), 12587–12592 (2009)
Y. Yamamoto, H. Sumizawa, H. Yamada, K. Tonokura, Appl. Phys. B 105(4), 923–931 (2011)
J.D. Whitehead, M. Twigg, D. Famulari, E. Nemitz, M.A. Sutton, M.W. Gallagher, D. Fowler, Environ. Sci. Technol. 42(6), 2041–2046 (2008)
L. Gong, R. Lewicki, R.J. Griffin, J.H. Flynn, B.L. Lefer, Atmos. Chem. Phys. 11(18), 9721–9733 (2011)
S. Maithani, S. Mandal, A. Maity, M. Pal, M. Pradhan, Analyst 143(9), 2109–2114 (2018)
D. Weidmann, A.A. Kosterev, C. Roller, R.F. Curl, M.P. Fraser, F.K. Tittel, Appl. Opt. 43(16), 3329–3334 (2004)
T. Yuanyuan, L. Wenqing, K. Ruifeng, L. Jianguo, H. Yabai, Z. Yujun, X. Zhenyu, R. Jun, G. Hui, Opt. Express 19(21), 20224–20232 (2011)
L. Tao, K. Sun, M.A. Khan, D.J. Miller, M.A. Zondlo, Opt. Express 20(27), 28106–28118 (2012)
R. Jiménez, M. Taslakov, V. Simeonov, B. Calpini, F. Jeanneret, D. Hofstetter, M. Beck, J. Faist, H. Van den Bergh, Appl. Phys. B 78(2), 249–256 (2004)
P. Sturm, W. Eugster, A. Knohl, Agric. For. Meteorol. 152, 73–82 (2012)
D. Weidmann, G. Wysocki, C. Oppenheimer, F.K. Tittel, Appl. Phys. B 80(2), 255–260 (2005)
R. Wada, J.K. Pearce, T. Nakayama, Y. Matsumi, T. Hiyama, G. Inoue, T. Shibata, Atmos. Environ. 45(5), 1168–1174 (2011)
A. Kammer, B. Tuzson, L. Emmenegger, A. Knohl, J. Mohn, F. Hagedorn, Agric. For. Meteorol. 151(1), 39–48 (2011)
L. Joly, V. Zeninari, B. Parvitte, D. Courtois, G. Durry, Opt. Lett. 31(2), 143–145 (2006)
American Thoracic Society, Am. J. Respir. Crit. Care Med. 171(8), 912–930 (2005)
M.L. Silva, D.M. Sonnenfroh, D.I. Rosen, M.G. Allen, A. O’keefe, Appl. Phys. B 81(5) 705–710 (2005)
S. Som, G.D. Banik, A. Maity, S. Chaudhuri, M. Pradhan, J. Breath Res. 12(2), 026005 (2018)
M. Pal, S. Maithani, A. Maity, S. Chaudhuri, M. Pradhan, J. Breath Res. 13(1), 016002 (2018)
J. Manne, O. Sukhorukov, W. Jäger, J. Tulip, Appl. Opt. 45(36), 9230–9237 (2006)
N. Pakmanesh, S.M. Cristescu, A. Ghorbanzadeh, F.J.M. Harren, J. Mandon, Appl. Phys. B 122(1), 10 (2016)
B.W.M. Moeskops, H. Naus, S.M. Cristescu, F.J.M. Harren, Appl. Phys. B 82(4), 649–654 (2006)
F. Nadeem, J. Mandon, A. Khodabakhsh, S. Cristescu, F. Harren, Sensors 18(7), 2050 (2018)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Maithani, S., Maity, A., Pradhan, M. (2019). Quantum Cascade Laser Spectroscopy for Atmospheric Sensing and Biomedical Diagnostics. In: Singh, D., Das, S., Materny, A. (eds) Advances in Spectroscopy: Molecules to Materials. Springer Proceedings in Physics, vol 236. Springer, Singapore. https://doi.org/10.1007/978-981-15-0202-6_5
Download citation
DOI: https://doi.org/10.1007/978-981-15-0202-6_5
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-15-0201-9
Online ISBN: 978-981-15-0202-6
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)